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231.
María Beatriz de la Calle Guntiñas Michiel Ceulemans Claudia Witte Ryszard Łobiński Freddy C. Adams 《Mikrochimica acta》1995,120(1-4):73-82
A method is presented for the selective determination of the volatile selenium species dimethylselenide and dimethyldiselenide, using a commercially available purge-and-trap injection system coupled to capillary gas chromatography-microwave induced plasma-atomic emission spectrometry. The efficiency of the purging step was evaluated and the parameters affecting the purge and trap processes were optimized. The method was applied to the determination of volatile selenium compounds in lake water. Relative detection limits of 2ng/l for dimethylselenide and dimethyldiselenide, corresponding to an absolute detection limit of 10 pg, were achieved. 相似文献
232.
233.
Summary The application of GLC, HPLC and TLC to the analysis of pharmaceutical creams is discussed with special attention to sample clean-up. The results of the determination of hydrocortisone acetate, salicylic acid, benzoic acid, diethyl stilbestrol, chloramphenicol, diphenhydramine HCl, tretinoin and some cream base components by reversed phase HPLC are given.Presented at the 14th International Symposium on Chromatography London, September, 1982 相似文献
234.
D. S. Gouveia R. Rosenhaim M. A. M. A. de Maurera S. J. G. Lima C. A. Paskocimas E. Longo A. G. Souza I. M. G. Santos 《Journal of Thermal Analysis and Calorimetry》2004,75(2):453-460
With the aim of obtaining materials with applications in pigments, CoxZn7-xSb2O12 spinels were synthesized using the Pechini method. This method consists in the formation of a polymeric net, where the metallic
cations are homogeneously distributed. In this work, two types of alcohol (ethyl glycol and ethylene glycol) were used for
the synthesis of a zinc antimoniate spinel, CoxZn7-xSb2O12 (x=0-7). The materials were characterized by termogravimetry (TG) and differential thermal analysis (DTA). TG results indicated
a decrease in total mass loss when cobalt was added to the solution substituting zinc, for samples prepared using the two
different alcohols. Decomposition temperatures, obtained by TG and DTA, presented a decreasing behavior as cobalt was added
to the material. In relation to the alcohols, all results indicated a better polymerization of the resin when ethylene glycol
was used, being the most indicated one for cation immobilization. X-ray diffraction did not show differences between the two
alcohols - both presented the spinel phase (Co, Zn)2.33Sb0.67O4. Samples with higher quantity of cobalt also presented ilmenite phase (Co, Zn)Sb2O6.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
235.
F. F. C. Bazito S. I. Córdoba de Torresi R. M. Torresi 《Journal of Solid State Electrochemistry》2007,11(11):1471-1479
Poly(phenylene sulfide phenyleneamine), PPSA, is a copolymer of poly(aniline) and poly(phenylene sulfide), soluble in conventional
organic solvents as tetrahydrofuran, dimethyl sulfoxide, dimethylformamide, and cyclohexanone. In this research, its electrochemical
behavior has been studied in acetonitrile in the presence of different electrolytes, where the loss of electroactivity was
observed after few cycles. In this paper, the charge compensation dynamics of PPSA is analyzed through electrochemical quartz
crystal microbalance experiments and electroacoustic impedance measurements. Raman spectroscopy data have shown that once
the oxidation of the sulfur atom occurs, a loss of electroactivity is observed, being not possible to recover the pristine
state of the polymer. Fourier transform infrared (FTIR) and X-ray diffraction (XRD) data obtained for the fully oxidized polymer
are consistent with the formation of a networked polymer due to the electrophilic attack of the positive sulfur atom on the
activated aromatic rings. Electrochemical quartz crystal microbalance results clearly show that the degree of irreversibility
fully depends on the chemical nature of the anions with a negligible participation of the cations of the electrolytic solution.
This work is in memoriam of Prof. Dr. Francisco C. Nart, dearest friend and colleague, whose scientific skills and enthusiasm
will always be remembered. 相似文献
236.
Treatment of methyl 3,5-dideoxy-β---pentofuranoside with the Ph3P-CCl4 reagent gave none of the expected 2-chloro derivative but a mixture of l→2 linked oligosaccharides, , with some higher homologues, terminated by αa 2-chloro-2,3,5-trideoxy-α---pentofuranosyl unit at the non reducing end. 相似文献
237.
Pilar Alonso Isabel de Frutos Teresa Gutiérrez Antonio Doadrio López 《Transition Metal Chemistry》1987,12(2):133-136
Summary The synthesis and the dinuclear or mononuclear nature of several molybdenum(VI) and molybdenum(V) oxocomplexes derived from 1,3-diphenyl-1,3-propanedione (HLL) are described. These complexes were identified by i.r. and electronic spectra, magnetic susceptibility and analytical data, and are assigned the following formulae: [MoO2(LL)2], [Mo2O5(LL)2], [Mo2O4(LL)2], [MoOCl(LL)2], [MoCl2(LL)] and [MoO(OH)(LL)2)]. The low magnetic moments of the dinuclear complexes are due, in part, to intramolecular interactions. The i.r. data show that the dionate is bound by two oxygen atoms forming a chelate six-membered ring. 相似文献
238.
239.
A. de la Hoz C. Pardo J. Elguero M. L. Jimeno 《Monatshefte für Chemie / Chemical Monthly》1992,123(1-2):99-104
Summary The reaction of tetracyanoethylene oxide on one hand and toluene, chlorobenzene, fluorobenzene, anisole, and nitrobenzene, on the other, has been studied. Toluene and the halogenobenzenes yield mixtures of monoadducts, anisole yieldp-methoxyphenylmalononitrile and its dimer and nitrobenzene does not react. These results are discussed with the help of a qualitative orbital model.1H-NMR analysis of some monoadducts has been carried out.
Der Benzolring als Dipolarophil: Reaktionen monosubstituierter Benzole mit Tetracyanoethylenoxid
Zusammenfassung Es wurden die Reaktionen von Tetracyanoethylenoxid mit Toluol, Chlorbenzol, Fluorbenzol, Anisol und Nitrobenzol untersucht. Toluol und die Halogenbenzole ergaben Mischungen von Monoaddukten, Anisol ergabp-Methoxyphenylmalononitril und sein Dimer, Nitrobenzol zeigte keine Reaktion. Diese Resultate werden mit Hilfe eines qualitativen Orbitalmodells diskutiert. Die Analyse einiger Monoaddukte erfolgte mittels1H-NMR-Analyse.相似文献
240.
I. V. Katal'nikov V. A. Kuz'min P. P. Levin K. de Jonge G. R. Myul'man 《Russian Chemical Bulletin》1989,38(8):1758-1760
The spectrokinetic indices of the triplet states of nitroaromatic amides were established. The quenching of triplet states by tertiary aromatic amines in apolar solvents leads to the formation of triplet exciplexes. A charge transfer state makes the major contribution to the structure of these exciplexes. Hydrogen atom transfer proceeds efficiently in the case of secondary aromatic amines, leading to the formation of the corresponding neutral radicals.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1912–1915, August, 1989. 相似文献