快前沿直线脉冲变压器单级模块开关触发时延分散性实验研究

针对12支路并联的快前沿直线脉冲变压器单级模块,给出了模块的电路结构和关键器件参数,实验获得了12只多间隙气体开关的自击穿特性和触发特性。同时,还给出了快前沿直线脉冲变压器模块输出电流的初步实验结果,工作电压150 kV时,次级短路放电电流幅值为235 kA,电流前沿88.2 ns（10%~90%）。次级带0.58 负载情况下,输出电流幅值114.5 kA,电流前沿88.9 ns（10%~90%）。利用微分环测量了12只开关的触发时延分散性,结果表明100次实验开关触发时延分散性近似符合正态分布,开关触发时延分散性对输出电流的影响不大,电流幅值和前沿的标准偏差分别小于2.0%,4.0%,电流波形的畸变主要以平顶为主。     

高峰值功率大模场全光纤脉冲放大器

报道了一种由纤芯直径分别为15 μm和25 μm的大模场光纤组成的全光纤脉冲放大器模块。当注入脉冲宽度为10 ns,重复频率为1 Hz,光谱宽度为0.3 nm,脉冲能量为80 nJ的激光脉冲时,经过两级放大输出的激光脉冲峰值功率为30 kW,单脉冲能量为300 μJ。此外,实验研究了该放大器模块输出的时间特性。研究发现：由于受激布里渊散射（SBS）效应,限制了单纵模光纤激光在光纤中的高能量放大,采用宽带激光脉冲可以有效地抑制SBS效应,提高光纤放大器的SBS阈值。     

N,N’-二苯基-N,N’-二(9,9-二甲基芴-2-基)-9-己基-(4,4’-二胺基苯基)咔唑的合成方法及表征

以2,7-二溴咔唑为原料经过N-烷基化、Suzuki偶联反应、Buchwald-Hartwig偶联反应合成了有机发光二极管(OLED)空穴传输材料N,N’-二苯基-N,N’-二(9,9-二甲基芴-2-基)-9-己基-(4,4’-二胺基苯基)咔唑,利用NMR、IR和熔点等分析方法对产物结构进行了表征,并通过TG、UV-Vis及荧光光谱研究了物质的热稳定性和光学性能。     

激光触发多级多通道开关研究

 研究了200kV激光触发多级多通道开关的运行机理，该开关在直流电压下以四倍频Nd:YAG激光器为触发源进行的实验结果表明：开关触发延迟时间及其抖动随开关电压、激光能量和充气压力上升呈指数下降趋势，对混合气体则随气体密度上升而上升。随透镜焦距的增大延迟时间及其抖动呈上升趋势。该开关实现了多通道放电。     

汽油族组成的近红外光谱快速测定

以荧光指示剂吸附色谱法（FIA）测定汽油族组成结果为基础，采用近红外光谱和化学计量学方法建立了快速、准确测定催化裂化馏出口汽油族组成（饱和烃、烯烃和芳烃）的分析模型；试验表明，该法分析速度快、重复性好、成本低，特别适用于生产中间控制分析。     

吖啶类衍生物的荧光性质

用比较法测得23种啶类衍生物的荧光量子效率（Φf)，以评估这些化合物的荧光性质，结果表明，N－烃基吖啶酮类化合物的荧光量子效率要比9－取代苯基吖啶类和9－取代苯亚甲基－10－甲基－9，10－二氢吖啶类化合物的荧光量子效率大，在非极性溶剂中，9－聚代苯亚甲基－9，10二氢吖啶分子内的强吸电子基NO2增强荧光量子效率，强推电子基OCH3降低荧光量子效率，这些测量结果与取代基的电子作用经验规律不相符，这种现象可以用分子内电荷转移理论进行解释。     

The Preparation and Characterization of Highly Dispersed PdO over Alumina for Low‐temperature Combustion of Methane

PdO/Al₂O₃ catalysts prepared by glow discharge plasma treatment followed by thermal calcination show a much higher dispersion and a better catalytic activity for methane combustion at relatively low temperatures. The dispersion of palladium active species by such plasma prepared catalysts is 29.7%, 5.4 times higher than that of conventional catalysts. XPS analysis indicates that a surface enrichment of Pd active species (PdO) has been achieved after plasma treatment. The surface atomic composition of PdO of plasma prepared catalysts reaches 10.5%. XRD characterization also confirms a wellcrystallized PdO phase present on the plasma prepared catalyst. The lightoff temperature of the plasma prepared catalyst is 370°C, 50°C lower than that obtained from the conventional catalyst.     

2MeV注入器脉冲电子束时间分辨能谱诊断研究

介绍了利用磁分析器和电子束产生的契伦科夫辐射光诊断直线感应加速器脉冲电子束时间分辨能谱的原理、方法及诊断系统,对中物院2MeV感应叠加型注入器的2kA强流脉冲电子束时间分辨能谱进行实验诊断,并与二极管电压进行对比分析。测得能量约2.2MeV,60ns内最大能量变化为4%。     

ICP-AES法测定铅锭中11种杂质元素

研究了用酸分解试样后不需分离基体直接用ICP-AES法测定铅锭中银、铜、铋、砷、锑、锡、锌、铁、镉、镍、铊11种杂质元素的方法。优化了样品前处理条件及仪器检测条件。方法的检出限为0.0012μg/mL-0.0168μg /mL,回收率为89%-113%,RSD为 1.88%-4.97% 。     

Chiral polymers containing a carbohydrate moiety: synthesis

This paper reports the preparation of poly(acetal-ethers) by two alternative synthetic pathways (alkaline and acid-catalyzed conditions). Polycondensations of methyl 2,3:4,6-di-O-salicylidene-alpha-D-mannopyranoside (3) (mixtures of endo-H and exo-H dioxolan-2-yl-diastereomers) with 1,4-dibromobutane (4) (method I a and I b) were performed in solvents (DMF, butyl acetate/DMF, DMSO) and were catalyzed by K2CO3/KI or KOH. A similar polymer (6) was formed by the reaction of methyl alpha-D-mannopyranoside (1) and 1,4-bis(2-formylphenoxy)butane (7), catalyzed by p-toluenesulfonic acid (method II). Regardless of conversion or initial comonomer feed ratios, the composition of the polycondensates depended on the reaction conditions, leading to the formation of macrocyclic [1 + 1] (5) and [2 + 2] compounds, which were macromolecules with diverse molecular weights and optical properties. The regioselective polycondensation was examined by 1H NMR spectroscopy of selected polymers. In the case of 5-membered cyclic acetal units, mixtures of the endo-H and exo-H dioxolan-2-yl system, diastereomers were formed in the polymer chain. The macrocycles and linear oligomers were identified by NMR and electrospray mass spectrometry (ESI-MS). Thermodynamically controlled reactions for making macrocycles as well as oligomers in the absence of templates are also discussed.