实用型简易激光诱导荧光检测器的研制及性能测试

基于正交型结构,研制了一种简易实用的高效液相色谱激光诱导荧光检测器。以930荧光光度计为骨架,用岛津RF-535荧光检测池,配以自制可调稳压电源,分别以波长532am和405nm的自制激光器为激发光源,以罗丹明B和荧光素为荧光试剂评价体系的性能。罗丹明B的检出限为2．0×10^-8mol／L（S／N〉10）,荧光素的检出限为3．0×10^-10mol／L（S／N〉10）。测试结果表明该检测器达到了设计要求,具有足够的实用灵敏度和较宽的线性范围。     

Banach空间中逆强增生算子修正的Halpern迭代序列强收敛性

在一致凸一致光滑的Banach空间中,引进了一个新的修正的Halpern迭代序列,并证明了该迭代序列关于α-逆强增生算子的强收敛性,所得结果把其他一些相关的近代结果从2-一致光滑Banach空间推广到一致光滑Banach空间,并且证明方法也不相同.     

Quantum correlations between two non-interacting atoms under the influence of a thermal environment

By considering a double Jaynes-Cummings model,we investigate the dynamics of quantum correlations,such as the quantum discord and the entanglement,for two atoms in their respective noisy environments,and study the effect of the purity and the cavity temperature on the quantum correlations.The results show that the entanglement suffers sudden death and revival,however the quantum discord can still reveal the quantum correlations between the two atoms in the region where the entanglement is zero.Moreover,when the temperature of each cavity is high the entanglement dies out in a short time,but the quantum discord still survives for quite a long time.It means that the quantum discord is more resistant to environmental disturbance than the entanglement at higher temperatures.     

大环手性磷酰胺对氨基酸衍生物的分子识别研究

以(S)-α-甲基苯乙胺和天然氨基酸(L-丙氨酸、L-苯甘氨酸及L-苯丙氨酸)为手性源,以2,5-二(邻羟基苯基)-1,3,4- 二唑和2,4-二(邻羟基苯基)-1,3,5- 二唑为刚性单元,合成了一系列具有光学活性的新型含 二唑磷酰胺和磷酯手性大环化合物.用NMR,IR和FABMS方法研究了所合成的手性大环对氨基酸甲酯盐酸盐和二肽的分子间相互作用和分子识别.结果表明,这些主体对D-或L-氨基酸甲酯盐酸盐和二肽具有选择性的结合作用.     

基于DBR结构自脉动激光器的波长及频率可变光微波源

首次报道了基于DBR结构自脉动激光器的波长及频率可变光微波源。该微波源可以或得1.87GHz至21.81GHz的微波信号同时可以获得1536.28nm至1538.73nm的波长调谐。     

受激布里渊散射的新介质

为了寻找性能良好的受激布里渊散射(SBS)介质,根据SBS对介质的要求,试验了几种全卤代烃新介质。测定或计算了增益系数、声子寿命和吸收系数等参数。四氯乙烯(C2Cl4)具有良好的SBS特性,其增益系数为9.0cm·GW-1,声子寿命为0.59ns,吸收系数为0.003cm-1。分析和讨论了介质化学结构对SBS特性的影响。     

温度调谐的MgO∶LiNbO3 光学参量振荡器

采用电光调Q Nd∶YAG经KTP晶体倍频得到0.532μm的激光,泵浦非临界相位匹配的MgO∶LiNbO3晶体。当光学参量振荡器(OPO)的输出镜采用对剩余泵浦光高反的腔镜时,泵浦阈值有明显的降低,转换效率提高了2个百分点。     

The entanglement between two isolated atoms in double mode--mode competition model

Extending the double Jaynes--Cummings model to a more complicated case where the mode--mode competition is considered, we investigate the entanglement character of two isolated atoms by means of concurrence, and discuss the dependence of atom--atom entanglement on the different initial state and the relative coupling strength between the atom and the corresponding cavity field. The results show that the amplitude and the period of the atom--atom entanglement evolution can be controlled by the choice of initial state and relative coupling strength, respectively. We find that the phenomenon of entanglement sudden death (ESD) is sensitive to the initial conditions. The length of the time interval for zero entanglement depends not only on the initial degree of entanglement between two atoms but also on the relative coupling strength of atom--field interaction. The ESD effect can be weakened by enhancing the mode--mode competition between the three- and single-photon processes.     

一种面向大面阵焦平面阵列的低功耗多功能读出电路设计

大面阵焦平面成像探测器需要具有随机开窗和反转读出功能,同时需要降低功耗。文章基于标准数字电路设计流程。设计了一种新型的基于格雷码编码规律的寻址计数器,用于对阵列的行地址和列地址进行寻址,提高了寻址的可靠性。对设计进行RTL级仿真,结果表明该设计能够实现任意开窗和反转读出功能。采用TSMC90工艺库对1024×1024阵列规模的RTL级设计进行分析计算,结果显示供电电压为3.3V时,寻址计数器功耗仅为19.56μW,整体设计功耗仅为58.75μW,适用于大面阵焦平面读出电路的设计。     

开链冠醚型手性双噁（噻）唑啉配体的合成及其应用研究

合成了6个新的具有开链冠醚结构的手性双噁唑啉配体（4a～4d）和手性双噻唑啉配体(5b，5c)，用红外光谱、核磁共振氢谱、核磁共振碳谱、元素分析等对其结构进行了表征。初步考察了其在Henry反应中的不对称催化活性。