全文获取类型
收费全文 | 2271篇 |
免费 | 77篇 |
国内免费 | 188篇 |
专业分类
化学 | 920篇 |
晶体学 | 1篇 |
力学 | 83篇 |
综合类 | 16篇 |
数学 | 201篇 |
物理学 | 1315篇 |
出版年
2022年 | 10篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2019年 | 6篇 |
2018年 | 13篇 |
2017年 | 17篇 |
2016年 | 47篇 |
2015年 | 29篇 |
2014年 | 30篇 |
2013年 | 35篇 |
2012年 | 37篇 |
2011年 | 288篇 |
2010年 | 177篇 |
2009年 | 127篇 |
2008年 | 46篇 |
2007年 | 40篇 |
2006年 | 81篇 |
2005年 | 132篇 |
2004年 | 259篇 |
2003年 | 222篇 |
2002年 | 145篇 |
2001年 | 152篇 |
2000年 | 38篇 |
1999年 | 45篇 |
1998年 | 39篇 |
1997年 | 29篇 |
1996年 | 30篇 |
1995年 | 29篇 |
1994年 | 12篇 |
1993年 | 46篇 |
1992年 | 41篇 |
1991年 | 26篇 |
1990年 | 29篇 |
1989年 | 37篇 |
1988年 | 48篇 |
1987年 | 20篇 |
1986年 | 23篇 |
1985年 | 15篇 |
1984年 | 17篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 13篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1977年 | 3篇 |
1919年 | 3篇 |
1911年 | 4篇 |
1910年 | 3篇 |
1909年 | 3篇 |
1907年 | 3篇 |
排序方式: 共有2536条查询结果,搜索用时 62 毫秒
71.
The organic nanoparticles of a blue-light-emitting molecule, 1,3-diphenyl-5-(9-anthryl)-2-pyrazuline, were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morphologies, spherical, doughnut-shaped and cubic, could be observed on the silicon substrate forthe nanoparfides by the volume-controlled addition of acetonitrile. The evolution of particle morphology as a function of acetonitrile addition was attributed to the variation of the growth habits of the particles in the different environment. The nanoparticles exhibit the novel photoluminescence spectra as compared to those of monomer and the bulk crystals. 相似文献
72.
Synthesis and Characterization of a Novel Biomaterial: Maleic Anhydride-modified Poly(dl-lactic acid) 总被引:2,自引:0,他引:2
YanFengLUO YuanLiangWANG XuFengNIU JunPAN LiangPingSHI 《中国化学快报》2004,15(5):521-524
A novel modified poly(dl-lactic acid) (PDLLA) was obtained by covalently grafting of maleic anhydride onto the backbone of PDLLA, attempting to improve PDLLA‘s hydrophilicity and cell affinity and to provide reactive groups for further chemical modification. FTIR, ^13 C NMR and DSC were used to characterize the maleic anhydride-modified PDLLA. 相似文献
73.
74.
ZHANG Cong-jie CAO Ze-xing ** ZHANG Qian-er . State Key Laboratory for Physical Chemistry of Solid Surface Department of Chemistry Center for Theoretical Chemistry Xiamen University Xiamen P. R. China . Department of Chemistry Shanxi Normal University Linfen P. R. China 《高等学校化学研究》2003,(4)
IntroductionCarbon chains are among the most attractivecandidates as the carriers of the diffuse interstellarbands ( DIBs) [1] .To detect the carbon chains indark clouds and carbon stars[2 ] ,itis very importantto understand their electronic spectra.Maier andhis coworkers have measured the polyacetylenicradicals C2 n H( n=1— 4) and C2 n-1H( n=2— 6) bythe rotational spectroscopy[3 ,4] and the species n≤ 4have been detected in dark interstellar clouds[5,6] .In neon matrices,the B2 Π← X2… 相似文献
75.
76.
In the presence of trialkylamine and formic acid RuCl2(PPh3)3 selectively reduces aldehydes to the corresponding alcohols at room temperature. Other reducible groups are unaffected. 相似文献
77.
78.
On the Criteria of Instability for Electrochemical Systems 总被引:7,自引:0,他引:7
Both cyclic-voltammetry-based and impedance-based experimental criteria that have been developed recently for the oscillatory electrochemical systems are critically appraised with two typical categories of oscillators.Consistent conclusions can be drawn by the two criteria for the category of oscillators that involve the coupling of charge transfer mainly with surface steps(e.g.ad-and desorption)such as in the electrooxidation of C1 organic molecules.Whereas,impedance-based criterion is not applicable to the category of oscillators that involve the coupling of charge transfer mainly with mass transfer(e.g.diffusion and convection) such as in the Fe(CN)6^3- reduction accompanying periodic hydrogen evolution.The reason is that the negative impedance cannot include the feedback information of convection mass transfer induced by the hydrogen evolution.However,both positive and negative nonlinear feedbacks,i.e., the diffusion-limited depletion and convection-enhanced replenishment of the Fe(CN)6^3- surface concentration,that coexist between the bistability,i.e.,Fe(CN)6^3- reduction with and without hydrogen evolution at lower and higher potential sides respectively,are all reflected in the crossed cyclic voltammogram(CCV).It can be concluded that the voltammetry-based criterion(in time domain)is more intuitive,less time-consuming and has a wider range of applications than the impedancebased one (in frequency domain). 相似文献
79.
OPAL Collaboration G. Alexander J. Allison N. Altekamp K. Ametewee K. J. Anderson S. Anderson S. Arcelli S. Asai D. Axen et al. 《Zeitschrift fur Physik C Particles and Fields》1995,69(1):543-560
Symmetric three-jet events are selected from hadronic Z0 decays such that the two lower energy jets are each produced at an angle of about 150° with respect to the highest energy
jet. In some cases, a displaced secondary vertex is reconstructed in one of the two lower energy jets, which permits the other
lower energy jet to be identified as a gluon jet through anti-tagging. In other cases, the highest energy jet is tagged as
a b jet or as a light quark (uds) jet using secondary vertex or track impact parameter and momentum information. Comparing
the two lower energy jets of the events with a tag in the highest energy jet to the anti-tagged gluon jets yields a direct
comparison of b, uds and gluon jets, which are produced with the same energy of about 24 GeV and under the same conditions.
We observe b jets and gluon jets to have similar properties as measured by the angular distribution of particle energy around
the jet directions and by the fragmentation functions. In contrast, gluon jets are found to be significantly broader and to
have a markedly softer fragmentation function than uds jets. For thek
⊥ jet finder withy
cut=0.02, we find
as the ratios of the mean charged particle multiplicity in the gluon jets compared to the b and uds jets. Results are also
reported using the cone jet finder. 相似文献
80.
ALEPH Collaboration D. Buskulic I. De Bonis D. Decamp P. Ghez C. Goy J. P. Lees A. Lucotte M. N. Minard P. Odier et al. 《Zeitschrift fur Physik C Particles and Fields》1996,71(3):357-378
The electroweak mixing angle is determined with high precision from measurements of the mean difference between forward and
backward hemisphere charges in hadronic decays of the Z. A data sample of 2.5 million hadronic Z decays recorded over the
period 1990 to 1994 in the ALEPH detector at LEP is used. The mean charge separation between event hemispheres containing
the original quark and antiquark is measured for
and
events in subsamples selected by their long lifetimes or using fastD*’s. The corresponding average charge separation for light quarks is measured in an inclusive sample from the anticorrelation
between charges of opposite hemispheres and agrees with predictions of hadronisation models with a precision of 2%. It is
shown that differences between light quark charge separations and the measured average can be determined using hadronisation
models, with systematic uncertainties constrained by measurements of inclusive production of kaons, protons andΛ’s. The separations are used to measure the electroweak mixing angle precisely as sin2
ϑ
w
eff
=0.2322±0.0008(exp.stat.) ±0.0007(exp.syst.)±0.0008(sep.). The first two errors are due to purely experimental sources whereas
the third stems from uncertainties in the quark charge separations.
Supported by Dirección General de Investigación Científica y Técnica, Spain 相似文献