X波段三维异构片式收发SiP模块设计

采用硅基三维异构集成技术,在极小的体积内,将多个微波单片集成电路(MMIC)和无源功分网络一体化集成,实现了一种X波段4通道片式收发系统级封装(SiP)。该SiP由2个体硅堆叠封装(PoP)而成,不同封装通过球栅阵列(BGA)方式互连,单层封装的内部腔体上下面均贴装芯片,封装内部采用硅通孔技术(TSV)实现垂直互连,SiP尺寸为14 mm×14 mm×3.2 mm。测试结果表明,在8~12 GHz内,SIP 4个通道的发射饱和输出功率≥30.5 dBm,接收增益≥24.5 dB,噪声系数≤3 dB,接收输入P_-1≥-26 dBm,同时具备6位数控移相和6位数控衰减功能,重量约1 g,可广泛用于微波收发系统。     

高温超导Ni-W基带的织构研究

涂层超导是目前国际超导界的研究热点和重点,所采用的韧性金属基带多为Ni和Ni-W合金.本文采用粉末冶金方法制备了Ni-3 at.%W和Ni-5 at.%W合金.利用轧制辅助双轴织构基带(RABiTS)技术制备了Ni-W合金基带,系统研究了Ni-W合金形变和再结晶织构转变规律.研究表明:通过大变形量的冷轧和高温再结晶退火,可以得到强立方织构的Ni-W合金基带.     

纳米纤维素/聚乳酸全绿色纳米复合材料的制备及性能

制备得到纳米纤维素(NC),其为横向尺寸20~40 nm、长度400~2000 nm的纳米丝.对NC进行醋酸酯化疏水改性得到醋酸酯化纳米纤维素(ANC).分别将NC和ANC与聚乳酸(PLA)复合制备纳米复合材料,研究了NC添加量、疏水改性及与PLA的复合方式对PLA力学性能和结晶性能的影响规律.结果表明,采用溶液浇铸法制备纳米复合膜时,ANC在PLA基体中的分散性优于NC,但是对于复合膜拉伸性能的改善不明显.DSC等温结晶结果表明,ANC可以提高PLA的结晶度和结晶速率;采用熔融复合法制备的NC/PLA纳米复合材料,不仅保持了PLA的高强度、高模量和较高的热稳定性,而且显著改善了其韧性,当NC添加量为3.5%(质量分数)时,断裂伸长率比纯PLA提高了12.1倍.     

First principles study on lattice vibration and electrical properties of layered perovskite Sr_2M_2O_7(M=Nb,Ta)

In this paper, we performed calculations to investigate the dielectric, piezoelectric properties, Born effective charge(BEC), and spontaneous polarization of Sr_2M_2O_7, the method used in our study was a well-known density functional theory based on first-principles. The optimized results were in good agreement with previous experiments and calculations,which indicates that our calculated method is reasonable. The research we have done suggested that greater piezoelectric components of Sr_2Nb_2O_7 were e_(31) and e_(33), and the contributions were derived from the A_1. By studying the Born effective charge, it could be seen that the valence of ions changed, and the O of Sr_2Nb_2O_7 were most obviously that caused by the covalent character of ions and the hybridization of O-2 p and Nb-4 d. The spontaneous polarization of Sr_2Nb_2O_7 in the [001]direction is 25 μC/cm~2, while for Sr_2Ta_2O_7, there was no spontaneous polarization in the paraelectric state. Finally, the effect of pressure on the piezoelectric properties were also investigated, the polarization of Sr_2Nb_2O_7 decreased linearly with the increase after pressure. All our preliminary results throw light on the nature of dielectric, piezoelectric properties,Born effective charge, and spontaneous polarization of Sr_2M_2O_7, it was helpful for experimental research, the development of new materials, and future applications.     

Excellent acetone sensing properties of porous ZnO

Porous Zn O was obtained by hydrothermal method.The results of scanning electron microscope revealed the porous structure in the as-prepared materials.The acetone sensing test results of porous Zn O show that porous Zn O possesses excellent acetone gas sensing properties.The response is 35.5 at the optimum operating temperature of 320?C to 100 ppm acetone.The response and recovery times to 50 ppm acetone are 2 s and 8 s,respectively.The lowest detecting limit to acetone is 0.25 ppm,and the response value is 3.8.Moreover,the sensors also exhibit excellent selectivity and long-time stability to acetone.     

基于Infinite integral的四象限探测器光斑位置检测算法

为了进一步提高基于四象限探测器的半主动式激光导引头的目标定位精度,本文以高斯分布的圆形光斑作为入射光斑模型,提出了一种基于Infinite integral拟合方法的改进算法(GII)。在Infinite integral拟合算法的基础上,考虑了外部光能和死区带来的误差影响,采用最小二乘法获得最佳拟合的解析表达式。为了简化算法的计算量,对部分解析表达式进行分段式多项式拟合,优化拟合区间,并得到GII算法的解析表达式。GII算法相较于传统Infinite integral拟合算法和8次多项式拟合法,精度大幅度提升。仿真和实验表明,该算法在确保良好实时性的同时,能增加四象限探测器的有效探测范围,提高不同光斑半径下四象限探测器的定位精度,为战场环境下精准激光制导武器的发展提供了理论参考。     

Schiff碱吡啶-2-甲醛缩氨基脲铅(Ⅱ)配合物的合成和晶体结构

缩氨基脲(或含硫)希夫碱及其配合物具有抗病毒、抗菌、抗麻风病等生物活性[1-3],因而引起了人们极度大的关注[4-6]。为了拓宽缩氨基脲及其配合物的研究领域,进一步了解该类化合物的结构特征,本文报道了Schiff碱吡啶-2-甲醛缩氨基脲铅(Ⅱ)配合物的合成和晶体结构。1实验部分1·1试剂和仪器吡啶-2-甲醛、盐酸氨基脲、硝酸铅、乙醇、乙酸钠等均为分析纯。VarioEL元素分析仪(德国ELEMENTAR公司),美国N icolet 50XB傅立叶红外光谱,AVANCE AV500MHz核磁共振仪,R igaku Mercury CCD衍射仪。1·2希夫碱吡啶-2-甲醛缩氨基脲(PNS)的合成…     

Schiff碱吡啶-4-甲醛缩氨基脲钴(Ⅱ)配合物的合成及其晶体结构

由Co(C lO4)2.6H2O和Sch iff碱吡啶-4-甲醛缩氨基脲反应合成了标题化合物[Co(H4FoPyS)2(H2O)4](C lO4)2.2H2O(1,H4FoPyS为Sch iff碱吡啶-4-甲醛缩氨基脲),其结构经IR,单晶X-射线衍射和元素分析表征。1属三斜晶系,空间群P,īa=6.9015(13),b=10.2030(19),c=11.136(2),α=104.960(3)°,β=90.090(3)°,γ=108.177(4),V=716.9(2)3,Dc=1.613 mg.m-3,Z=1,Mr=696.29,μ=0.868 mm-1和F(000)=359,最终偏差因子分别为R1=0.0857和wR2=0.2361。在1的晶体结构中,Co(Ⅱ)是六配位的稍变形八面体构型,其中2个吡啶氮原子和2个配位水分子占据赤道平面,另外2个配位水分子处于轴向位置。配合物分子通过氢键(N-H┈O和O-H┈O)相连,形成三维超分子网状结构。     

惰性气体原子与HF分子相互作用的分子形貌动态研究

研究了惰性气体原子(Rg=He,Ne,Ar和Kr)分别向HF分子两端原子接近过程中分子形貌的动态变化,使用MELD精密从头算方法中的CISD/6-311++G(2d,2p)方法,计算了FH-Rg和HF-Rg2个二聚体的单电子作用势、分子平面的边界轮廓以及相应界面上的电子密度.研究表明,惰性气体原子Rg分别向HF的两端接近时,双方的外形在接近的方向上均有伸手欢迎的表示,分子的前沿电子密度也相应的发生变化,对惰性键提供了一种新的认识.