CRYSTAL STRUCTURE OF NEODYMIUM（Ⅲ）COMPLEX WITH1，2，4—BENZENETRICARBOXYLIC ACID

<正> [NdC6H3(COO)3(H2O)3]·H2O, Mr=423. 45, orthorhombic,space groupP212121,a=6. 120(3) ,b=9. 719(2) ,c=20. 133(8) A ,V=1197. 5A3.Z = 4,F (000) = 820,DC=2. 35g/cm3,μ(Moka) = 44. 1cm-1.The final R = 0. 0278 and Rw= 0. 0270 for 1760(I>3σ(I)) observed unique reflections. The neodymium ion is nine-coordinated by six oxygen atoms of carboxylato groups from four 1, 2, 4-benzenetricar-boxylates and three aqua molecules,forming a distorted monocapped square antiprism. The Nd -O distances fall in the range of 2. 41 - 2. 70A with an average of 2. 51A     

用Monte-Carlo方法研究八面沸石的脱铝过程

八面沸石中的骨架铝可按其环境次邻位上出现的铝数分为4类。环境无次邻铝的铝离子形成分子筛的强酸中心;周围有1至3个次邻铝的铝离子形成的酸中心酸性较弱,与前者相比易于从骨架上解脱。基于一级动力学近似,用Monte-Carlo方法模拟八面沸石脱铝过程,得到4种类型铝离子的数目随硅铝比改变而演化的规律。预计硅铝比在6.68附近,脱铝八面沸石中的强酸中心数目达到极大值;如果强、弱酸中心铝离子的解脱速率差别较大,则脱铝八面沸石中强酸中心浓度较高。 关键词：     

DETERMINATION OF BRANCHING DISTRIBUTION IN HIGH cis-1,4-POLYBUTADIENE BY GPC AND AUTOMATIC VISCOMETRY

Based on the methods reported by Ambler and Kraus, a method has been developed for the determination of long-chain branching distribution in polymers by the combined use of GPC and intrinsic viscosity data of polymer fractions. In this method, g_i, λ_i, G_i, m_i, the weight percentage of polymer that is branched, etc. can be used simultaneously to characterize the distribution, degree and content of branching in polymers. Some relations between molecular weight polydispersity and branching polydispersity in Nickel-based high cis-1,4-polybutadiene samples are discussed. It was found that the number of long branches λ. per unit molecular weight is a function of molecular weight and all of the samples are highly branched at a molecular weight of about 10~6.     

现代移动通信网络安全分析

网络安全作为移动通信系统发展的关键影响因素一直是通信领域的专家和学者研究的重点和热点。文章对移动通信系统安全技术进行了简要分析,同时分析了提高移动通信系统网络安全性的研究要点,并相应给出一些策略。     

PTN技术体制下的QoS技术服务探究

PIN体制下,QoS服务模型的合理选择可以提高网络服务的效率,利用一系列的模式组合与实现,可以打造更加细致化的网络服务体系,实现持续发展.     

基于足球赛事现场PQC方式的画面控制——2016中超联赛PQC运营的思考

制作质量管理(Production Quality Control,简称PQC),是在既有技术质量管理体系的基础上,以视觉为切入,将主、客观评价体系有机结合,精益化分析各工种间的影响要素,逐步梳理工作界面、优化机制和流程的对于节目质量合理控制的机构.本文简要阐述了SMG作为中超联赛PQC建设和运营的总体现状、规划思路与主要举措,并结合具体比赛效果对具体的内容进行详细的阐述.     

低温接收机功率稳定度自动测量及数据处理的研究

低温接收机功率稳定度是表征低温接收机性能的主要指标之一,它反映低温接收机本身的稳定性和其对外界各种干扰因素的敏感程度。设计具有单纯环境的自动测量技术并在时域范围采用阿伦方差的方式对测量数据进行处理,计算得出低温接收机不同时间间隔的功率稳定度。该方法经过延伸后可用于测量低温、常温放大器等组部件,具有较好的实践性。     

A picosecond widely tunable deep-ultraviolet laser for angle-resolved photoemission spectroscopy

We develop a picosecond widely tunable laser in a deep-ultraviolet region from 175 nm to 210 nm,generated by two stages of frequency doubling of a 80-MHz mode-locked picosecond Ti:sapphire laser.A β-BaB2O4 walk-off compensation configuration and a KBe2BO3F2 prism-coupled device are adopted for the generation of second harmonic and fourth harmonics,respectively.The highest power is 3.72 mW at 193 nm,and the fluctuation at 2.85 mW in 130 min is less than ±2%.