高氯酸锂在有机溶剂中离子溶剂化和离子缔合的红外光谱研究

利用红外光谱技术研究了LiClO4在碳酸丙烯酸,γ－丁内酯和碳酸二乙酯中的离子缔合和离子溶剂化。溶剂分子谱带的变化证明,锂离子与溶剂分子的相互作用主要是通过羰基氧原子进行的,醚氧也可能参与了相互作用,高氯酸锂的v1和v4谱带变化则证明了溶液中离子对的存在,而离子对的种类与溶剂分子的特性有关。     

不同驱动力下瓦斯水合物生长过程Raman光谱特征

基于煤矿瓦斯(CH₄∶C₂H₆∶N₂=67.5∶22.5∶10)水合物相平衡曲线开展四种驱动力ΔP水合动力学实验,利用可见显微Raman光谱仪获取水合物生长过程光谱图,根据水合物相中C₂H₆ C-C键伸缩振动特征峰Raman位移确定了4组实验中水合物为sⅡ结构。基于van der Waals与Platteeuw模型获取瓦斯水合物生成过程中水合物相气体组分及水合指数变化规律。研究表明： 驱动力的大小影响水合物的稳定性,随着驱动力的增加,CH₄相比C₂H₆逐渐占据更多的孔穴结构,CH₄在水合物相内比例增加,水合物稳定性越强;瓦斯中N₂,CH₄和C₂H₆进入水合物孔穴优先级可以通过分子与水合物孔穴的直径比进行确定,分析认为在sⅡ水合物结构中小孔穴CH₄优先级最高,大孔穴C₂H₆最高;基于瓦斯水合物稳定性,对水合物生长过程客体分子的物质传递规律进行描述,为瓦斯水合物的微观生长提供理论基础。     

Study of the beam loading effect in the CSNS/RCS

The China Spallation Neutron Source/Rapid Cycling Synchrotron (CSNS/RCS) accelerates a high-intensity proton beam from 80 MeV to 1.6 GeV. Since the beam current and beam power is high, the beam loading is a severe problem for the stability of the circulating beam in the RCS. To study the beam loading effect in the CSNS/RCS theoretically, the RLC circuit model of the rf cavity, the method of Fast Fourier Transform and the method of Laplace transform have been employed to obtain the impedance of the rf system, the beam spectrum and the beam-induced voltage, respectively. Based on these physical models, the beam dynamics equations have been revised and a beam loading model has been constructed in the simulation code ORIENT. By using the code, the beam loading effect on the rf system of the CSNS/RCS has been investigated. Some simulation results have been obtained and conclusions have been drawn.     

互泵浦相位共轭器的阈值耦合强度的分析

从理论上计算具有两个作用区的互泵浦相位区轭器的阈值耦合强度（γＬ）ｔｈ，给出了（γＬ）ｔｈ与输入光强比ｑ、光折变晶体内部通道强度传输系数Ｔｔ的规律。     

M+AsF6-(M=Li,Na,K,Rb和Cs)离子对的结构和振动光谱

利用abinitio计算方法研究了AsF6-阴离子和M AsF6-(M =Li ,Na ,K ,Rb 和Cs )直接接触离子对的结构和光谱行为。结果表明,具有C3V结构三齿相互作用的M AsF6-最稳定,二齿配位的结构只有在特定条件下才可能稳定存在。当形成离子对后,阳离子与AsF6-的相互作用将改变AsF6-的结构,这其中Li 的影响最大。另外,AsF6-光谱的变化可用来指认溶液中离子的缔合和离子对的种类。     

自聚焦透镜的薄透镜等效系统

本文分析了自聚焦透镜的成象特性,提出了用薄透镜系统等效自聚焦透镜的方法,这种方法给用几何作图法和解析法求解物象关系带来了很大方便。     

Synchronization of the fractional-order generalized augmented L u¨system and its circuit implementation

In this paper, the synchronization of the fractional-order generalized augmented Lu¨ system is investigated. Based on the predictor–corrector method, we obtain phase portraits, bifurcation diagrams, Lyapunov exponent spectra, and Poincare′maps of the fractional-order system and find that a four-wing chaotic attractor exists in the system when the system parameters change within certain ranges. Further, by varying the system parameters, rich dynamical behaviors occur in the2.7-order system. According to the stability theory of a fractional-order linear system, and adopting the linearization by feedback method, we have designed a nonlinear feedback controller in our theoretical analysis to implement the synchronization of the drive system with the response system. In addition, the synchronization is also shown by an electronic circuit implementation for the 2.7-order system. The obtained experiment results accord with the theoretical analyses,which further demonstrate the feasibility and effectiveness of the proposed synchronization scheme.     

激光偏振性的量子理论与实验研究

本文建立了激光偏振性的全量子理论。分析了各向异性腔中多模运转下激光束的偏振特性。给出He-Ne激光器在6328振荡谱线上各模相互间角度随各向异性变化的基本方程、计算曲线及偏振组态。本文还给出了由应力导致相位各向异性对模式偏振性影响的实验结果。理论分析与实验结果相符。     

半导体激光器脉冲调制理论分析

本文用龙格-库塔法求解高斯脉冲调制下半导体激光器速率方程,对结果进行了分析。推出了较高偏置直流和高斯脉冲调制下计算激光脉冲延迟时间、脉冲宽度和最大调制码率的公式。给出了调制畸变的实验结果。     

致密微孔壁绝热冷却效果研究

本文采用经热电偶标定的红外热像表面温度测量技术,实验研究了吹风比M(M=0．30-1．59)对致密微孔壁热侧壁面上绝热冷却效果ηaw的影响,并与数值模拟结果进行了比较。实验与数值模拟的结果都表明:与常规气膜冷却在M≥1．0时ηaw随着M增大而减小的现象不同,致密微孔壁的ηaw随着M增大逐渐增加的,但随着M的增大,ηaw增加的幅度越来越小。在相同的吹风比M下,致密微孔壁的绝热冷却效果ηaw明显高于常规气膜冷却的ηaw。