THE CATALYTIC EFFECTS OF OXYGEN AND AMINES IN THE REDOX-INITIATED DIMERIZATION OF N-VINYLCARBAZOLE*

The redox reaction between N-vinylcarbazole (NVC) and various oxidants including Ce(Ⅳ), Fe(Ⅲ)and benzoylperoxide in methanol proceeds via the initial formation of the NVC N-cation radical which in turn leads to the formation of the NVC cyclic dimer, trans-1,2-dicarbazylcyclobutane. Molecular oxygen and a few arylamines are able to accelerate the rate of the formation and increase the yield of the dimer. The mechanism of this process and the functions of oxygen and arylamines are presented as follows: The participation of molecular oxygen is to facilitate the dissociation of the resulting reduced metal ion and the NVC N-cation radical ion pair or charge transfer complex, thereby releasing the free NVC N-cation radical and increase the rate of the formation and yield of the dimer. The arylamine in this reaction between NVC and oxidants can be viewed as electron transfer agent between NVC and the oxidant. Because the amines are present in small amount relative to the oxidants and can be regenerated in pr     

双频共塔中的避雷

本文以比较实际的经验简述了双频共塔中的避雷措施，较详细地分析了避雷电路改进的理由，并介绍了双频共塔避雷电路使用元件的计算方法。     

Si-Si直接键合的研究及其应用

硅片直接键合技术是一种简单易行的硅片熔合技术,由于该技术不受材料的结构、晶向和点阵参数的影响,因而得到了广泛的应用。介绍了硅片直接键合的方法和键合模型,并简单介绍了硅片直接键合技术的应用。     

软件的MTBF及其验证试验

目前国内计算机软件绝大部分没有ＭＴＢＦ指标要求，个别有指标要求的也无验证考核办法，故实际上其软件的可靠性是没有保证的。从硬件可靠性发展的经验看，软件必需有ＭＴＢＦ要求，必需切实通过验证试验后才能交付使用方。本文提出一种软件ＭＴＢＦ指标分配方法及通过软件测试平台的验证试验考核方法。对不太大的软件而言，软件测试平台可以用３８６、４８６来实现，在手段上一般不成问题。验证试验成功的前提是完整的软件任务书，     

7050航空铝合金结构材料激光冲击强化处理研究

用自行研制的激光冲击强化处理(LSP)装置对两种重要航空铝合金结构材料7050T7451，7050T7452冲击强化试验，进行了疲劳寿命对比试验。给出了反映疲劳应力水平与结构件寿命对应关系的σm-N曲线。结果表明．在67．3MPa的加载应力水平下，激光冲击处理后7050T7451结构材料的疲劳寿命提高到未经处理的435％，而7050T7452在81．4MPa的应力水平下提高到518%。并对试件进行了激光冲击处理机理的研究。结果显示试件表面具有较大的残余压应力和较高的位错密度。     

一种基于蜂窝基站的全空间自定位方法

根据双频相位差测量的双曲线定位原理，提出一种基于蜂窝基站的全空间自定位方法。该方法不需要测量精确的时间差和标淮同步的模拟脉冲。文中首先给出全空间定位的精度分布表达式，然后详细讨论了基于蜂窝基站实现全空间自定位的基站布局可能性以及实时自定位算法。仿真与原理实验表明，基于蜂窝基站自定位方法合理，基站坐标经处理后，无定位盲区、无模糊多解、无解等现象，自定位算法满足实时性和高精度的要求，其中单点定位仿真计算仅需0．13g，理论迭代误差数量级小于10^-4。     

Effects of preparation parameters on growth and properties of β-Ga2O3 film

The Ga$_{2}$O$_{3}$ films are deposited on the Si and quartz substrates by magnetron sputtering, and annealing. The effects of preparation parameters (such as argon-oxygen flow ratio, sputtering power, sputtering time and annealing temperature) on the growth and properties ($e.g.$, surface morphology, crystal structure, optical and electrical properties of the films) are studied by x-ray diffractometer (XRD), scanning electron microscope (SEM), and ultraviolet-visible spectrophotometer (UV-Vis). The results show that the thickness, crystallization quality and surface roughness of the $\beta $-Ga$_{2}$O$_{3}$ film are influenced by those parameters. All $\beta $-Ga$_{2}$O$_{3 }$films show good optical properties. Moreover, the value of bandgap increases with the enlarge of the percentage of oxygen increasing, and decreases with the increase of sputtering power and annealing temperature, indicating that the bandgap is related to the quality of the film and affected by the number of oxygen vacancy defects. The $I$-$V$ curves show that the Ohmic behavior between metal and $\beta $-Ga$_{2}$O$_{3}$ films is obtained at 900 ${^\circ}$C. Those results will be helpful for the further research of $\beta $-Ga$_{2}$O$_{3}$ photoelectric semiconductor.     

稀土元素的摩擦学研究发展概况

本文对稀土元素的摩擦学研究发展概况作了综述与讨论,主要涉及的是稀土金属及稀土无机化合物和稀土配合物作为润滑油、脂及润滑涂层的添加剂的摩擦学特性,并对稀土无机化合物的高温润滑特性、稀土金属及其化合物在高温涂层中的应用作了简要讨论,最后还提出了稀土的摩擦学研究中当前值得注意的几个重要课题。     

基于LAMP的WEB服务器安全架构

本文分析了网络系统中WEB服务器面临的安全威胁,提出了基于LAMP平台的WEB服务器安全架构,通过对Linux操作系统、Apache服务器、MYSQL和PHP的安全策略配置,以及构建Snort入侵检测系统、netfilter/iptables防火墙和Cacti监控系统,实现了对WEB服务器的全方位安全防护。