聚乙烯空间电荷包行为的形成机理与仿真方法研究

聚乙烯中的空间电荷包行为是空间电荷的一种特殊的输运行为.研究表明,空间电荷包行为由于受材料本身特性、外加电场大小以及环境温度等的影响,导致其产生过程及传输特性上存在较大差异,这些因素给空间电荷包行为产生机理研究带来了较大困难.通过对电荷的电极注入过程、载流子的体内迁移规律及空间电荷与体内陷阱的相互作用机制进行分析,探讨了不同外加电场及不同深度陷阱能级对电荷包行为造成的相关影响,在此基础上建立物理模型来描述电荷包的产生和迁移过程.模型中提出了在高于阈值电场时,载流子迁移速度与电场关系存在负微分迁移率的假设.基于此模型对空间包行为的模拟结果与实验结果取得较好的一致. 关键词： 空间电荷包 数值模拟 负微分迁移率     

Formation Mechanism and Binding Energy for Equilateral Triangle Structure of He3+ Cluster

The formation mechanism for the equilateral triangle structure of the He3 cluster is proposed. The curveof the total energy versus the internuclear distance R for this structure has been calculated by the method of a modifiedarrangement channel quantum mechanics. The result shows that the curve has a minimal -7.81373 a.u at 1 = 1.55 a0.The binding energy of He3 with respect to He He He was calculated to be 0.1064 a.u. (about 2.89 eV). This meansthat the He3 cluster may be formed in the equilateral triangle structure stably by the interaction of He with two heliumatoms.     

A Novel Method for the Synthesis of High Hindered Iminoesters by the Reaction of Decomposition of Phenyldiazoacetate in the Presence of Rh2(OAc)4 with Arylamines and DEAD

It is well known that iminoesters were condensed by ketoesters with amines, but the procedure to ketoesters require harsh reaction conditions and multi steps. Herein we report a mild and practical one-step approach for the synthesis of iminoesters, especially for the high steric hindered iminoesters. Decomposition of phenyl diazoacetate catalyzed by rhodium acetate with amines to give N-H insertion product has been reported.     

Entropy of Dirac Field in Non-stationary and Slowly Changing Reissner-Nordstrom Black Hole

Using the thin film brick-wall model and WKB approximation, the entropy of the Dirac field in the nonstationary and slowly changing Reissner-Nordstrom （R-N） black hole is calculated. The result shows that the entropy of the R-N black hole is still proportional to its surface area if we choose proper cut-off.     

Theoretical Calculations for Structural, Elastic and Thermodynamic Properties of MgB2 under High Pressure

We have investigated the structural and elastic properties of MgB₂ under high pressures using the full-potential linearized muffin-tin orbital (FP-LMTO) scheme within the generalized gradient approximation correction (GGA) in the frame of density functional theory. The calculated pressure dependence of the normalized volume is in excellent agreement with the experimental results. At the same time the elastic constants and acoustic anisotropy as a function of applied pressure are presented. Through the quasi-harmonic Debye model, we also investigate the thermodynamic properties of MgB₂.     

First-Principle Calculations for Thermodynamic Properties of LiBC Under High Temperature and High Pressure

The thermodynamic properties of LiBC are investigated by using the full-potential linearized muffin-tin orbital method (FP-LMTO) within the frame of density functional theory (DFT) and using the quasi-harmonic Debye model. The dependencies of the normalized lattice parameters a/a0 and c/c0, the ratio (c/a)/2, the normalized primitive volume V/V0 on pressure and temperature are successfully obtained. It is found that the interlayer covalent interactions (Li-B bonds or Li-C bonds) are more sensitive to temperature and pressure than intralayer ones (B-C bonds), as gives rise to the extreme lattice anisotropy in the bulk hcp LiBC.     

中国东北区域盛夏雨季的客观识别

鉴于我国东北三省雨季客观识别方法不尽相同,且无东北区域统一的雨季监测指标.为了更好地开展区域关键天气过程的客观化识别和监测,本文从区域角度出发,采用东北三省102站逐日降水量资料,通过对东北区域多年平均5点平滑处理的4月1日—10月31日逐日降水量序列的综合分析,及对历年逐日滑动平均雨量的对比试验,确定了东北盛夏雨季判别的阈值参数及通过阈值后的持续时间参数,进而研发了适合东北区域盛夏雨季开始和结束日期的客观识别方法.并采用美国环境预报中心和国家大气研究中心逐日再分析的风场、位势高度场资料,通过对盛夏雨季前、中、后期不同高度层大气环流场的对比分析,验证了该客观识别方法的合理性.结果表明,东北区域1981—2010年气候态平均的盛夏雨季的起止日期分别为每年的6月26日和8月30日.     

Mechanical properties of silicon nanobeams with undercut evaluated by combining dynamic resonance test and finite element analysis

Mechanical properties of silicon nanobeams are of prime importance in nanoelectromechanical system applications. A numerical experimental method of determining resonant frequencies and Young's modulus of nanobeams by combining finite element analysis and frequency response tests based on an electrostatic excitation and visual detection by laser Doppler vibrometer is presented in this paper. Silicon nanobeams test structures are fabricated from silicon-on-insulator wafers by using a standard lithography and anisotropic wet etching release process, which inevitably generates the undercut of the nanobeam clamping. In conjunction with three-dimensional finite element numerical simulations incorporating the geometric undercut, dynamic resonance tests reveal that the undercut significantly reduces resonant frequencies of nanobeams due to the fact that it effectively increases the nanobeam length by a correct value Δ L, which is a key parameter that is correlated with deviations in the resonant frequencies predicted from the ideal Euler-Bernoulli beam theory and experimentally measured data. By using a least-square fit expression including Δ L, we finally extract Young's modulus from the measured resonance frequency versus effective length dependency and find that Young's modulus of silicon nanobeam with 200-nm thickness is close to that of bulk silicon. This result supports that the finite size effect due to surface effect does not play a role in mechanical elastic behaviour of silicon nanobeams with the thickness larger than 200 nm.     

自聚焦激光束光束质量评价的功率谱密度方法

把功率谱密度分析的方法引入到激光束光束质量的评价中，分析了自聚焦激光束的近场分布，研究了强激光非线性自聚焦的一般规律，给出了在一定强度调制下的光束经过钕玻璃介质发生自聚焦成丝效应的B积分阈值条件，实验和理论模拟结果基本一致.