Solution and Application of the Matrix Equation AX~=b~

§１．　ＩｎｔｒｏｄｕｃｔｉｏｎＪ．ＪＢｕｃｋｌｅｙａｎｄＹ．ＱｕｈａｖｅａｌｒｅａｄｙｇｉｖｅｎｔｈｅｓｏｌｕｔｉｏｎｔｏｔｈｅｍａｔｒｉｘｅｑｕａｔｉｏｎＡｘ＝ｂｗｈｅｎｔｈｅｅｌｅｍｅｎｔｓｉｎＡａｎｄｂａｒｅｔｒｉａｎｇｕｌａｒｆｕｚｚｙｎｕｍｂｅｒｓ,Ａｉｓｓｑｕａｒｅａｎｄａｌｗａｙｓｎｏｎ－ｓｉｎｇｕ－ｌａｒ．Ｉｎｔｈｉｓｐａｐｅｒ,ｗｅａｒｅｃｏｎｃｅｒｎｅｄｗｉｔｈｔｈｅａｐｐｌｉｃａｔｉｏｎａｎｄｓｏｌｕｔｉｏｎｏｆｔｈｅｅｑｕａｔｉｏｎＡｘ＝ｂｗｈｅｎｔｈ…     

锑烯吸附金属Li原子的密度泛函研究

锑烯(antimonene)是继石墨烯和磷烯之后出现的新型二维材料,在锂离子电池等领域受到关注.本文基于第一性原理的密度泛函理论,计算研究了锑烯对Li原子的吸附特性,包括Li原子的最稳定吸附构型、吸附密度以及吸附Li原子的扩散路径.结果表明:Li原子最稳定的吸附位置位于谷位,即底层Sb原子之上、顶层三个Sb原子中心位置,吸附能为1.69 eV,吸附距离为2.81?;能带计算发现,锑烯为带隙宽度1.08 eV的间接带隙半导体,吸附Li原子后费米能级上升进入导带,呈现出金属性;原子分波态密度分析发现, Sb原子的p电子态和Li原子的p和s电子态形成明显的共振交叠,表现出杂化成键的特征;随着吸附Li原子数量增加,锑烯晶格结构和电子结构发生较大变化.通过微动弹性带方法计算发现, Li原子在锑烯表面的扩散势垒为0.07 eV,较小的势垒高度有利于快速充放电过程.     

Field—ion microscopy observation of single—walled carbon nanotubes

Field-ion microscopy(FIM),a tool for surface analysis with atomic resolution,has been employed to observe the end structure of single-walled carbon nanotubes(SWCNTs).FIM images revealed the existence of open SWCNT ends,Amorphous carbon atoms were also observed to occur around SWCNTs and traditional field evaporation failed to remove them.Heat treatment was found to be efficacious in altering the end structures of SWCNT bundles.Carbon and oxygen atoms released from heated tungsten filament are believed to be responsible for the decoration imposed on the SWCNT ends.     

聚(2-甲氧基-5-辛氧基)对苯乙炔/TiO2纳米复合材料的光物理性能研究

通过原位强碱诱导下的脱氯化氢缩合聚合法制备了一系列不同纳米TiO2含量的聚(2-甲氧基-5-辛氧基)对苯乙炔/纳米二氧化钛(PMOCOPV/TiO2)光电复合材料。红外光谱和拉曼光谱证实了在纳米TiO2表面的包覆层为PMOCOPV。紫外-可见吸收光谱表明随着TiO2含量的增加PMOCOPV/TiO2纳米复合材料的吸收强度提高。高分辨透射电镜观察发现PMOCOPV/TiO2是具有核-壳结构的纳米复合粒子,直径约30 nm,其中PMOCOPV包覆层的厚度约为8~10 nm。荧光光谱研究表明,PMOCOPV/TiO2纳米复合材料的最大发射波长随着TiO2含量的增加发生红移,荧光寿命约为1 ns,且随着TiO2含量的增加荧光强度和荧光寿命得到显著提高,并通过PMOCOPV/TiO2纳米复合材料中的激子离化和电荷传输过程以及复合材料中的电势能级探讨了PMOCOPV/TiO2的荧光量子效率和荧光强度增加的机理。     

Superconductivity of Lanthanum Superhydride Investigated Using the Standard Four-Probe Configuration under High Pressures

Recently,the theoretically predicted lanthanum superhydride,LaH_10±δ,with a clathrate-like structure was successfully synthesized and found to exhibit a record high superconducting transition temperature T_c≈250 K at～170 GPa,opening a new route for room-temperature superconductivity.However,since in situ experiments at megabar pressures are very challenging,few groups have reported the ～250 K superconducting transition in LaH_10±δ.Here,we establish a simpler sample-...     

高k栅介质纳米MOSFET栅电流模型

介绍了一种纳米MOSFET(场效应管)栅电流的统一模型,该模型基于Schrodinger-Poisson方程自洽全量子数值解,特别适用于高k栅介质和多层高k栅介质纳米MOSFET.运用该方法计算了各种结构和材料高k介质的MOSFET栅极电流,并对pMOSFET和nMOSFET高k栅结构进行了分析比较.模拟得出栅极电流与实验结果符合,而得出的优化氮含量有待实验证实.     

复杂环境背景下典型飞行器表面红外反射特性研究

飞机蒙皮对于背景辐射的反射可以作为红外目标识别的辐射源,但背景辐射通常来源于太阳辐射和地面背景辐射等辐射的综合作用,其复杂性和多变性也可能使飞机的红外反射辐射严重干扰红外制导的准确性,因此,研究复杂环境背景下的飞机蒙皮红外反射特性对于红外目标识别和红外导弹制导等应用具有重要意义.本文基于Schlick双向反射分布函数(...     

Ionic-Liquid-Gating Induced Protonation and Superconductivity in FeSe,FeSe_(0.93)S_(0.07), ZrNCl, 1T-TaS_2 and Bi_2Se_3

We report protonation in several compounds by an ionic-liquid-gating method, under optimized gating conditions.This leads to single superconducting phases for several compounds. Non-volatility of protons allows post-gating magnetization and transport measurements. The superconducting transition temperature T_c is enhanced to 43.5 K for FeSe_(0.93)S_(0.07), and 41 K for Fe Se after protonation. Superconducting transitions with T_c～15 K for ZrNCl,～7.2 K for 1-TaS_2, and ～3.8 K for Bi_2Se_3 are induced after protonation. Electric transport in protonated FeSe_(0.93)S_(0.07) confirms high-temperature superconductivity. Our~1 H nuclear magnetic resonance(NMR)measurements on protonated Fe Se_(1-x)S_x reveal enhanced spin-lattice relaxation rate 1/~1T_1 with increasing x,which is consistent with the LDA calculations that H~+ is located in the interstitial sites close to the anions.     

数字脉压的DSP实现及性能模拟

本文主要介绍具体工程上实现数字脉压的基本原理和用DSP实现的方法，以及如何对数据进行合理的分段，并对影响脉压的几个重要因素作了仿真模拟。     

可溶性聚对苯乙炔衍生物非线性光学效应研究

以对甲氧基苯酚和溴代烷为原料,经过脱氯化氢反应合成了三种可溶性非对称烷氧基取代聚对苯乙炔 (PPV)衍生物,分别为聚(2 甲氧基 5 丁氧基)对苯乙炔(PMOBOPV)、聚[2 甲氧基 5 (3′ 甲基)丁氧基]对苯乙炔 (PMOMBOPV)和聚(2 甲氧基 5 辛氧基)对苯乙炔(PMOCOPV)。利用后向式简并四波混频(DFWM)研究了它们 的三阶非线性光学性质。结果表明PMOBOPV,PMOMBOPV和PMOCOPV的三阶非线性极化率(χ(3))分别为 3.14×10-10,5.96×10-10和3.71×10-10esu,相应的二阶分子超极化率(γ)分别为4.22×10-28,7.78×10-28和 5.00×10-28esu。分析了分子结构对聚对苯乙炔衍生物非线性光学性质的影响。采用分光光度计对三种材料的 光学禁带宽度(Eg)进行了测量,线性拟合的结果表明PMOBOPV,PMOMBOPV和PMOCOPV的Eg值分别为 2.08,2.03及2.05eV。