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81.
Laser cleaning of copper roofing sheets subjected to long-lasting environmental corrosion 总被引:1,自引:0,他引:1
H. Garbacz E. Fortuna J. Marczak M. Strzelec A. Rycyk A. Koss J. Mróz A. Zatorska K. J. Kurzyd?owski 《Applied Physics A: Materials Science & Processing》2010,100(3):693-701
The study was concerned with the effect of the laser fluence and pulse duration on the microstructure of copper roofing of
the Wilanów Palace in Warsaw (Poland) subjected to environmental degradation since the turn 19th century. The techniques used
for the microstructure examinations included: SEM+EDS, X-ray diffraction analysis, surface profiling and colour analysis.
The measurements of colour of the laser-cleaned surfaces showed that series of 100-μs pulses offer the most effective cleaning.
It was also found that by controlling the number of laser pulses it is possible to control the roughness of the cleaned surface. 相似文献
82.
László Lázár Erika Mező Mihály Herczeg András Lipták Sándor Antus Anikó Borbás 《Tetrahedron》2012,68(36):7386-7399
A glucoronic acid-containing trisaccharide related to the antithrombin-binding DEFGH domain of heparin and its methanesulfonic acid analogues were synthesized. Trisaccharides without sulfonic acid content or possessing a sulfonatomethyl moiety at position 2 or 6 of unit F were prepared in high yields by [DE+F] couplings using the same disaccharide uronate donor, respectively. Synthesis of the trisaccharide with a 3-deoxy-3-sulfonatomethyl function was accomplished in three different pathways, from which a [D+EF] coupling and applying a non-oxidized precursor of the glucuronic acid afforded the trisaccharide in the highest yield. 相似文献
83.
A model for the differential capacitance of metal electrodes coated by solid polymer electrolyte membranes, with acid/base groups attached to the membrane backbone, and in contact with an electrolyte solution is developed. With proper model parameters, the model is able to predict a limit response, given by Mott–Schottky or Gouy–Chapman–Stern theories depending on the dissociation degree and the density of ionizable acid/base groups. The model is also valid for other ionic membranes with proton donor/acceptor molecules as membrane counterions. Results are discussed in light of the electron transfer rate at membrane-coated electrodes for electrochemical reactions that strongly depend on the double layer structure. In this sense, the model provides a tool towards the understanding of the electro-catalytic activity on modified electrodes. It is shown that local maxima and minima in the differential capacitance as a function of the electrode potential may occur as consequence of the dissociation of acid/base molecular species, in absence of specific adsorption of immobile polymer anions on the electrode surface. Although the model extends the conceptual framework for the interpretation of cyclic voltammograms for these systems and the general theory about electrified interfaces, structural features of real systems are more complex and so, presented results only are qualitatively compared with experiments. 相似文献
84.
Cholesterol-oleate-doped polymer-dispersed liquid-crystal voltage-controlled ring projector 总被引:1,自引:0,他引:1
Olivares-Pérez A Pérez-Cortéz M Juãârez-Pérez JL Treviã O-Palacios CG 《Optics letters》2002,27(12):1022-1024
We report a cholesterol-oleate-doped polymer-dispersed liquid-crystal (PDLC) device that, under laser illumination, exhibits a ring diffraction pattern, the radius of which is controlled by an externally applied voltage. This effect is accurately explained by modeling of the random distribution of spiral cells shown in the microstructure with a voltage-dependent shape variation. 相似文献
85.
O. Çakır İ. T. Çakır H. Duran Yıldız R. Mehdiyev 《The European Physical Journal C - Particles and Fields》2008,56(4):537-543
We study the single production of fourth-family quarks through the process pp→Q′jX at the Large Hadron Collider (LHC). We have calculated the decay widths and branching ratios of the fourth-family quarks
(b′ and t′) in the mass range 300–800 GeV. The cross sections for the signal and background processes have been calculated in a Monte
Carlo framework. It is shown that the LHC can discover single t′ and b′ quarks if the CKM matrix elements |V
t′q
|,|V
qb′|≳0.01. 相似文献
86.
Given a Tychonov space X we can construct another space Y with the same group of homeomorphisms such that X and Y are, in some sense, "almost arbitrarily different". 相似文献
87.
T. Güzel S. P. Tretyakova T. Akyüz Yu. Ts. Oganessian . Bolcal P. Saritepe N. a
atay N. Kiratli 《Radiation measurements》1997,28(1-6):405-408
The fissionable elements content, particularly uranium, of the Blask Sea sediment samples obtained in 1978 and 1989 as surfacial sediments were determined by neutron radiography using solid state nuclear track detectors (SSNTDs). 相似文献
88.
89.
90.
Masanori Yoshikawa Michio Sorai Hiroshi Suga Syŭzŏ Seki 《Journal of Physics and Chemistry of Solids》1983,44(4):311-321
Heat capacity measurements have been made for six kinds of specimens prepared by different methods. Among them, Sample A exhibited a A-type ferromagnetic pahse transition at 1.347 K and a Schottky-type anomaly due to the zero-field splitting around 9K. The total entropy and enthalpy were (11.05 ± 0.04) J K?1mol?1 and (97.0 ± 0.4) J mol?1, respectively. Sample B exhibited a Sehottky-type anomaly around 0.4 K due to the ferro-magnetic dimeric coupling with as well as the Schottky-type anomaly at 9K. The total magnetic entropy and enthalpy were (11.45 ± 0.03) JK?1 mol?1 and (93.8 ± 0.8) J mol?1, respectively. The remaining samples are simple mixtures of the λ-type modification and the dimeric modification. Irrespective of the magnetic behavior at low temperatures, all the samples showed a non-magnetic first-order phase transition around 270 K. The heat capacity and entropy of this phase transition have been accounted for in terms of the Frenkel theory of heterophase fluctuation. Construction of an adiabatic-type calorimeter workable between 1.5 and 393 K has been also presented. 相似文献