电解质-非电解质-水体系溶解度的热力学关联

通过对计算电解质水溶液的过剩自由焓GW^EX、非电解质水溶液的过剩自由焓GS^EX及电争质从电解质水溶液转移到非电解质水溶液中的转移自由焓△Gtr^EX，建立了一个通用的电解质一含水混合溶剂体系的热力模型，适用于非电解质浓度较高的体系，并应用该模型对一些体系的相平衡数据进行了关联，结果较好。     

电离层斜向返回探测系统中的DSP设计

研制了一个应用于电离层斜向返回探测的实时同步信号处理系统 该系统采用间隔收发体制 ,无探测盲区 ,比STUDIO系统探测精度更高、速度更快、距离更远 ,并且软件化程度更高 ,适应性更强     

互耦系数误差与通道幅相误差的等效关系

从天线阵列互耦补偿的理论出发，导出了互耦系数误差与接收通道幅相 误差的等效关系。理论分析表明，互耦系数误差引起的通道幅相误差与阵列单元数和互耦系数的方差成正比；利用互耦系数矩阵能补偿因互耦造成的误差，但补偿效果依赖于互耦系数的精度，要实现低副瓣并有效地进行互耦补偿，必须准确测量或计算出天线阵的互耦系数。     

过渡金属TM(V,Cr,Mn)掺杂ZnS的电子结构和磁性

采用基于密度泛函理论(DFT)的第一性原理赝势平面波方法,对过渡金属V、Cr、Mn 掺杂ZnS的超晶胞体系进行了几何结构优化,计算了晶格常数、电子结构与磁学性质。研究结果表明：掺入V,Cr后,ZnS表现出明显的半金属性,而掺入Mn后,半金属性不明显;掺入过渡金属TM(V,Cr,Mn)后系统产生的磁矩主要有杂质的3d态电子贡献,且磁矩的大小与过渡金属的电子排布有关。     

交错圆盘的滚动轨迹

研究对称交错圆盘在水平面上的无滑滚动.给出了交错圆盘的质心坐标和转动矩阵的表达式.讨论了滚动周期长度与圆盘交错的关系.画出了圆盘与地面接触点和交错线段中点的轨迹.     

局域网中网络拥塞的成因分析及改进策略

局域网中网络拥塞问题对于大规模的上机考试来说是十分严重的，发生的可能性也比较大，涉及的环节多，原因复杂，加上条件限制，分析处理有一定难度。针对上机考试中的网络拥塞现象进行了分析，并提出了改进策略。     

椭圆偏振光谱技术的腐蚀研究应用

椭圆偏振光谱技术是一种高度灵敏、非破坏性的原位实时表征技术,可获取腐蚀过程“电极材料-介质”界面的动态变化信息,因此在腐蚀研究中得到了广泛应用. 本文结合解析椭圆偏振光谱数据所采用的光学模型的发展,介绍了近年来椭圆偏振光谱技术在腐蚀研究中的典型应用,并分析了该技术的发展趋势.     

应用交互叠层空穴传输层的高效铕配合物发光二极管

制备了铕配合物有机发光二极管(OLED),为了获得Eu(DBM),bath的特征发射,在器件中引入BCP作为空穴阻挡层。通过引入交互叠层的TPD／m-MTDATA作为空穴传输层,与传统异质结器件相比,最大发光效率及最大发光亮度都有明显提高。其最大发光效率在电流密度为2．8mA/cm^2时达到3cd／A,在电流密度为170mA/cm^2时器件达到最大亮度670cd／cm^2。对BCP空穴阻挡层及TPD／m-MTDATA交互叠层改善器件性能机理亦进行了讨论。     

Rational Design of a Dual‐Reactivity‐Based Fluorescent Probe for Visualizing Intracellular HSNO

Thionitrous acid (HSNO), the smallest S‐nitrosothiol, is emerging as a potential key intermediate in cellular redox regulation linking two signaling molecules H₂S and NO. However, the chemical biology of HSNO remains poorly understood. A major hurdle is the lack of methods for selective detection of HSNO in biological systems. Herein, we report the rational design, synthesis, and evaluation of the first fluorescent probe TAP‐1 for HSNO detection. TAP‐1 showed high selectivity and sensitivity to HSNO in aqueous media and cells, providing a useful tool for understanding the functions of HSNO in biology.     

Hydrophilic modification of polyvinylidene fluoride membrane by blending amphiphilic copolymer via thermally induced phase separation

A new amphiphilic copolymer TD‐A is melt‐blended with polyvinylidene fluoride to fabricate hollow fiber membranes in order to improve the hydrophilicity and anti‐fouling property. Membrane samples with different blending ratios are prepared via thermally induced phase separation method. An optimum blending ratio of TD‐A (10 wt%) is determined by a series of characterizations to evaluate the effects of TD‐A contents on membrane properties. The hydrophilicity of the blended membrane samples increases with the increasing blending ratio, but excessive content of TD‐A in blended membranes can lead to structural defects and reduction of mechanical properties. TD‐A blended hollow fiber membrane with optimum blending ratio shows excellent bi‐continuous structure and high water flux. Membrane fouling is remarkably reduced due to the incorporation of TD‐A by static absorption and cyclic filtration tests of bovine serum albumin. Moreover, constant surface chemical compositions and stable flux during long‐term chemical cleaning demonstrate the hydrophilic stability of the blended membrane.