等规聚苯乙烯的分子量分级

用配位聚合法得到的高等规度的等规聚苯乙烯(i-PS),一般具有较宽的分子量分布,对其进行分子量分级是比较难的,迄今已有不少这方面的报道,其中包括采用热力学的方法,以及采用分子量降解的方法。为了获得分子量分布较窄的i-PS样品来研究单链单晶,我们也进行了i-PS的分级研究,我们选用了一种新的溶剂/不良溶剂体系对i-PS     

乙烯-甲基丙烯酸共聚物离聚体在聚对苯二甲酸乙二酯中的相分离行为

聚对苯二甲酸乙二酯(PET)结晶速度很慢,通常加入成核剂来提高结晶速度。从专利文献来看,以离子聚合物为成核剂的例子也是很多的。离子聚合物与小分子成核剂的显著差别是:离子聚合物有一个很长的碳氢主链,其侧基为酸基,酸基被部分或全部地中和成盐。很明显,离子聚合物不象小分子成核剂那样能很好地分散在PET基体中,而是以独立的相存在。作为PET体系系列研究的继续,本文报道了离子聚合物Surlyn在PET中的相分离行为。     

甲基丙烯酸甲酯光引发聚合中的初级自由基终止效应

本文研究了甲基丙烯酸甲酯在30℃时的光引发聚合。当光强较强时,聚合速率和光强的平方根不呈线性关系,聚合速率略低于经典动力学关系式所预示的数值。粘均聚合度的倒数和聚合速率也不呈线性关系。在考虑了初级自由基的终止反应后,这些偏离都得到了合理的解释。 比较甲基丙烯酸甲酯在30℃的光引发聚合和在60℃的过氧化苯甲酰引发聚合的数据,可以看出,初级自由基的终止效应在低温时更为重要。     

硅甲基硼烯异构化反应机理研究

用量子化学理论方法研究了硅甲基硼烯(SiH_3B)单重态和三重态异构化反应,计算了有关化合物的电子结构,优化了过渡态构型,讨论了两个反应的控制类型.     

Coupling matrix element of electron self-exchange reactions in solution

On the basis of the common feature among the electron transfer process and the ion hydration process as well as the relevant experimental kinetic data of electron transfer reaction,a new accurate hydration potential function scheme for the determination of electron transfer coupling matrix element is presented.The coupling matrix element between two hydrated ions of the reacting system in solution is calculated.The results and the applicability of this scheme are discussed.     

CRYSTALLIZATION AND MELTING OF NYLON 610

Differential scanning calorimetry was used to study the crystallization andmelting of nylon 610. For nylon 610 crystallized from the melt state (260℃), the overall rateof bulk crystallization can be described by a simple Avrami equation with Avrami exponentn ≈ 2, independent of crystallization temperature. With the experimentally obtainedT_m~0 (235℃ ～ 255℃) of nylon 610, the fold surface free energy σ_e was determined to be35 ～38 erg/cm~2. The effects of annealing temperature and time on the melting of quenchednylon 610 were also investigated. For nylon 610 quenched at room temperature there isonly one DSC endotherm peak DSC scans on annealed samples exhibited an endothermpeak at approximately 10℃ above the annealing temperature. The size and position of theendothermic peak is strongly related to annealing temperature and time. An additionalthird melting was observed when quenched nylon 610 was annealed at high temperaturefor a sufficiently long residence time. The existence of the third melting peak suggests thatmore than one kind of distribution of lamella thickness may occur when quenched nylon610 is annealed. The implications of these results in terms of crystal thickening mechanismwere discussed.     

移动通信系统VoIP高效传输方法

研究在移动通信终端和P-GW/GGSN之间采用短标签替代VoIP标准协议头以提高传输效率的传输方案与实现方法。     

一道课外练习题的别证

题在矩形ABCD中,点M是边AD的中点,点N是边BC的中点,在边CD的延长线上任取一点P,联结PM并延长交AC于点Q,求证:∠PNM=∠MNQ.这是贵刊2011年3月下的一道课外练习题,是由笔者编拟提供的,原解答比例代换繁杂,一般学生不易掌握,今再给出一种学生易掌握的证法.     

低频压电马达的工作机理与动力学研究

为了满足当前精密仪器对压电马达小尺寸,大扭矩的要求,设计了一种倾斜式压电低频马达,这种马达不仅节约成本,且能由低频电源驱动,使用范围比高频压电马达广泛。该文研究了这种马达驱动能力形成的机理,建立了驱动结构的动力学模型,根据试验研究的需要制作了样机,并对样机进行了实验测试,完成了输入频率对输出转速和输出扭矩影响的实验研究。结果表明,新型低频压电马达在输入频率为290Hz时性能最优。