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11.
1,3‐Dichloro‐tetra‐n‐butyl‐distannoxane was firstly used to catalyze the direct substitution of 9H‐xanthen‐9‐ol with indoles at room temperature to afford a class of 3‐(9H‐xanthen‐9‐yl)‐1H‐indole derivatives in good to excellent isolating yield. Moreover, other nucleophiles (such as diketone and pyrrole) could also proceed smoothly in this methodology. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
12.
氢化硝基苯合成对氨基酚中活性炭负载铂催化剂的新制备方法研究 总被引:2,自引:0,他引:2
采用不同还原剂(甲醛、甲酸、硼氢化钾和氢气),或于还原Pt(IV)过程中引入少量Pt/AC(AC:活性炭)催化剂“催化”氢气分子,制备了Pt/AC催化剂。其催化氢化硝基苯制对氢基酚的反应结果表明,制备催化剂时所用的还原剂对催化剂的活性影响很大,但对反应选择性影响较小。用甲醛、甲酸和硼氢化钾还原制成的催化剂的活性皆较高;以氢气还原制得的催化剂活性较差;采用“催化”氢气还原法,可大大提高Pt/AC催化剂的活性,与传统甲醛还原法相比,甲酸和“催化”氢气还原制备Pt/AC催化剂的方法较简便、有效。 相似文献
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集对Fuzzy格及其在格表示论中的应用 总被引:1,自引:0,他引:1
用幂集格构造了集对 Fuzzy 格(这与用整数对构造有理数集有相似之处),并用它证明了完整的软代数表示定理,即定义了到自身的映射且有最大元和最小元的格为软代数的充要条件是它与某个集对 Fuzzy 格的子格同构.这样,与分配格在幂集 Boole 格中表示相对应,软代数在集对 Fuzzy 格中有表示,在理论上是很完美的 相似文献
15.
间隔靶对射流侵彻影响的数值模拟和实验研究 总被引:3,自引:0,他引:3
对某聚能装药射流侵彻靶板的过程进行了数值模拟 ,得出其碰撞点附近应力分布与传统理论相符 ,侵彻深度与实验结果及工程计算结果基本相符 ;分别对该聚能装药侵彻连续靶和间隔靶的过程进行了数值模拟 ,数值模拟结果显示间隔靶的侵彻深度明显低于连续靶的侵彻深度 ,这说明侵彻开坑阶段的能耗侵深比远大于准定常阶段。为了验证间隔靶对射流侵彻的影响 ,用另一聚能装药分别对连续靶和间隔靶进行了侵彻实验 ,并排除了炸高的影响。实验结果也表明 ,间隔靶对射流侵彻的确存在着不利影响。还结合数值模拟及实验结果对传统的侵彻公式进行了修正。 相似文献
16.
考察了 J/ψ→π+π- π0 衰变中的 A值分布 ,所定义的 A值是一个由末态π介子动量构成的一个无量纲的量 A =(Pπ-x Pπ+y - Pπ-x Pπ+y ) /P+π P- π ,其中 Ph、Phx 与 Phy 分别表示强子 h的动量的大小、该动量沿 X轴与 Y轴方向的分量 .这里 J/ψ是由 e+e- 碰撞产生的 ,而 e+的动量方向被取为 Z轴正向 .如果实验上能够证实 A的事例平均值〈A〉不等于零 ,则存在 CP(由电荷共轭变换与空间反演变换构成的联合变换 )或者 T(时间反演变换 )破坏 .通过筛选到的 748个事例 ,测得〈 A〉=0 .0 10 39± 0 .0 146 1± 0 .0 15 2 .进而 ,对于深入研究所需的数据样本大小和可能达到的观测水平作了数值估算 . 相似文献
17.
Heterogeneous palladium catalysts anchored on functionalized silica were prepared by sol–gel methods and their catalytic properties for the oxidative carbonylation of phenol to diphenyl carbonate (DPC) were investigated. The catalysts were characterized by means of IR, XPS, EA and BET. The Pd loading in the heterogeneous catalysts and leaching in solution were detected by atomic absorption. The effects of different reaction parameters such as temperature, solvent and inorganic cocatalyst on the yield of DPC and Pd leaching were also studied. It was found that Cu2O and tetrahydrofuran (THF) were the best partners with these heterogeneous catalysts. In the presence of 3 Å molecular sieves as dehydrating agent, the heterogeneous palladium catalyst prepared from 2‐acylpyridine revealed excellent catalytic performance and stability at 110 °C for 5 h, giving 13.7% yield of DPC based on phenol and 4.0% Pd loss in solution. The heterogeneous catalyst was more active and stable compared with traditional supported Pd? C catalyst under the same reaction conditions. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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Target cell extraction coupled with LC‐MS/MS analysis for screening potential bioactive components in Ginkgo biloba extract with preventive effect against diabetic nephropathy
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Jing‐ying Qiu Xu Chen Xiao‐xiao Zheng Xiang‐lan Jiang Dong‐zhi Yang Yan‐yan Yu Qian Du Dao‐quan Tang Xiao‐xing Yin 《Biomedical chromatography : BMC》2015,29(2):226-232
A rapid and useful approach for screening potential bioactive components in Ginkgo biloba extract (GBE) with preventive effect against diabetic nephropathy (DN) was developed using mesangial cells extraction coupled with high‐performance liquid chromatography tandem mass spectrometry (LC‐MS/MS) analysis. Mesangial cells were first divided into two groups according to their treatments with high glucose or high glucose plus GBE. After incubation for 4, 8, 12, 16, 24 and 48 h, the cells were harvested and extracted with 40% acetic acid in water before LC‐MS/MS analysis. Then, 19 compounds and five metabolites were found to selectively combine with mesangial cells. Notably, compounds including quercetin and rutin were identified or tentatively characterized according to the results of retention time and MS spectra, which is highly consistent with our previous reports that quercetin and rutin are potent protective agents against glomerulosclerosis in DN. Therefore, all these results indicate that target cell extraction coupled with LC‐MS/MS analysis can be successfully applied for predicting the bioactive components in GBE with preventive effect against DN. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
20.
A Multi‐signal Fluorescent Probe with Multiple Binding Sites for Simultaneous Sensing of Cysteine,Homocysteine, and Glutathione
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Guo‐xing Yin Ting‐ting Niu Ya‐bing Gan Ting Yu Dr. Peng Yin Prof. Hai‐min Chen Prof. You‐yu Zhang Prof. Hai‐tao Li Prof. Shou‐zhuo Yao 《Angewandte Chemie (International ed. in English)》2018,57(18):4991-4994
A novel fluorescent probe was developed by integrating chlorinated coumarin and benzothiazolylacetonitrile and exploited for simultaneous detection of cysteine (Cys), homocysteine (Hcy), and glutathione (GSH). Featuring four binding sites and different reaction mechanisms for different biothiols, this probe exhibited rapid fluorescence turn‐on for distinguishing Cys, Hcy, and GSH with 108‐, 128‐, 30‐fold fluorescence increases at 457, 559, 529 nm, respectively, across different excitation wavelengths. Furthermore, the probe was successfully applied to the fluorescence imaging of endogenous Cys and GSH and exogenous Cys, Hcy, and GSH in living cells. 相似文献