H^＋离子与Li（5f）碰撞单俘获过程理论研究

利用经典径迹蒙特卡罗研究了H^＋离子与Li（5f）碰撞单俘获过程，分析了不同碰撞速度时截面随末态主量子数n变化的分布行为，截面随末态n变化的分布中存在一个明显峰值，此峰值对应的n随碰撞速度变化不是很明显．同时还计算了不同碰撞速度下，截面随末态角量子数l变化的规律，在截面随角量子数l变化的分布中，存在一个最大峰值，此峰值对应的角动量为lmax，lmax随着碰撞速度的增加而减小，由于l≤n-1的限制，从而使l的分布有两种不同的行为．     

肽类树枝状大分子:自组装胶束及药物释放研究

本文以三代聚谷氨酸肽类树枝状分子(G3-Glu)为大分子引发剂,引发N-羧基-L-苯丙氨酸-环内酸酐(NCA-Phe)的开环聚合反应,制备聚谷氨酸树枝状大分子-聚苯丙氨酸嵌段共聚物.嵌段共聚物通过自组装形成以聚苯丙氨酸链段为核,聚谷氨酸树枝状大分子为壳的胶束.将抗肿瘤药物阿霉素负载到高分子胶束中,研究其药物释放性能及体外抗肿瘤效果.结果表明,共聚物胶束具有良好的生物相容性.载药胶束具有药物缓释效果,药物持续释放时间可达60h.载药胶束的体外抗肿瘤实验表明其对肝癌细胞HepG2具有很好的杀灭效果,共培养48h后对癌细胞的杀死率可高达75%.     

Smooth and Peaked Solitary Wave Solutions of the Broer–Kaup System Using the Approach of Dynamical System

The bifurcations of traveling wave solutions of the Broer–Kaup system are investigated and all possible exact parametric representations of the smooth and peaked solitary waves are presented.     

Configuration optimization of laser guide stars and wavefront correctors for multi-conjugation adaptive optics

Multi-conjugation adaptive optics(MCAOs) have been investigated and used in the large aperture optical telescopes for high-resolution imaging with large field of view(FOV).The atmospheric tomographic phase reconstruction and projection of three-dimensional turbulence volume onto wavefront correctors,such as deformable mirrors(DMs) or liquid crystal wavefront correctors(LCWCs),is a very important step in the data processing of an MCAO's controller.In this paper,a method according to the wavefront reconstruction performance of MCAO is presented to evaluate the optimized configuration of multi laser guide stars(LGSs) and the reasonable conjugation heights of LCWCs.Analytical formulations are derived for the different configurations and are used to generate optimized parameters for MCAO.Several examples are given to demonstrate our LGSs configuration optimization method.Compared with traditional methods,our method has minimum wavefront tomographic error,which will be helpful to get higher imaging resolution at large FOV in MCAO.     

A high precision phase reconstruction algorithm for multi-laser guide stars adaptive optics

Adaptive optics(AO) systems are widespread and considered as an essential part of any large aperture telescope for obtaining a high resolution imaging at present.To enlarge the imaging field of view(FOV),multi-laser guide stars(LGSs) are currently being investigated and used for the large aperture optical telescopes.LGS measurement is necessary and pivotal to obtain the cumulative phase distortion along a target in the multi-LGSs AO system.We propose a high precision phase reconstruction algorithm to estimate the phase for a target with an uncertain turbulence profile based on the interpolation.By comparing with the conventional average method,the proposed method reduces the root mean square(RMS) error from 130 nm to 85 nm with a 30% reduction for narrow FOV.We confirm that such phase reconstruction algorithm is validated for both narrow field AO and wide field AO.     

氨水介质中含Ti的MCM-41介孔分子筛的合成

 在氨水介质中采用TiCl3和正硅酸乙酯合成了含Ti量不同的MCM-41介孔分子筛. 该方法可避免使用昂贵的辅助模板剂,也不需要加入醇来调节水解速度,因而合成过程相对简单、易于控制. 采用XRD和N2吸附-脱附等技术对介孔分子筛的结构进行了表征. 结果表明,合成的MCM-41介孔分子筛的六方介孔有序性好,结晶度高. UV-Vis光谱表明,Ti-MCM-41在200～300 nm间出现了四个清晰可辨的吸收峰,说明Ti原子以多种状态存在于介孔分子筛骨架中.     

硝酸咪康唑的合成工艺改进

2,4-二氯-α-氯代苯乙酮(1)与咪唑进行N-烷基化反应制得α-(1-咪唑基)-2,4-二氯苯乙酮(2);2经硼氢化钾还原得α-(1-咪唑基)-2,4-二氯苯基乙醇硼络合物(3);3直接与2,4-二氯氯苄进行O-烷基化反应合成了硝酸咪康唑(4). 2和4的结构经1H NMR, 13C NMR, IR和MS表征.用正交试验优化了合成2的工艺条件.在最佳反应条件[1＝50 mmol, n(1) ∶ n(咪唑) ∶ n(三乙胺)=1.0 ∶ 1.2 ∶ 1.2,以苯为溶剂,于70 ℃反应1.5 h]下,2的收率达90.4%.4的总收率为68.2%.     

Finite element analysis of ionic liquid gel soft actuator

A new type of soft actuator material-ionic liquid gel(ILG),which consists of HEMA,BMIMBF4,and TiO_2,can be transformed into gel state under the irradiation of ultraviolet(UV)light.In this paper,Mooney–Rivlin hyperelastic model of finite element method is proposed for the first time to study the properties of the ILG.It has been proved that the content of TiO_2 has a great influence on the properties of the gel,and Young’s modulus of the gel increases with the increase of its content,despite of reduced tensile deformation.The results in this work show that when the TiO_2 content is 1.0 wt%,a large tensile deformation and a strong Young’s modulus can be obtained to be 325%and 7.8 k Pa,respectively.The material parameters of ILG with TiO_2content values of 0.2 wt%,0.5 wt%,1.0 wt%,and 1.5 wt%are obtained,respectively,through uniaxial tensile tests,including C_(10),C_(01),C_(20),C_(11),C_(02),C_(30),C_(21),C_(12),and C_(03)elements.In this paper,the large-scaled general finite element software ANSYS is used to simulate and analyze the ILG,which is based on SOLID186 element and nonlinear hyperelastic Mooney–Rivlin model.The finite element simulation analysis based stress-strain curves are almost consistent with the experimental stress–strain curves,and hence the finite element analysis of ILG is feasible and credible.This work presents a new direction for studying the performance of soft actuator for the ILG,and also contributes to the design of soft robot actuator.     

基于Z变换的局部匀速运动模糊图像恢复算法

针对背景不变的局部匀速运动模糊图像复原问题,提出一种基于Z变换的恢复算法.在前景和背景色差较大的假设前提下,基于背景差方法将前景从图像中分离出来;利用旋转矩阵将前景在像平面内任意方向的运动转换成X轴方向的运动;进而把复杂的局部模糊恢复问题简化为前景模糊恢复及前景和背景融合两个子问题来解决,使求解过程得到最大程度简化;在严格的数学推导基础上建立基于Z变换的退化及恢复模型,将模型中的差分方程转化为简单的代数方程求解;仿真结果表明,提出的算法能正确、有效并且快速地恢复由于局部匀速运动所造成的图像退化;算法对模糊宽度的变化不敏感,较维纳滤波恢复算法有一定的稳健性、优越性.     

人体肿瘤组织的光谱识别

本文对人体胃肿瘤组织和正常组织的激光诱导荧光光谱进行了研究。结果表明：对于肿瘤组织，其光谱的强度和形状都不同于正常组织，对肿瘤组织区分的符合率为８９％，对正常组织区分的符合率为９１％。另外，还对病人的胃肿瘤组织进行了光谱实时测定。