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961.
一个实方阵A称为是S2NS阵,若所有与A有相同符号模式的矩阵均可逆,且它们的逆矩阵的符号模式都相同.若A是S2NS阵且A中任意一个零元换为任意非零元后所得的矩阵都不是S2NS阵,则称A是极大S2NS阵.设所有n阶极大S2NS阵的非零元个数所成之集合为S(n),Z4(n)={1/2n(n-1) 4,…,1/2n(n 1)-1},除了2n 1到3n一4间的一段和Z4(n)外,S(n)得到了完全确定.本文将用图论方法证明Z4(n)∩S(n)=(?). 相似文献
962.
963.
LI Wangliang XING Jianmin XIONG Xiaochao SHAN Guobin & LIU Huizhou . Laboratory of Separation Science Engineering Institute of Process Engineering Chinese Academy of Sciences Beijing China . Graduate School of the Chinese Academy of Sciences Beijing China 《中国科学B辑(英文版)》2005,(6)
More and more stringent regulations of gasoline and diesel oil were proposed with the awareness of environmental protection. Hydrodesulfurization (HDS) is a conventional method to remove sulfur compounds for industrial purpose. The main drawbacks of this … 相似文献
964.
965.
DaXinSHI YaQingFENG ShunHeZHONG 《中国化学快报》2005,16(5):685-687
Photoinduced synthesis of CO2 and CH4 was investigated using a batch reaction system on several photoactive materials supported on silicon dioxide. Single semiconductor showed higher selectivity to C1 compounds. The production of C2-C3 oxygenates took place preferentially on composite semiconductor photocatalysts. In particular, it was found that acetone was the primary product over Cu/CdS-TiO2/SiO2. 相似文献
966.
967.
Devdutt Chaturvedi Nisha Mishra Virendra Mishra 《Monatshefte für Chemie / Chemical Monthly》2007,70(6):57-60
A novel Mitsunobu-based protocol was developed for the synthesis of carbamates from the corresponding alcohols using carbon dioxide and amines
in good to excellent yields. This protocol is mild, chemoselective, and efficient compared to other reported methods. 相似文献
968.
J rgen Rosenqvist Kristina Axe Staffan Sj berg Per Persson 《Colloids and surfaces. A, Physicochemical and engineering aspects》2003,220(1-3):91-104
The adsorption of the dicarboxylates o-phthalate, maleate, fumarate, malonate, and oxalate (representing ligands with the general composition −O2C---Cn---CO2−; n=0, 1, or 2) on gibbsite were studied by means of quantitative batch adsorption experiments and attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. The interpretations of ATR-FTIR spectra were aided by comparison with IR spectra of solution species and by results from theoretical frequency calculations. The main objectives of the study were to identify the molecular level bonding mechanisms of the dicarboxylates to gibbsite, and to investigate how these were influenced by the composition and structure of the ligands. Carboxylates with n=2 formed predominantly outer sphere complexes, whereas the importance of inner sphere complexes progressively increased for n=1 and 0. The inner sphere structures were identified as mononuclear chelates with one oxygen from each carboxylate group bonded to Al(III) at the surface. This showed the importance of chelate ring structure for the formation of inner sphere surface complexes, with stabilities of the complexes increasing in the order seven-membered ring less than six-membered ring less than five-membered ring. For ligands with n=2 only small variations in surface speciation were observed as a function of steric factors; irrespective of the relative positions of the carboxylate groups and bulkiness of the ligands outer sphere bonding is the dominating adsorption mode. Adsorption experiments were also conducted with gibbsite particles exhibiting differences in shape and surface roughness. These experiments showed that inner sphere complexes were favored on the less well-developed and more irregular gibbsite particles. 相似文献
969.
The supersymmetric WKB approximation of ring-shaped oscillator potential in r and θ dimensions with spherical polar coordinates
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According to calculation of the energy spectrum of ring-shape oscillator potential by using the supersymmetric WKB approximation, it is shown that the energy spectrum of some noncentral separable potentials can be exactly obtained in r and θ dimensions by above method. 相似文献
970.
Enrique Bendito ngeles Carmona Andr s M. Encinas 《Applied Numerical Mathematics》2004,50(3-4):343-370
Our aim is to set the foundations of a discrete vectorial calculus on uniform n-dimensional grids, that can be easily reformulated on general irregular grids. As a key tool we first introduce the notion of tangent space to any grid node. Then we define the concepts of vector field, field of matrices and inner products on the space of grid functions and on the space of vector fields, mimicking the continuous setting. This allows us to obtain the discrete analogous of the basic first order differential operators, gradient and divergence, whose composition define the fundamental second order difference operator. As an application, we show that all difference schemes, with constant coefficients, for first and second order differential operators with constant coefficients can be seen as difference operators of the form
for suitable choices of q,
and
. In addition, we characterize special properties of the difference scheme, such as consistency, symmetry and positivity in terms of q,
and
. 相似文献