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931.
J. Goschnick J. Schuricht H. J. Ache 《Fresenius' Journal of Analytical Chemistry》1994,349(1-3):203-205
A gravimetric method is presented for the easy determination of sputter erosion rates for powders, applicable also to non-conducting materials. Measurements of the erosion rates of 22 powders gave an average value of 0.4 nm/s ±50% for bombardment with 400 eV Ar+ at 1 mA/cm2. The validity of the data has been demonstrated with technical pigments and outdoor aerosol particles. 相似文献
932.
B. Hornetz H.-J. Michel J. Halbritter 《Fresenius' Journal of Analytical Chemistry》1994,349(1-3):233-235
ARXPS (angle resolved X-ray photoelectron spectroscopy) measurements are used to obtain informations about surfaces and grain boundaries. Data acquired from nanocrystalline carbidic hard coatings have been employed to establish structural models. Magnetron-sputtered coatings of TiC, SiC and TiC/SiC were examined. In such coatings, partly defective TiC nanocrystallites are surrounded by interfacial carbide. This excess carbon shows a binding state similar to that of doped graphite or fullerenes. X-ray amorphous SiC is found in the residue. On top of sputtered SiC coatings, less oxide and graphite is found as compared to TiC/SiC or TiC coatings. 相似文献
933.
Mingyang Zhao Warren T. Ford Stefan H. J. Idziak Nicholas C. Maliszewskyj Paul A. Heiney 《Liquid crystals》1994,16(4):583-599
The hexa-4-dodecyloxybenzoyl derivative 1 of azacrown [18]-N6 was originally reported to have a 'tubular' mesophase on the basis of its large central ring and 6-fold symmetry. Starting in the mesophase, annealing of 1 under a cover slip results in formation of a new crystalline phase that melts directly to an isotropic liquid at the temperature previously observed for the mesophase to isotropic transition. Thus the phase behaviour of 1 is kinetically controlled. The analogous hexa-3,4-bisdodecyloxybenzoyl derivative 2 of azacrown [18]-N6 has no kinetic limitations to its phase changes and has an enantiotropic columnar liquid crystalline phase. We have synthesized side chain copolysiloxanes with a (CH2)11 spacer and 75-84 per cent by weight of the same 4-dodecyloxybenzoyl-[18]-N6 mesogen. The polysiloxanes also display a liquid crystalline phase. 相似文献
934.
Steven Schmidt Gü nter Lattermann Ralf Kleppinger Joachim H. Wendorff 《Liquid crystals》1994,16(4):693-702
Liquid crystalline complexes with chromium, molybdenum and with tungsten as metallic centres are reported. 1,4,7-Trisubstituted 1,4,7-triazacyclononane and three carbonyl groups are coordinated in an octahedral geometry. The observed mesophases are characterized as disordered rectangular columnar of a pyramidic type. 相似文献
935.
A kinetic model is presented to describe the high temperature (1800 K < T < 3000 K) surface oxidation of particulate boron in a hydrocarbon combustion environment. The model includes a homogeneous gas-phase B/O/H/C oxidation mechanism consisting of 19 chemical species and 58 forward and reverse elementary reactions, multi-component gas-phase diffusion, and a heterogeneous surface oxidation mechanism consisting of ‘elementary’ adsorption and desorption reaction steps. Thermochemical and kinetic parameters for the surface reactions are estimated from available experimental data and/or elementary transition state arguments. The kinetic processes are treated using a generalized kinetics code, with embedded sensitivity analysis, for the combustion of a one-dimensional (particle radius), spherical particle. Model results are presented for the oxidation of a 200 μm boron particle in a JP-4/air mixture at ambient temperatures of 1400 K and 2000 K. These results include temperature and gas-phase species profiles as a function of radial distance and particle burning rates. © 1994 John Wiley & Sons, Inc. 相似文献
936.
937.
Héléne Gispert 《ZDM》2002,34(4):158-163
Evolutions of mathematical curricula in French society have been marked by the successive answers intitutions have given to the following question since one century: Why and whom teaching mathematics? Here I present two of these, one given in 1908 and one in 1967. Each symbolises a breaking period of reforms in secondary mathematics teaching in France. We will see in the two first part of this paper that they belong to two different worlds, with social, institutional, ideological and mathematical specific features. In the third part, I’ll focus on geometry, showing the effects of the different answers concerning the public and the aims of mathematical teaching. 相似文献
938.
939.
940.
S. I. Pesotskii R. B. Lyubovskii W. Biberacher M. V. Kartsovnik V. I. Nizhankovskii N. D. Kushch H. Kobayashi A. Kobayashi 《Journal of Experimental and Theoretical Physics》2002,94(2):431-433
Behavior of the de Haas-van Alphen (dHvA) oscillations depending on the angle between the magnetic field direction and the perpendicular to conducting layers in the quasi-two-dimensional organic metal α-(BETS)2 KHg(SCN)4 was studied in detail. The angular dependence of the dHvA oscillation amplitude exhibits a series of minima (at ±43.2°, ±64.6°, and ±72.0°) related to the “zero spin” effect, through which it is possible to estimate the splitting factor. An analysis of this value suggests that many-body interactions in the compound studied are either absent or at least radically weakened. 相似文献