Preparation and semiconducting properties of Th3As4

The resistivity, thermoelectric power and Hall constant in the temperature range of 78–830 K were determined for polycrystalline Th₃As₄ samples obtained by annealing thin thorium slabs in arsenic vapour. The samples examined were n-type semiconductors with a carrier concentration ranging from 1.0 × 10¹⁸cm^?3 to 2.8 × 10¹⁸ cm^?3 for which the effective mass was found to be equal to 0.55–0.76m₀. The Hall mobility, about 450cm²V^?1s^?1 at room temperature, obeys a $\text{T}{}^{\mathrm{<mtext>?3</mtext><mtext>2</mtext>}}$ law at high temperatures. On the basis of the electrical measurements the forbidden gap of Th₃As₄ was found to be equal to 0.43 eV.     

Determination of the electron temperature from partial LTE populations in a mercury plasma flow

Population densities of excited levels of mercury atoms were measured in a supersonic plasma flow. Existence of partial LTE permitted determination of the electron temperature from the slope of the Boltzmann plot.     

Microscopic theory of superfluid3He-superfluid4He solutions II. Acoustical approximation. Propagation of sounds

Linearized hydrodynamic equations for superfluid³He-superfluid⁴He solutions are examined. The addition of a new parameter, the velocity of the Fermi-pair condensate, increases the number of equations and, in consequence, the rank of the determinant of the equations. This leads to a new energy root of the determinant which describes an extra sound mode different from the first and second sound.     

Classical bouncing Universes from vector fields

For the anisotropic Universe filled with massless vector field in the General Relativity frame we obtain bouncing solution for one of scale factors. We obtain the Universe with finite maximal energy density, finite value of R,RμνRμν,RμναβRμναβ and non-zero value of a scale factor for directions transverse to a vector field. Such a bounce can be also obtained for a massive vector field with kinetic initial conditions, which gives isotropic low energy limit. We discuss the existence of a bounce for a massless vector field with additional matter fields, such as cosmological constant or dust. We also discuss bouncing solution for massless vector field domination in n+2-dimensional space-time.     

Spectrophotometric determination of Fe(II) in milligram solid samples

The analytical procedure of determination of Fe(II) in the presence of Fe(III) in milligram samples is proposed. A solid sample is dissolved in hydrochloric acid in argon atmosphere. Subsequently, the pH-value of the solution is fixed and Fe(III) complexed by phosphoric buffer. At the next step Fe(II) is oxidized by -molybdosilicic acid. Finally, the intensity of colouring caused by the reduced form of the acid is measured at the wavelength 770 nm. The proper treatment of the sample during oxidation, and immediately before, is decisive for the accuracy of the analysis. The method was verified by means of the analysis of synthetic magnetite. The theoretical content of Fe(II) was 24.12%, the determined one was 24.02 ± 0.10%. The method was applied to the determination of the homogeneity of an iron catalyst for ammonia synthesis.     

Two-Color Two-Photon Excitation of Fluorescence

Abstract— We report the observation of two-photon excitation of an organic fluorophore with two different wavelengths, a phenomenon we refer to as two-color two-photon (2C2P) excitation. Ultraviolet emission of p -Merphenyl at 340 nm was observed when the sample was illuminated with both 375 and 750 nm pulses from a picosecond dye laser. The emission of p -terphenyl was about 100-fold and more than 1000-fold less for illumination at only 375 or 750 nm, respectively. Observation of the 2C2P signal required temporal and spatial overlap of the 375 and 750 nm pulses. The amplitude of the signal depended on the polarization of each beam. 2C2P excitation can have applications in fluorescence microscopy and elsewhere when spatially localized excitation is desirable.