氧化钴溶胶复合酚醛树脂的热解碳结构变化

以乙醇为介质将制备的氧化钴溶胶与酚醛树脂进行复合,经固化后在埋炭条件下炭化处理,制备热解碳。借助场发射扫描电镜、高分辨率透射电镜、X射线衍射仪等手段对热解碳的晶体结构、显微结构进行了分析表征。结果表明：氧化钴溶胶粒子在酚醛树脂中以纳米尺寸均匀分散,复合树脂热解过程中氧化钴被还原为单质钴,从而对树脂热解过程起到了催化作用,使其由无定形玻璃态碳部分转变为石墨化碳。对热解碳的显微结构分析表明,热解碳中有大量的碳纳米管生成,其含量、形貌与氧化钴溶胶掺杂量有关。     

基于多项式内插的MIMO时间-频率双选择性信道的信道估计

数据的高速率传输以及终端的高速移动,导致无线通信信道具有时间选择性与频率选择性两个特征。该文主要研究了数据分组传输方式下,基于导频符号辅助调制(PSAM)的多输入多输出(MIMO)时间-频率双选择性信道的信道估计问题。首先,将时间-频率双选择性MIMO信道,建模为一个随时间变化的多项式内插信道模型;然后,根据信道Doppler衰落速率、多项式模型中的误差项,确定出模型的阶数以及整个数据块的长度;最后,基于该多项式内插信道模型,提出了采用PSAM的MIMO双选择性信道估计方法。实验结果表明该算法在时间-频率双选择性衰落信道下具有较好的性能。     

数字调幅广播中多级编码的译码方案

数字调幅广播采用了基于码率匹配的删除卷积码的多级编码调制技术,结合 OFDM信道估计,研究了其译码方案。提出基于软判决的并行译码、多级译码和迭代多级译码 3种译码方案,仿真了其在长、中、短波段各信道的性能。试验结果表明,迭代多级译码方案性 能最优,但从实现的复杂度和性能改善程度来看,在AWGN信道采用迭代多级译码方案,中短 波信道采用多级译码方案更合适。     

Syntheses and Characterization of Half—Sandwich Zirconium Complexes with Dichalcogenolate o—Carborane Ligands

Metallocene complex Cp2^ttZrCl2(Cp^tt=η^5-1,3-^tBu2C5H3)(1)has been prepared from the reaction of LiCp^tt with ZrCl4 in good yield.Reactions of 1 with dilithium dichalcogenolate o-carboranes afforded new type of half-sandwich compounds with dichalcogenolate o-carboranyl ligands,[Li(THF)4][Cp^ttZr(E2C2B10H10)2](E=S,2a;E=Se,2b)in which only one cyclopentadienyl ring ligand existed.Complexes 1 and 2a were structurally characterized by X-ray analyses.In complex 2a,the Zr(IV)ion is η^5-bound to one 1,3-ditert-cyclopentadienyl ring and σ-bound to four μ2-sulfur atoms of two dithio-carboranes.the zirconium atom and four sulfur atoms form a distorted pyramid.The coordination sphere around the zirconium atom resembles in a piano stool structure with four legs of sulfur stoms and the fulcrum at the zirconium stom.     

Quantum confinement effect in <Emphasis Type="Italic">β</Emphasis>-SiC nanowires

The quantum confinement effect is important in nanoelectronics and optoelectronics applications; however, there is a discrepancy between the theory of quantum confinement, which indicates that band-gap widening occurs only at small sizes, and experimental observations of band-gap widening in large-diameter nanowires (NWs). This paper reports an obvious blue shift of the absorption edge in the UV-visible absorption spectra of SiC NWs with diameters of 50–300 nm. On the basis of quantum confinement theory and high-resolution transmission electron microscopy images of SiC NWs, band-gap widening in SiC NWs with diameters of up to hundreds of nanometers is fully explained; the results could help to explain similar band-gap widening in other NWs with large diameters.     

La3+,Ce3+溶液中樟子松吸收的差异性研究

选用樟子松(Pinus sylvestris var. mongolica Litv.)为研究对象,分析其在水培条件下吸收稀土可溶态镧、铈离子(六水硝酸镧、六水硝酸铈,七水氯化镧、七水氯化铈,八水硫酸镧和八水硫酸铈)的过程,揭示樟子松修复镧、铈离子污染的机制。本研究应用吸收动力学的方法探究了樟子松在不同时间内吸收镧、铈离子的含量和速率;并通过回归分析法探究了樟子松-水培体系中吸收镧和铈离子的实测值与预测值之间的相关性。水培溶液中的镧和铈离子浓度分别设置为100, 300, 500, 1000 mg·L^-1。试验结果表明,樟子松体内的镧、铈离子含量随着水培溶液浓度升高而增加,其中,La₂(SO₄)₃, La(NO₃)₃, LaCl₃的含量范围分别为0.0014～0.0142 g, 0.0009～0.0115 g, 0.0017～0.0195 g; Ce2(SO₄)₃,Ce(NO₃     

聚苯硫醚的红外光谱研究

用红外反射光谱和X射线衍射方法研究了聚苯硫醚(PPS)在不同热处理条件下的结构和结晶度的变化,发现814cm~(-1)和804cm~(-1)峰分别对应PPS中晶态部分和非晶态部分的C-H面外弯曲振动,1067cm~(-1)～1088cm~(-1)双峰为构象敏感谱带,1067cm~(-1)峰对应无定形态链构象,而1088cm~(-1)峰对应PPS原粉的规整链构象。X射线衍射的结果进一步证实了这些结论。