STRUCTURE AND PROPERTIES OF THE La-DOPED Bi-2201 SYSTEM

In this article, the influence of La substitution for Sr on structure and physi-cal properties of the 2201 phase is studied. First, the crystal microstructure of the Bi_2.1Sr_1.9-xLa_xCuO_y (0≤x≤1.0) is characterized by means of X-ray diffraction and electron diffraction analyses, it is discovered that in the La-doped 2201 system with increasing La content the 2201 phase undergoes tetragnoal-orthorhombic-monoclinic structural transition. With this phase transition, the modulation vector of the 2201 phase transforms from incommensurate to commensurate, and the period of the mod- ulation wave decreases. Secondly, the superconductivity of this system is analyzed systematically. The results of the resistivity measurement show that the appropriate amount of La doping can raise the superconducting transition temperature (T_c) of the 2201 phase, with x=0.2, T_c reaches as high as 25K. However the excessive doping of La (x≥0.3) leads the 2201 phase to transit from metal to insulator and the su-perconductivity disappears. The measurement of thermoelectric power (TEP) of this system shows that with increasing La content the TEP value also increases gradu-ally. But the interesting point is that the transition from positive to negative in TEP occurs for x=0.2 sample. In addition, the electronic structure and oxygen content of this system are also studied. Based on these, we analyze the relation between the microstructure, electronic structure of the La-doped 2201 phase and its superconduc-tivity, indicating that the type of element substitution with higher valence, together with the microstructural distortion induced by the substitution affects the electronic states of Cu 3d seriously, that is, changes the degree of coulomb correlation of Cu 3d electrons, thus resulting in the transition of the type of carrier of this system and the decrease of hole carrier concentration, as well as the corresponding variation of the superconductivity of La-doped 2201 phase.     

Ca5N4高压新相的第一性原理研究

通过在氮中引入杂质离子,利用高压手段获得具有新奇结构的多氮化合物是目前被广泛应用的研究方法.钙氮材料在催化、光电方面有着广泛的应用.具有较低电离能的钙(Ca)元素很容易和氮原子形成离子键钙氮化物.高压为寻找新型钙氮化合物提供了全新的技术途径.因此,利用高压方法,通过改变配比的方式,寻找具有新奇特性的钙氮高压结构,是一项非常有意义的工作.本文利用基于密度泛函理论的结构搜索方法,在100 GPa条件下,通过预测得到了一个稳定的Ca5N4相.该结构内部氮原子之间以N-N共价单键键合,氮原子和钙原子之间是离子键相互作用,且钙氮之间的电荷转移量为1.26 e/N atom.能带结构计算表明P 21/c-Ca5N4是一个直接带隙为1.447 eV的半导体结构.最后,系统地给出了该结构的拉曼振动光谱,并指认了拉曼振动模式,为实验合成该结构提供了理论指导.     

高温超导电缆减压制冷仿真及试验研究

过冷77K液氮循环是保持超导电缆系统稳定的重要前提。为避免循环液氮发生相变,需设计安全性高、成本低、维护便利的低温制冷系统。抽真空减压制冷方式以其节能、环保方面的巨大潜力,是超导电缆制冷系统设计重要技术之一。针对抽真空减压过程中温度变化、气液相状态、液氮消耗问题,本文开展了减压制冷系统设计计算及仿真研究,搭建了减压制冷系统测试装置平台,对减压制冷系统设计方案进行验证,测试结果表明,减压制冷系统实际温度下降速度小于仿真数据,液氮消耗量实测大于仿真值,对于超导电缆减压制冷系统设计具有参考意义。     

移动电子商务开创盈利新空间

随着移动网络从2.5G到3G的演进,网络所支持的移动数据速率的快速提升,一些面向移动商务领域发展的趋势日益明显:越来越多的消费者喜欢上了网上购物,增值的SMS业务大受欢迎,而且越来越多的预付费充值购买可以通过移动电话进行。移动商务成为现在和今后的移动应用的重要内容,本文     

后SMS时代的“杀手应用”——上海贝尔阿尔卡特RUSH-TO-TALK业务解决方案

Push—To—Talk目前是业界普遍关注的话题，它被称为基于SMS后的另一种“杀手级”的应用，它拓展了移动数据应用，必将为运营商带来丰厚的利润回报。     

Preferred orientations of encapsulated C60 molecules inside single wall carbon nanotubes

A systematical study of the orientational behavior of C60 molecules in single wall carbon nanotubes (SWCNTs) with different chirality and diameter has been performed by using a model of an infinite long nanotube filled with two C60 (denoted as C60-1 and C60-2) molecules. We studied the preferred orientation of the C60-1 molecule when the neighboring C60-2 molecule was fixed at the pentagon, double-bond, and hexagon orientations respectively. Our results showed that the C60-1 molecule prefers the pentagon (hexagon) orientation when the tube diameter is smaller (larger) than 1.31nm (1.36nm). For the tube diameter in between, the preferred molecular orientation of C60-1 changes from pentagon to hexagon with the increasing tube diameter when the neighboring C60-2 molecule is fixed at the pentagon or double-bond orientation. A novel vertex orientation for the C60-1 molecule has been found when the C60-2 molecule is fixed at the hexagon orientation.     

GdNbO_4∶Er~(3+)/Yb~(3+)荧光粉的上转换发光与温度特性

采用传统高温固相法制备了GdNbO_4∶10%Yb~(3+),x%Er~(3+)荧光粉。利用XRD对样品的晶体结构进行了分析,结果表明所得的样品为纯相。在980nm光纤激光器激发下,测量了样品的上转换发射光谱,实验发现样品发生了浓度猝灭。利用荧光强度比(FIR)方法研究了GdNbO_4∶Yb~(3+)/Er~(3+)荧光粉的温度传感特性,结果表明灵敏度随温度的升高先增大后减小。建立了Er~(3+)的两个绿色发射能级的温度猝灭物理模型并用其成功解释了样品的绿色上转换发光温度猝灭现象。     

Stable single helical C-and I-chains inside single-walled carbon nanotubes

The helicity of stable single helical carbon chains and iodine chains inside single-walled carbon nanotubes(SWCNTs)is studied by calculating the systematic van der Waals interaction energy.The results show that the optimal helical radius increases linearly with increasing tube radius,which produces a constant separation between the chain structure and the tube wall.The helical angle exhibits a ladder-like decrease with increasing tube radius,indicating that a large tube can produce a small helicity in the helical structures.