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21.
A new type of amorphous helical carbon nanofibers has been synthesized using copper nanocatalysts and an acetylene gas source at atmospheric pressure. The nanofibers are grown at 468 K, which is the lowest temperature by ordinary metal-catalyzed thermal chemical vapor deposition of hydrocarbon, and exhibit a symmetric growth mode in the form of twin helices. IR, XRD, Raman, and C/H molar ratio analyses reveal a polymer-like structure with a weak trans-polyacetylene feature. The nanofibers are a mixture of solid polymers and a small amount of carbon. A reaction mechanism has been proposed on the basis of the previous studies of acetylene adsorption, desorption properties, and surface reactions on copper (111), (110), and (001) planes under ultrahigh-vacuum (UHV) conditions as well as the results obtained in our study. The reaction mechanism of acetylene on copper single-crystal surfaces under UHV conditions indeed reflects the reaction mechanism under practical catalytic conditions at atmospheric pressure. The nanofibers grow mainly via acetylene coupling to solid polymers on copper nanocrystal surfaces. Acetylene also couples to yield small amounts of liquid oligomers and gaseous products, and undergoes slight carbon deposition during the fiber growth. 相似文献
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This paper presents two experiment phenomena of nanocrystalline particles. One is the dispersion of rare earth element on the surface of transition metal particles by hydrogen arc plasma method, the other is that nanocrystalline metal particles were dispersed into the pores of alumina: The dispersion mechanism was discussed 相似文献
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Synthesis and characterization of single-crystal Ce(OH)CO3 and CeO2 triangular microplates 总被引:1,自引:0,他引:1
Single-crystal cerium hydroxide carbonate (Ce(OH)CO3) triangular microplates with the hexagonal phase have been successfully synthesized by a hydrothermal method at 150 degrees C using cerium nitrate (Ce(NO3)3.6H2O) as the cerium source, aqueous carbamide as both an alkaline and carbon source, and cetyltrimethylammonium bromide (CTAB) as a surfactant. Single-crystal ceria (CeO2) triangular microplates have been fabricated by a thermal decomposition-oxidation process at 650 degrees C for 7 h using single-crystal Ce(OH)CO3 microplates as the precursor. The shape of the Ce(OH)CO3 microplate was sustained after thermal decomposition-oxidation to CeO2. The products were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM), differential scanning calorimetric analysis (DSC), and thermogravimetric analysis (TG). 相似文献
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Carbon-encapsulated copper nanoparticles were synthesized by a modified arc plasma method using methane as carbon source.
The particles were characterized in detail by transmission electron microscope, high-resolution transmission electron microscopy,
selected-area electron diffraction, X-ray diffraction, thermogravimetric and differential scanning calorimetry. The encapsulated
copper nanoparticles were about 30 nm in diameter with 3–5 nm graphitic carbon shells. The outside graphitic carbon layers
effectively prevented unwanted oxidation of the copper inside. The effect of the ratio of He/CH4 on the morphologies and the formation of the carbon shell were investigated. 相似文献
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本文报导了苯与正已烷二元有机混合吸附薄膜在低能电子(<50eV)轰击下正已烷的原位离解,研究了苯的加入对正已烷离解的影响及作用机制。发现苯增加了正已烷的离解,这种现象由苯与正已烷分子间的激发转移予以解释。 相似文献
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The oriented ZnO nanorod arrays have been synthesized on a silicon wafer that coated with TiO2 films by aqueous chemical method. The morphologies, phase structure and the photoluminescence (PL) properties of the as-obtained
product were investigated by field-emission scanning electron microscopy (FE-SEM), X-ray diffractometer (XRD), transmission
electron microscope (TEM) and PL spectrum. The nanorods were about 100 nm in diameter and more than 1 μm in length, which
possessed wurtzite structure with a c axis growth direction. The room-temperature PL measurement of the nanorod arrays showed strong ultraviolet emission. The
effect of the crystal structure and the thickness of TiO2 films on the morphologies of ZnO nanostructures were investigated. It was found that the rutile TiO2 films were appropriate to the oriented growth of ZnO nanorod arrays in comparison with anatase TiO2 films. Moreover, flakelike ZnO nanostructures were obtained with increasing the thickness of anatase TiO2 films. 相似文献