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11.
制备了四种不同铒离子掺杂浓度的碲酸盐玻璃,通过测定吸收光谱计算了吸收谱线的振子强度,根据Judd-Ofelt理论计算了不同浓度下Er3 离子发光光谱的强度参数Ωi(i=2,4,6),计算了自发辐射电偶和磁偶跃迁概率、辐射寿命、荧光分支比等参数,讨论了Er3 离子浓度变化对以上这些参数的影响.测试了Er3 :4I13/2→4I15/2跃迁对应的荧光光谱和Er3 :4I13/2能级荧光寿命.最后应用McCumber理论计算了玻璃中Er3 :4I13/2→415/2跃迁对应的受激发射截面大小.结果表明:振子强度基本上随Er3 离子浓度的增大而增强;随着Er3 离子浓度的增加,自发辐射跃迁概率A基本呈现出递增的趋势,但荧光分支比β却只有很小的变化;Er3 :4I13/2→4I15/2的发射截面随Er3 离子浓度的增大而改变很小,有效线宽都在50 nm左右. 相似文献
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在组成为15Li2O-15Nb2O5-70TeO2-0.1Er2O3-0.4Yb2O3(%, 摩尔分数)的碲酸盐玻璃基础上, 采用两步热处理法制备了透明的含纳米晶颗粒碲酸盐玻璃陶瓷. 通过X射线衍射(XRD)测试表明, 玻璃陶瓷中的晶体颗粒组成为Yb6Te5O19.2或Er6Te5O19.2, 晶粒尺寸约为55 nm. 根据Judd-Ofelt理论计算了Er^3+离子在基质玻璃和玻璃陶瓷中的光谱参数Ωt(t=2, 4, 6)以及Er^3+:4I15/2→4I13/2跃迁自发辐射几率, 根据McCumber理论计算了Er^3+:4I13/2→4I15/2跃迁的发射截面. 测试了基质玻璃和玻璃陶瓷的拉曼光谱, 对比研究了铒离子在基质玻璃和玻璃陶瓷中1.5 μm处荧光和上转换光谱特性. 相似文献
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Yb3+掺杂锌锗碲酸盐玻璃的热分析、光谱和激光性质 总被引:3,自引:2,他引:3
设计了组成为0.70TeO2-(0.20-x)ZnO-xGeO2—0.05La2O3-0.025K2O-0.025Na2O-0.01Yb2O3(摩尔分数x=0,0.05,0.10,0.15和0.20)的碲酸盐激光玻璃,测试了热学性质、吸收光谱、荧光光谱和荧光寿命。计算了Yb^3 离子的吸收截面、受激发射截面、荧光有效线宽等参数。结果表明,组成为0.70TeO2-0.20GeO2-0.05La2O3-0.025K2O-0.025Na2O的玻璃具有优于著名的碲锌钠(TZN)玻璃的热稳定性,高的受激发射截面(1.23pm^2)。长的荧光寿命(0.92ms)和宽的荧光有效线宽(77nm)。通过激光性能评价。最小抽运强度为0.98kW/cm^2,表明掺Yb^3 组份的碲酸盐玻璃是实现高能短脉冲可调谐激光器的理想增益介质。 相似文献
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研究了重金属氧氟硅铋酸盐玻璃 (50-x)SiO2 xBi2O3 50PbF2(x=0, 3, 5, 8, 10, 13, 15 mol%)中Er3+离子的吸收光谱、荧光光谱、荧光半高宽、荧光 寿命和热稳定性能.应用Judd Ofelt理论计算了玻璃的强度参数Ωt(t=2,4,6),应用 McCumber计算了能级4I13/2→4I15/2跃迁的受激发射截面. 结果发现荧光半高宽与Ω6有较大联系,Ω6越大,荧光半高宽越宽.对Er3+
关键词:
重金属氧氟硅铋酸盐玻璃
光谱性质
Er3+离子
Judd Ofelt参数 相似文献
15.
Laser-diode excited intense upconversion luminescence of Er^3+ in bismuth-lead-germanate glasses 下载免费PDF全文
We have investigated infrared-to-visible upconversion luminescence of Er^3+ in bismuth-lead-germanate glasses. The UV cutoff wavelength is shortened while its lifetime is increased almost linearly, with PbF2 substituting for PbO in the bismuth-lead germanate glasses. Three emissions centred at around 529, 545 and 657 nm are clearly observed, which are identified as originating from the ^2H11/2→^4 I15/2,^4S3/2→^4 I15/2 and ^4 F9/2 →^4 I15/2 transitions, respectively. It is noted that all the upconversion emission intensities increase with PbF2 concentration increasing. The ratio between the intensities of red and green emissions increases with the increasing of PbF2 content. Energy transfer processes and nonradiative phonon-assisted decays account for the populations of the ^2 H11/2,^4 S3/2 and ^4F 9/2 levels. The quadratic dependence of fluorescence on excitation laser power confirms a two-photon process to contribute to the upconversion emissions. 相似文献
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用准连续60W的二极管激光列阵侧面泵浦“之”字形Nd:YAG板条激光器,当泵浦功率为45W,脉宽为400μs时,得到3.5mJ的激光输出。用KD*P电光开关调Q,得到18ns(FWHM)、2mJ的脉冲激光输出,用KTP晶体作腔内倍频,得到15ns、0.85mJ的二次谐波激光输出。在腔内无调Q元件且腔长小于5cm时,于近阈值处得到单频绿光输出,而当泵浦功率稍大,腔内有数个纵模振荡时,观察到激光的反相态,并用数值模拟的结果对此作了解释。 相似文献
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Er3+-doped heavy metal borosilicate glasses were prepared using conventional melting and quenching method. The emission spectra of 4I13/2 → 4I15/2 transition were observed upon excitation at 974 nm and the lifetime of 4I13/2 level of Er3+ was measured. Based on these data, the fluorescence properties of Er3+ are investigated on the emission and gain characteristics at the 1.5 μm bands. In particular, the effect of relative heavy metal content on fluorescence properties is discussed. 相似文献
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Host dependent thermal stability and frequency upconversion of Er^3+-doped heavy metal oxyfluoride germanate glasses 下载免费PDF全文
The upconversion properties of Er^3+-doped heavy metal oxyfluoride germanate glasses under 975 nm excitation have been investigated. The intense green (551 and 529 nm) and relatively weak red (657 nm) emissions corresponding to the transitions ^4S3/2→^4I15/2, ^2H11/2→^4 I15/2 and ^4F9/2 →^4I15/2, respectively, were simultaneously observed at room temperature. The content of PbF2 has an important influence on the upconversion luminescence emission. With increasing content of PbF2, the intensities of green (529 nm) and red (657 nm) emissions increase slightly, while the green emission (551 nm) increases markedly. These results suggest that PbF2 has an influence on the green (551 nm) emission more than on the green (529 nm) and red (657 nm) emissions. 相似文献
20.
玻璃的最大声子能量决定稀土离子的上转换发光强度,但本研究发现:Yb^3 /Er^3 共掺锗碲酸盐玻璃在980nm LD抽运下,上转换荧光强度随着Bi2O3对PbO的取代和碱金属离子半径的增大而明显增强.而Raman光谱显示基质玻璃的最大声子能量并不随Bi2O3对PbO的取代和碱金属离子半径的增大而变化,但玻璃的最大声子密度随着Bi2O3对PbO取代和碱金属离子半径的增大而降低.从玻璃无辐射跃迁概率的角度,通过分析表明,最大声子密度的降低是玻璃上转换发光强度增强的主要原因. 相似文献