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1.
The concept of control signals is fundamental to digital design. It evokes the notion of one or more signals that influence computation on other signals in a system, and regulate the behavior of the system. A formal definition of control signals is presented. It is argued that knowledge of the control signals in a complex design such as a microprocessor or a computer is crucial to the comprehension and specification of the design and that knowledge of the control signals of a design leads to a more efficient hardware implementation. The identification of control signals in two microprocessors are presented as examples 相似文献
2.
A rapid single-step method for the electrosynthesis of chloro and bromo complexes of palladium(II and IV), viz. M2[PdX4] and M2[PdX6], by the dissolution of a palladium anode in chloride or bromide containing media is described. Electrolysis of dilute HX solution in the presence of pyridine, 2,2′-bipyridyl or 1,10-phenanthroline gives rise to non-electrolytes, e.g. trans-[PdX2(py)2], [PdX2(bipy)] and [PdX2(phen)]. Anodic oxidation of palladium in HX medium in the presence of acetonitrile and benzonitrile also gives the non-electrolytes trans-[PdX2(CH3CH2NH2)2] and trans-[PdX2(C6H5CH2NH2)2], respectively. 相似文献
3.
M. Subrahmanyam S. J. Kulkarni B. Srinivas 《Reaction Kinetics and Catalysis Letters》1993,49(2):455-459
N-(2-hydroxyethyl) ethylenediamine reaction was observed over zeolite catalysts giving rise to only dehydrocyclization and over chromite catalysts showing dehydrocyclization together with dehydrogenation. The major product changes from the cyclized compound piperazine to pyrazine when the reactant is switched from zeolite to chromite catalyst. This process stands as a model reaction for characterizing lone acid sites and adjacent acid-base sites over zeolite and chromite catalysts, respectively.IICT Communication No. 3175 相似文献
4.
Some procedures for the gravimetric determination of silica in lead-bearing samples involve the extraction of lead sulphate with ammonium acetate. Results for silica are then low because some silica is dissolved in ammonium acetate solution. Correct results can be obtained only by avoiding fuming with sulphuric acid. If samples contain a large proportion of insoluble silica, preliminary fusion with sodium hydroxide is recommended. 相似文献
5.
The effect of isomeric butanols on the temperature corresponding to the adiabatic compressibility minimum of water (T β) was studied using a variablepath interferometer working at 3 MHz. The structural contribution to the shift inT β, [ΔT βstr]exp, was found to be positive and to increase with concentration to a maximum atX 2?0.0193, 0.0100, and 0.0090 fort-butanol, sec-butanol, and isobutanol, respectively. The results have been explained on the basis of stabilization of water structure at low concentrations of alcohol. The quantity [ΔT βstr]exp forn-butanol is practically zero at low concentrations, while at high concentrations it is negative, indicating rupture of the hydrogen-bonded structure of water by this solute. At any given concentration,t-butanol > sec-butanol > isobutanol >n-butanol is the order of increasing structural contribution to the shift inT β. Theoretical values of the structural contribution to the shift inT β are in good agreement with the experimental data. 相似文献
6.
Kanchi Suvardhan Kailasa Suresh Kumar Dasari Rekha Pantrangam Subrahmanyam Kapuvedi Kiran Bellum Jayaraj Surasura Ramanaiah Kandhukuri Janardhanam Pattium Chiranjeevi 《Mikrochimica acta》2007,157(3-4):237-244
Cloud point extraction was applied as a method for preconcentration of rhodium after formation of a complex with 2-propylpiperidine-1-carbodithioate
(2-PPC), and later determined by flame atomic absorption spectrometry using TritonX-114 as surfactant. Rhodium was complexed
with 2-PPC in an aqueous phase and kept for 15 min in a thermostatted bath at 40 °C. Separation of the two phases was accomplished
by centrifugation for 15 min at 4000 rpm. The chemical variables affecting the cloud point extraction were optimized and successfully
applied to rhodium determination in various water samples. Under optimized conditions, the preconcentration system (100 mL
sample) permitted an enhancement factor of 50. The detection limits obtained under optimal conditions was 0.052 ng mL−1. The extraction efficiency was investigated at different rhodium concentrations (7.0–42.0 μg mL−1), and good recoveries (96.42–99.14%) were obtained using this method. It has been applied to the determination of rhodium
in water and was compared with reported methods in terms of Student’s ‘t’-test and variance ratio ‘f’-test. 相似文献
7.
Catalytic gas-phase abatement of air containing 250 ppm of isopropanol (IPA) was carried out with a novel dielectric barrier
discharge (DBD) reactor with the inner catalytic electrode made of sintered metal fibers (SMF). The optimization of the reactor
performance was carried out by varying the voltage from 12.5 to 22.5 kV and the frequency in the range 200–275 Hz. The performance
was significantly improved by modifying SMF with Mn and Co oxide. Under the experimental conditions used, the MnO
x
/SMF showed a higher activity towards total oxidation of IPA as compared to CoO
x
/SMF and SMF electrodes. The complete destruction of 250 ppm of IPA was attained with a specific input energy of ∼235 J/L
using the MnO
x
/SMF catalytic electrode, whereas, the total oxidation was achieved at 760 J/L. The better performance of the MnO
x
/SMF compared to other catalytic electrodes suggests the formation of short-lived active species on its surface by the in-situ
decomposition of ozone. 相似文献
8.
Dmitrenok A. S. Radhika P. Anjaneyulu V. Subrahmanyam C. Subba Rao P. V. Dmitrenok P. S. Boguslavsky V. M. 《Russian Chemical Bulletin》2003,52(8):1868-1872
Sphingolipids and glycolipids including previously unknown (2S,3S,4R)-1,3,4-trihydroxy-2-(2-(R)-hydroxyoctadecanoylamino)octadec-8E-ene, (2S,3R)-1,3-dihydroxy-2-octadecanoylamino-4E,8E-hexadecadiene, and (2-hydroxy-3-hexadecyloxypropyl)--L-fucopyranoside were isolated from soft corals collected on the shelf near the Andaman Islands (Indian Ocean). The structures of all compounds were established by spectroscopic methods and chemical analyses. The lipids possessed antibacterial activity against Bacillus subtilis, Bacillus pumilus, Escherichia coli, and Pseudomonas aeruginosa and antifungal activity against Aspergillus niger, Rhizopus oryzae, and Candida albicans. 相似文献
9.
P. V. Subrahmanyam 《Monatshefte für Mathematik》1975,80(4):325-330
In this note the converses of recent fixed-point theorems due toKannan andChatterjea are obtained. An example is constructed to show that a metric space having the fixed-point property for homeomorphisms need not be metrically topologically complete. An example ofConnell is formulated in a more general perspective. 相似文献
10.
Dr. Ashok Yadav Meghamala Sarkar Dr. Sappati Subrahmanyam Atul Chaudhary Prof. Dr. Evamarie Hey-Hawkins Prof. Dr. Ramamoorthy Boomishankar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(19):4209-4213
The design of porous materials for the recognition of multiple hydrocarbons is highly desirable for the energy-efficient separation and recognition of chemical feedstock. Herein, three new iso-structural porous discrete metal–organic cages of formula {[Pd3(NiPr)3PO]4(R-AN)6} (R-AN=anilate linkers) for the selective recognition of substituted aromatic hydrocarbons are reported. The tetrahedral cages 1 , 2 , and 3 containing anilate, chloranilate, and bromanilate linkers exhibited selective encapsulation of mesitylene, o-xylene, and p-xylene, respectively, over other analogous aromatic hydrocarbons. These selective encapsulations were driven by the variations in the portal diameters present at each of these cages and their interactions with the hydrocarbon guests. These observations are supported by mass spectrometry, NMR studies, and theoretical binding-energy calculations. 相似文献