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81.
Urbonaviciūte A Jakstas V Kornysova O Janulis V Maruska A 《Journal of chromatography. A》2006,1112(1-2):339-344
Flavonoids are an important group of natural compounds, which can prevent coronary heart disease and have antioxidant properties. Hawthorn is a well known and widely used medicinal plant due to its cardiotonic activity. Previous studies refer mostly to the HPLC analysis of the flavonoids: vitexin, quercetin, hyperoside, oligomeric procyanidins, which appear to be primarily responsible for the cardiac action of the plant. Aqueous ethanolic extracts of single-styled hawthorn (Crataegus monogyna Jacq., f.: Rosaceae Juss.) leaves and sprouts were analyzed by means of capillary zone electrophoresis (CZE). Influence of vegetation period on the extract qualitative composition and flavonoids quantities was evaluated. Sample preparation by extraction using different concentration of aqueous ethanol (40-96%, v/v) and the influence of extractant composition on the recovery of flavonoids are discussed in detail. The results obtained using CZE are compared to the results of spectrophotometric and HPLC analysis of the extracts. The effect of storage conditions of extracts (solar irradiation, temperature and duration) on degradation of flavonoids was investigated. 相似文献
82.
Boglio C Lenoble G Duhayon C Hasenknopf B Thouvenot R Zhang C Howell RC Burton-Pye BP Francesconi LC Lacôte E Thorimbert S Malacria M Afonso C Tabet JC 《Inorganic chemistry》2006,45(3):1389-1398
The incorporation of lanthanides into polyoxometalates provides entry to new classes of potentially useful materials that combine the intrinsic properties of both constituents. To utilize the [alpha1-Ln(H2O)4P2W17O61]7- species in applications of catalysis and development of luminescent materials, the chemistry of this family of lanthanide polyoxometalates in organic solvents has been developed. Organic-soluble polyoxometalate-lanthanide complexes TBA5H2[alpha1-Ln(H2O)4P2W17O61] (Ln = La(III), Sm(III), Eu(III), Yb(III)) were prepared and characterized by elemental analysis, acid-base titration, IR, 31P NMR, and mass spectrometry. The synthetic procedure involves a cation metathesis reaction in aqueous solution under strict pH control. A solid-liquid-phase transfer protocol yielded a unique species (TBA)8K3[Yb(alpha1-YbP2W17O61)2] with three ytterbium ions and two [alpha1-P2W17O61]10- polyoxotungstates. A centrosymmetric dimeric complex [{alpha1-La(H2O)4P2W17O61}2]14- was crystallized from aqueous solution and characterized by X-ray diffraction. ESI mass spectral analysis of the complexes TBA5H2[alpha1-Ln(H2O)4P2W17O61] shows that similar dimers exist in organic solution, in particular for the early lanthanides. Fragmentation in the mass spectrometer of the complexes from dry acetonitrile solution involves double protonation of an oxo ligand and loss of one water molecule. Low mass tungstate fragments combine into [(WO3)n]2- (n = 1-5) ions and their condensation products with phosphate. Reaction of TBA5H2[alpha1-Eu(H2O)4P2W17O61] with 1,10-phenanthroline or 2,2'-bipyridine showed an increase of the europium luminescence. This result is explained by the formation of a ternary complex of [alpha1-Eu(H2O)4P2W17O61]7- and two sensitizing ligands. 相似文献
83.
Raphaël Côte Claudio Muñoz Didier Pilod Gideon Simpson 《Archive for Rational Mechanics and Analysis》2016,220(2):639-710
We prove that solitons (or solitary waves) of the Zakharov–Kuznetsov (ZK) equation, a physically relevant high dimensional generalization of the Korteweg–de Vries (KdV) equation appearing in Plasma Physics, and having mixed KdV and nonlinear Schrödinger (NLS) dynamics, are strongly asymptotically stable in the energy space. We also prove that the sum of well-arranged solitons is stable in the same space. Orbital stability of ZK solitons is well-known since the work of de Bouard [Proc R Soc Edinburgh 126:89–112, 1996]. Our proofs follow the ideas of Martel [SIAM J Math Anal 157:759–781, 2006] and Martel and Merle [Math Ann 341:391–427, 2008], applied for generalized KdV equations in one dimension. In particular, we extend to the high dimensional case several monotonicity properties for suitable half-portions of mass and energy; we also prove a new Liouville type property that characterizes ZK solitons, and a key Virial identity for the linear and nonlinear part of the ZK dynamics, obtained independently of the mixed KdV–NLS dynamics. This last Virial identity relies on a simple sign condition which is numerically tested for the two and three dimensional cases with no additional spectral assumptions required. Possible extensions to higher dimensions and different nonlinearities could be obtained after a suitable local well-posedness theory in the energy space, and the verification of a corresponding sign condition. 相似文献
84.
Franziska Doll Annette Buntz Anne‐Katrin Späte Verena F. Schart Alexander Timper Waldemar Schrimpf Prof. Dr. Christof R. Hauck Prof. Dr. Andreas Zumbusch Prof. Dr. Valentin Wittmann 《Angewandte Chemie (International ed. in English)》2016,55(6):2262-2266
Protein glycosylation is a ubiquitous post‐translational modification that is involved in the regulation of many aspects of protein function. In order to uncover the biological roles of this modification, imaging the glycosylation state of specific proteins within living cells would be of fundamental importance. To date, however, this has not been achieved. Herein, we demonstrate protein‐specific detection of the glycosylation of the intracellular proteins OGT, Foxo1, p53, and Akt1 in living cells. Our generally applicable approach relies on Diels–Alder chemistry to fluorescently label intracellular carbohydrates through metabolic engineering. The target proteins are tagged with enhanced green fluorescent protein (EGFP). Förster resonance energy transfer (FRET) between the EGFP and the glycan‐anchored fluorophore is detected with high contrast even in presence of a large excess of acceptor fluorophores by fluorescence lifetime imaging microscopy (FLIM). 相似文献
85.
Starting from an $n$ -point circular gravitational lens having $3n+1$ images, Rhie (ArXiv Astrophysics e-prints, 2003) used a perturbation argument to construct an $(n+1)$ -point lens producing $5n$ images. In this work we give a concise proof of Rhie’s result, and we extend the range of parameters in Rhie’s model for which maximal lensing occurs. We also study a slightly different construction given by Bayer and Dyer (Gen Relativ Gravit 39(9):1413–1418, 2007) arising from the $(3n+1)$ -point lens. In particular, we extend their results and give sharp parameter bounds for their lens model. By a substitution of variables and parameters we show that both models are equivalent in a certain sense. 相似文献
86.
The addition of an essentially nonlinear membrane absorber to a linear vibroacoustic system with multiple resonances is studied experimentally, using quasiperiodic excitation. An extended experimental dataset of the system response is analyzed under steady-state excitation at two frequencies. Thresholds between low and high damping states within the system and associated noise reduction are observed and quantified thanks to frequency conversion and RMS efficiency indicators. Following previous numerical results, it is shown that the membrane NES (Nonlinear Energy Sink) acts simultaneously and efficiently on two acoustic resonances. In all cases, the introduction of energy at a second excitation frequency appears favorable to lower the frequency conversion threshold and to lower the noise within the system. In particular, a simultaneous control of two one-to-one resonances by the NES is observed. Exploration of energy conversion in the two excitation amplitudes plane advocates for a linear dependence of the frequency conversion thresholds on the two excitation amplitudes. 相似文献
87.
Otherwise sluggish or completely ineffective radical reductions of alkyl and aryl halides by N-heterocyclic carbene boranes (NHC-boranes) are catalyzed by thiols. Reductions and reductive cyclizations with readily available 1,3-dimethylimidazol-2-ylidene borane and a water-soluble triazole relative are catalyzed by thiophenol and tert-dodecanethiol [C(9)H(19)C(CH(3))(2)SH]. Rate constants for reaction of the phenylthiyl (PhS?) radical with two NHC-boranes have been measured to be ~10(8) M(-1) s(-1) by laser flash photolysis experiments. An analysis of the available evidence suggests the operation of polarity reversal catalysis. 相似文献
88.
A Goban KS Choi DJ Alton D Ding C Lacroûte M Pototschnig T Thiele NP Stern HJ Kimble 《Physical review letters》2012,109(3):033603
We report the experimental realization of an optical trap that localizes single Cs atoms ?215 nm from the surface of a dielectric nanofiber. By operating at magic wavelengths for pairs of counterpropagating red- and blue-detuned trapping beams, differential scalar light shifts are eliminated, and vector shifts are suppressed by ≈250. We thereby measure an absorption linewidth Γ/2π=5.7±0.1 MHz for the Cs 6S_{1/2}, F=4→6P_{3/2}, F^{'}=5 transition, where Γ_{0}/2π=5.2 MHz in free space. An optical depth d?66 is observed, corresponding to an optical depth per atom d_{1}?0.08. These advances provide an important capability for the implementation of functional quantum optical networks and precision atomic spectroscopy near dielectric surfaces. 相似文献
89.
Yu.A. Nastishin M. Kléman J. Malthête H.T. Nguyen 《The European physical journal. E, Soft matter》2001,5(3):353-357
We have shown that cholesteryl nonanoate, a thermotropic compound which is well known to exhibit pretransitional effects at
the smectic A (SmA) cholesteric (N*) transition (W.L. McMillan, Phys. Rev. A 4, 1238 (1971); 6, 936 (1972)), has in fact a TGBA phase in between. Our arguments rely on the observation of new TGBA defects, either in Robinson
spherulites cooled from the N* phase or in free-standing films. The same new defects can be obtained in a well-documented
TGBA phase of a tolane compound. We analyze qualitatively the TGBA defects in both geometries, in particular their relation
to the disclination radius of the N* Robinson spherulites.
Received 12 February 2001 相似文献
90.
Maxime Guillaume Benoît Champagne Eric A. Perpète Jean-Marie André 《Theoretical chemistry accounts》2001,105(6):431-436
The electronic structure of finite and infinite linear, cyclic and M?bius strip polyacenes has been investigated by adopting
Hückel and semiempirical schemes. Using the Hückel approach, it turns out that the M?bius belting process modifies the highest
occupied molecular orbital (HOMO)–lowest unoccupied molecular orbital (LUMO) gap in such a way its evolution with chain length
is similar to the linear polyacenes rather than their cyclic analogs. These results are corroborated at the Austin model 1
(AM1) level, where the geometry relaxation effects are taken into account. The optimized AM1 structures show that the M?bius
defect is localized and extends over a third of the ring. With respect to the Hückel approach, accounting for geometry distortion
at the AM1 levels results in an increase in the HOMO–LUMO gap of the M?bius strip relative to the linear and cyclic finite-size
structures. On the other hand, when including electron-hole correlation at the configuration interaction singles/Zerner's
intermediate neglect of differential overlap level the behavior with system size of the first excitation energy of cyclic
and M?bius polyacenes differs from their linear analogs and leads to smaller singlet excitation energies.
Received: 20 September 2000 / Accepted: 21 September 2000 / Published online: 28 February 2001 相似文献