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中性载体阳离子电极膜电化学的计算机数字模拟 总被引:1,自引:0,他引:1
对中性载体阳离子电极膜3种可能的传输模式进行了数字模拟,研究了淌度、浓度、配合物稳定常数以及阴离子亲脂性对电极电位响应的影响。模拟结果对于廓清这类电极响应机理,解释有关实验现象及指导新电极设计提供了有用的信息。 相似文献
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0IntroductionThe solid-state chemistry of manganese!car-boxylate coordination polymers has received growingattention over the past few years,owing to their fasci-nating network topologies and potential application inthe field of molecular magnetism and bi… 相似文献
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A novel coordination polymer of [Sr2(4-CPOA)2(H2O)5]n (where 4-CPOA2- is 4-carboxylphenoxyacetate) has been synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The title complex belongs to monoclinic system with space group C2/c, a=2.563 9(5) nm, b=1.162 7(2) nm, c=0.742 96(15) nm, β=99.64(3)°. V=2.183 5(7) nm3, Z=4, Mr=653.60, Dc=1.988 g·cm-3, R=0.027 8, wR=0.058 1. The strontium atom has a bicapped triangular prismatic coordination geometry, involving four oxoacetate oxygen atoms, one ether oxygen atom from different 4-CPOA2- ligands and three water molecules. The strontium(Ⅱ) ions are linked by 4-CPOA2- ligands and water molecules to form a 3D network structure. CCDC: 223313. 相似文献
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对闪电时域波形的分形研究由于忽略了其频率特性,致使复杂多变的闪电过程的全部特性无法得到充分表征。针对此问题,本文将多重分形理论引入到现代谱估计中,提出了一种基于AR(auto-regressive)谱的闪电电场信号的多重分形特性分析及放电类型的识别方法。首先基于AR模型谱估计法获得闪电电场信号的功率谱,然后,通过多重分形去趋势波动分析(multifractal detrended fluctuation analysis,MF-DFA) 法验证了闪电AR谱序列具有多重分形特性,并进一步对AR谱序列的Hurst指数以及多重分形谱进行了讨论,最后将相关参数作为闪电信号的有效特征值输入支持向量机进行了云闪(intracloud lightning) 和地闪(cloud-to-ground lightning,CG) 不同放电类型的识别。实验结果表明,本文方法对云、地闪信号的有效识别率达到了94%以上,该研究成果对闪电的特性研究与自动化识别技术均具有一定的参考价值。 相似文献
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Chunliu Xu Weibo Hua Qinghua Zhang Yuan Liu Rongbin Dang Ruijuan Xiao Jin Wang Zhao Chen Feixiang Ding Xiaodong Guo Chao Yang Liangrong Yang Junmei Zhao Yong-Sheng Hu 《Advanced functional materials》2023,33(33):2302810
Na superionic conductor of Na3MnTi(PO4)3 only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn2+ ions resided in Na+ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn2+/Mn3+ and Mn3+/Mn4+ redox couples. These findings indicate that the sodium excess Na3.5MnTi0.5Ti0.5(PO4)3 cathode with Ti4+ reduction has a lowest Mn2+ occupation on the Na+ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na3.6Mn1.15Ti0.85(PO4)3 cathode achieved a high energy density over 380 Wh kg−1 (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries. 相似文献
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EstimationoflocaldensityofsolventaboutthesoluteSolvatochromicbehaviorsofspectroscopicprobesarewidelyusedtoestimatethesol-ventstrengthofsupercriticalfluids(SCF,).i-3lnthiswork,thesolvatochrondcshiftofthen-n*transitionbandforacetone(O.o37mo1.L-')insupercrihcal(SC)CO2wasde-terminedbyUVspectroscopytostUdythesolvationeffect.TheMcRae-BaylissexpressionbasedonthedielectriccontinUUInmodelgivestherelahonshipbetWeenso1vatochromicshiftandpo1arizabilityofnonPolarsolvents4-5asfollows:wherevisthewave… 相似文献
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With the aid of matrix theory and computer a series of data can be obtained such as the total number of localities in which r species of graptolites appears, the common number of localities in which both i and j species of graptolites appear, the total number of species of graptolites in one locality, the common number of species of graptolites found in both i and j localities, the total number of zones in which r species of graptolites appears, the common number of zones in which both i and j species appear, the total number of species of graptolites found in one zone, the common number of species of graptolites found in both i and j zones. Based on these data a common problem in biostratigraphy may be solved, that is, in the absence of the zonal graptolite which species of graptolites can be chosen to replace the zonal graptolite, or how to detect the zonal graptolite of a graptolite biozone. The result of matrix treatment not only detects the graptolite biozone but is useful to infer the paleo-biogeo 相似文献
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1INTRODUCTIONTheorganicaromaticcarboxylatemetalcom-plexeshavearousedmuchattentionandbeenwidelyinvestigated.However,thestrategyofdesignandsynthesisofthesecomplexesismostlyfocusedonrigidligands,suchasterephthalicacidandbenzenetricarboxylicacid,etc.[1~5].Theassemblyofcom-plexesbyusingflexiblearomaticcarboxylateli-gandsisfarlessdeveloped[6,.Phenylenedioxydia-7]ceticacids(bdoaH2)withbiologicalactivitiesandwideapplicationsinagriculture[8]areafamilyofmultidentateflexibleligandswithversatilebind… 相似文献