SiO-2包覆超细CaCO-3的结构和机理分析

合成了表面包覆SiO2的超细CaCO3。通过XPS，XRD对包覆表面层结构的分析，证实了SiO2以无定形包覆于CaCO3表面，并在其表面形成了Si-O-Ca键。对SiO2包覆超细CaCO3的机理分析结果可知：Na2SiO3的加入量是影响包覆效率的重要因素，由于硅酸易自聚，控制SiO2与CaCO3的重量比约为4％－5％时为包覆的最佳点；CaCO3晶粒度大小影响分散性能，进而影响包覆效率，分散性能好的包覆效率较高。     

行波管相位一致性的理论研究与计算机模拟

 采用行波管一维大信号非线性理论,建立了高频参数和外部工作状况零散模型,对影响增益、相位频率特性的主要因素进行了理论分析和数值计算,分析了如何合理地选择相位一致行波管工作点,为新近研制的相位一致行波管提供了计算机模拟并得到了很有价值的计算结果。     

改进型双盘靶实验与分析

 采用改进型双盘靶结构,初级改用为斜柱腔结构,激光加热初级薄箔,后向出射的X光烧蚀次级,这样降低初级等离子体喷射的影响,使烧蚀次级的X光更纯净。采用X光条纹相机测量双盘靶等离子体喷射的时空扫描图象,采用两台软X光谱仪分别对初级和次级辐射的X光进行测量,研究次级盘对初级发射的X光谱的改造。测量结果表明：这种结构的双盘靶基本上能避免初级盘喷射等离子体的影响,初级盘后向辐射的X光谱具有明显 的N和O带谱结构,而次级辐射的X光谱主要以O带为主。     

EPR investigations of Cu(II) complexes with 5′-CMP and 5′-GMP

Electron paramagnetic resonance investigation of the Cu(II) complexes with guanosine-5′-monophosphate (5′-GMP) and cytidine-5′-monophosphate (5′-CMP) shows the affinity of the Cu(II) ion to interact with the base and the phosphate group. The different modes of the coordination of the metal ion at the nucleotide and the water molecules lead to octahedral species, distorted by dynamical Jahn-Teller effect (g₀ = 2.106) for the Cu(II)-5′-CMP complex and rhombically distorted (g₁ = 2.358, g₂ = 2.126, g₃ = 2.068) or tetragonally distorted (g_∥^′ = 2.299, g_⊥^′ = 2.126) for the Cu(II)-5′ -GMP complex. The compound with 5′-CMP presents also a more stable in time square-planar species (g_∥ = 2.265, A_∥ = 162 G, g_⊥ = 2.076). The local symmetry changes in aqueous solution by coordination of water molecules.     

对悬链式超声功率计测量误差的理论探讨

对在使用悬链式超声功率计测量时由于声源指向性所产生的误差进行了理论探讨，并对几个实例进行了数值计算，给出了相应的修正值。     

某SUV车门关门声品质建模及优化

本文介绍了汽车关门声品质的客观评价方法和评价参数以及关门声品质影响因素等方面的研究现状。在此基础上,针对某SUV车型车门关门声音的响度和尖锐度偏大的问题,进行了关门声的客观测试和特性分析,结合正交实验设计,建立关门声品质优化模型,针对关门声音振颤的问题,结合CAE分析,确定了车门外板高灵敏度区域,并对该区域进行了吸振处理,措施实施后关门声音的响度、尖锐度以及振颤均达到了更好的水平,且关门声主观评价也有明显提升。     

最大后验方法在图像复原中的应用

从统计学的角度讨论了图像复原的方法，然后根据图像的协方差矩阵的傅立叶变换对应于功率谱，从空间域变换到频域，从而使计算简化，易于计算机编程实现。     

利用原子与SU(2)相干态腔场的Raman相互作用制备原子纠缠态

利用一个参量频率转换过程,在腔中制备双模SU(2)相干态,然后注入一系列全同的Λ型三能级原子,这些原子与腔场的一个模发生拉曼相互作用,通过系列原子-腔场相互作用生成腔场-原子纠缠态,通过对腔场进行选择性测量,可获得多种形式多原子纠缠态.     

Ne、Ar、Kr、Xe等离子体Planck和Rosseland平均不透明度的近似计算

根据平均原子模型和类氢光吸收系数，近似地计算了Ne、Ar、Kr、Xe等惰性元素高温、高密度等离子体的Planck和Rosseland不透明度。在计算线谱吸收过程中，采用了唯象方法处理线谱演化成谱带时的加宽效应及谱带重叠效应。将不透明度数据拟合成温度和密度的幂函数形式，它能够用于辐射体的数值拟合。     

Characterization of the Binding of Metoprolol Tartrate and Guaifenesin Drugs to Human Serum Albumin and Human Hemoglobin Proteins by Fluorescence and Circular Dichroism Spectroscopy

The interactions of metoprolol tartrate (MPT) and guaifenesin (GF) drugs with human serum albumin (HSA) and human hemoglobin (HMG) proteins at pH?7.4 were studied by fluorescence and circular dichroism (CD) spectroscopy. Drugs quenched the fluorescence spectra of HSA and HMG proteins through a static quenching mechanism. For each protein-drug system, the values of Stern-Volmer quenching constant, bimolecular quenching constant, binding constant and number of binding site on the protein molecules were determined at 288.15, 298.15, 310.15 and 318.15 K. It was found that the binding constants of HSA-MPT and HSA-GF systems were smaller than those of HMG-MPT and HMG-GF systems. For both drugs, the affinity of HMG was much higher than that of HSA. An increase in temperature caused a negative effect on the binding reactions. The number of binding site on blood proteins for MPT and GF drugs was approximately one. Thermodynamic parameters showed that MPT interacted with HSA through electrostatic attraction forces. However, hydrogen bonds and van der Waals forces were the main interaction forces in the formation of HSA-GF, HMG-MPT and HMG-GF complexes. The binding processes between protein and drug molecules were exothermic and spontaneous owing to negative ?H and ?G values, respectively. The values of binding distance between protein and drug molecules were calculated from Förster resonance energy transfer theory. It was found from CD analysis that the bindings of MPT and GF drugs to HSA and HMG proteins altered the secondary structure of HSA and HMG proteins.