卟啉自组装超薄膜的制备及其在光电转换方面的研究*

卟啉及其衍生物的π电子共轭平面结构,使其具有独特的光电性能和良好的热稳定性,在仿生、催化、医学及材料科学等领域得到了广泛的应用。随着自组装技术的不断发展,其在制备功能化超薄膜方面表现出显著的优越性。本文重点介绍了卟啉及其衍生物自组装超薄膜的制备方法,并总结了近年来卟啉自组装膜在光电转换方面的研究进展。     

噻咯类有机小分子光电材料*

噻咯衍生物由于其特殊的σ*-π*共轭,具有较低的最低未占轨道（LUMO）,使得它在电致发光领域有着极大的应用前景。本文从材料合成的角度综述了1,1,2,3,4,5-六取代的噻咯、硅-桥联稠环体系、联噻吩噻咯和螺噻咯类小分子类光电材料的国内外所取得的一些最新进展,介绍了它们作为发光材料和电子传输材料在电致发光器件中的应用情况,讨论了硅原子的引入怎样调节杂环的电子结构,总结了分子结构的修饰对噻咯电子性能的影响。同时,对该领域的发展提出了一些想法。     

Effect of sheath potential on electromagnetic radiation emitted from the rear surface of a metallic foil target

In ultra-intense laser--matter interactions, intense electric fields formed at the rear surface of a foil target may have strong influences on the motion of energetic electrons, and thereby affect the electromagnetic emissions from the rear surface, usually ascribed to transition radiation. Due to the electric fields, transition radiation occurs twice and bremsstrahlung radiation also happens because the electrons will cross the rear surface twice and have large accelerations. In the optic region, transition radiation is dominant. The radiation spectrum depends on the electric field only when the electrons are monochromatic, and becomes independent of the electric field when the electrons have a broadband momentum distribution. Therefore, in an actual experiment, the electric field at the rear surface of a foil could not be studied just with the measurement of optic emissions. In the terahertz region, both bremsstrahlung and transition radiations should be taken into account, and the radiation power could be enhanced in comparison with that without the inclusion of bremsstrahlung radiation. The frequency at which the maximum terahertz radiation appears depends on the electric field.     

各向异性脑组织内的电磁场分布

推导出用时域有限差分（ＦＤＴＤ Ｍｅｔｈｏｄ）计算电导率为各向异性脑组织内部电磁场的一般迭代公式,在此基础上计算了典型各向异性脑组织在几种入射情况下内部电磁场的分布,得出有益的结论。此导出的公式可应用于电磁兼容和生物效应的研究之中。     

飞机构型Euler绕流结构网格方法计算的可信度

采用三种方法验证飞机构型Euler绕流结构网格方法计算。第一,同一网格,采用不同的方甚或程序进行计算;采用Jameson中心差分有限体积方法和Steger-warming流量分裂迎风格式有限体积方法,为计算提供容错手段;第二,网格细化和网格点重新分布,并通过网格收敛指标进行评估;第三,提出新的多块拼接网格拓扑,采用不同的网格拓扑进行计算。     

EFFECT OF EXCITATION-AUTOIONIZATION IN NON-LOCAL THERMODYNAMIC EQUILIBRIUM PLASMAS

Based on the detailed configuration accounting model, the authros have developed a method to calculate the rate of excitation-autoionization (EA) in the average atom model and used it in the rate equations. The numerical results show that EA effect is signifficant in high temperature low density plasma and can cause an additional ionization up to 15% of an ionization stage.     

直流电动机工作时会产生感应电流吗

直流电动机正常工作时, 线圈中的电流不能认为是感应电流. 所以, 不能认为电动机工作过程中, 线圈 中也产生感应电流     

Oracle查询优化的研究与应用

数据库的性能会随着应用系统的数据量变大而降低,甚至会遇到系统卡顿、长时间未响应等问题,而查询SQL的执行效率是影响数据库性能的关键要素之一,因此对数据库性能优化的研究很有必要.首先,简要阐述了Oracle数据库性能优化的相关概念,同时根据总结出3条SQL优化本质.然后,提出了SQL优化的一般步骤路线,通过制定SQL优化...     

填充率对有限高度二维光子晶体带隙的影响

针对三角晶格空气孔和四方晶格介质柱这两种结构的有限高度二维光子晶体,用平面波展开法计算它们在不同填充率下的带隙结构,分析了带隙特性及填充率对带隙结构的影响。结果表明,晶胞中的空气所占的比例较大时,带隙的位置向高频方向移动,带隙宽度则在逐渐增大的同时又受到光锥边界的限制,结构参数为相对介电常数2和12,总高度为3L1;三角和四方晶格的中间层高度分别为L1=0．6a和L1=1.5a时,填充率r／a分别取0．42和0．19可得到较大的带隙,范围分别是(0．30～0．45)和(0．34～0．45)wa／2πc。     

Nonlinear compression of picosecond chirped pulse from thin-disk amplifier system through a gas-filled hollow-core fiber

We theoretically study the nonlinear compression of a 20-m J, 1030-nm picosecond chirped pulse from the thin-disk amplifier in a krypton gas-filled hollow-core fiber. The chirp from the thin-disk amplifier system has little influence on the initial pulse, however, it shows an effect on the nonlinear compression in hollow-core fiber. We use a large diameter hollow waveguide to restrict undesirable nonlinear effects such as ionization; on the other hand, we employ suitable gas pressure and fiber length to promise enough spectral broadening; with 600-μm, 6-bar(1 bar = 105Pa), 1.8-m hollow fiber,we obtain 31.5-fs pulse. Moreover, we calculate and discuss the optimal fiber lengths and gas pressures with different initial durations induced by different grating compression angles for reaching a given bandwidth. These results are meaningful for a compression scheme from picoseconds to femtoseconds.