全文获取类型
收费全文 | 1155246篇 |
免费 | 134164篇 |
国内免费 | 141207篇 |
专业分类
化学 | 503142篇 |
晶体学 | 7989篇 |
力学 | 39399篇 |
综合类 | 13497篇 |
数学 | 81861篇 |
物理学 | 318736篇 |
无线电 | 465993篇 |
出版年
2024年 | 8272篇 |
2023年 | 26873篇 |
2022年 | 31556篇 |
2021年 | 29786篇 |
2020年 | 24513篇 |
2019年 | 27525篇 |
2018年 | 24190篇 |
2017年 | 23669篇 |
2016年 | 27681篇 |
2015年 | 30389篇 |
2014年 | 53292篇 |
2013年 | 46946篇 |
2012年 | 82125篇 |
2011年 | 94602篇 |
2010年 | 54710篇 |
2009年 | 51959篇 |
2008年 | 85453篇 |
2007年 | 84821篇 |
2006年 | 84099篇 |
2005年 | 78333篇 |
2004年 | 68679篇 |
2003年 | 57295篇 |
2002年 | 49756篇 |
2001年 | 40695篇 |
2000年 | 38685篇 |
1999年 | 20593篇 |
1998年 | 12562篇 |
1997年 | 9628篇 |
1996年 | 15095篇 |
1995年 | 12793篇 |
1994年 | 13804篇 |
1993年 | 14144篇 |
1992年 | 13550篇 |
1991年 | 9513篇 |
1990年 | 9232篇 |
1989年 | 9090篇 |
1988年 | 9435篇 |
1987年 | 8681篇 |
1986年 | 8318篇 |
1985年 | 7689篇 |
1984年 | 5747篇 |
1983年 | 4663篇 |
1982年 | 3946篇 |
1981年 | 3356篇 |
1980年 | 2339篇 |
1979年 | 1415篇 |
1978年 | 812篇 |
1975年 | 520篇 |
1965年 | 504篇 |
1948年 | 903篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
21.
MUHAMMAD Naeem Ahmed KHAWAJA Ansar Yasin MUHAMMAD Nawaz Tahir IFZAN Arshad MURTAZA Madni 《结构化学》2015,34(1):26-32
Two new 1,4-disubstituted 1,2,3-triazoles-4-carboxylates were synthesized via click reaction. Compound 1a was synthesized by the interaction of 6-nitro-tetrazolo[1.5-a]-pyridine with ethyl propynoate at room temperature in the presence of Cu(OAc)2 as a catalyst and THF as solvent. Compound 1b was also synthesized by the same manner except that tert-butyl propionate, instead of ethyl propynoate, was used. The compounds were characterized by IR, 1H-NMR, 13C-NMR and single-crystal X-ray diffraction analysis. Compound 1a(C10H9N5O4) crystallizes in the triclinic system, space group P1 with a = 5.0894(9), b = 8.9834(13), c = 13.089(2) ?, α= 83.041(7), β= 80.256(7), γ=87.296(8)°, V = 585.24(16)?3, Z = 2, Mr = 263.22, crystal size(mm) = 0.37 × 0.20 ×0.18,(I 2σ(I)) = 8557, 2493, 1229, Rint = 0.057. Compound 1b(C12H13N5O4) crystallizes in the monoclinic system, space group P21/c with a = 6.8854(5), b = 21.783(2), c = 9.3986(8) ?,β = 93.239(4)°, V = 1407.4(2)?3, Z = 4, Mr = 291.27, crystal size(mm) = 0.38 × 0.22 × 0.20,(I 2σ(I)) = 11842, 3172, 1866, Rint = 0.047. Antimicrobial assay results showed that the title compounds display excellent activities to different bacterial and fungal strains. 相似文献
22.
本文介绍了广元广电在专网业务上的积极探索实践,讲述了远程教育专网项目的具体解决方案,分享了专网业务给广电带来的价值及意义,给广电开启新的业务发展和业务合作思路。 相似文献
23.
Within the framework of the effective-mass approximation and the dipole approximation, considering the three-dimensional confinement of the electron and hole and the strong built-in electric field(BEF) in strained wurtzite Zn O/Mg0:25Zn0:75O quantum dots(QDs), the optical properties of ionized donor-bound excitons(D+, X)are investigated theoretically using a variational method. The computations are performed in the case of finite band offset. Numerical results indicate that the optical properties of(D+, X) complexes sensitively depend on the donor position, the QD size and the BEF. The binding energy of(D+, X) complexes is larger when the donor is located in the vicinity of the left interface of the QDs, and it decreases with increasing QD size. The oscillator strength reduces with an increase in the dot height and increases with an increase in the dot radius. Furthermore, when the QD size decreases, the absorption peak intensity shows a marked increment, and the absorption coefficient peak has a blueshift. The strong BEF causes a redshift of the absorption coefficient peak and causes the absorption peak intensity to decrease remarkably. The physical reasons for these relationships have been analyzed in depth. 相似文献
24.
25.
In this study,a series of experiments were carried out on the AZ31B magnesium alloy,including both a macro-experiment(mechanical experiment)and a micro-experiment(dislocation observation).Next,based on the consideration of the deformation mechanism of magnesium alloys(dislocation slip and twinning),a dynamic constitutive model of the magnesium alloy was established.In the developed model,the strain-rate-sensitivity control and the effect of temperature on the dynamic mechanical performance of the alloy were also investigated.The model parameters were determined by fitting the macroscopic experimental results.Next,the evolution of the micro-deformation mechanism was calculated by the developed model,and the trend of macro-mechanical behavior was also discussed. 相似文献
27.
针对基站柜式空调耗电量大的问题,创造性地使用基站分布式冷却的方式,达到精确送风,节能高效的目的.在应用实践中检验了分布式冷却系统实际节能量和应用效果,总结出分布式冷却系统应用场景和范围,为更大范围推广应用DCS分布式冷却系统提供实践依据. 相似文献
28.
Lijuan Shen Li Li Sheng Lu Xiaohan Zhang Jie Liu Junlin An Guojun Zhang Bo Wu Fei Wang 《中国颗粒学报》2015,(3):10-15
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion. 相似文献
29.
We investigate the effect of dopant random fluctuation on threshold voltage and drain current variation in a two-gate nanoscale transistor. We used a quantum-corrected technology computer aided design simulation to run the simulation (10000 randomizations). With this simulation, we could study the effects of varying the dimensions (length and width), and thicknesses of oxide and dopant factors of a transistor on the threshold voltage and drain current in subthreshold region (off) and overthreshold (on). It was found that in the subthreshold region the variability of the drain current and threshold voltage is relatively fixed while in the overthreshold region the variability of the threshold voltage and drain current decreases remarkably, despite the slight reduction of gate voltage diffusion (compared with that of the subthreshold). These results have been interpreted by using previously reported models for threshold current variability, load displacement, and simple analytical calculations. Scaling analysis shows that the variability of the characteristics of this semiconductor increases as the effects of the short channel increases. Therefore, with a slight increase of length and a reduction of width, oxide thickness, and dopant factor, we could correct the effect of the short channel. 相似文献
30.