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941.
提出和研究了噪声情况下的量子网络直接通信. 通信过程中所有量子节点共享多粒子Greenberger-Horne-Zeilinger (GHZ)量子纠缠态; 发送节点将手中共享的GHZ态的粒子作为控制比特、传输秘密信息的粒子作为目标比特, 应用控制非门(CNOT)操作; 每个接收节点将手中共享GHZ 态的粒子作为控制比特、接收到的秘密信息粒子作为目标比特, 再次应用CNOT门操作从而获得含误码的秘密信息. 每个接收节点从秘密信息中提取部分作为检测比特串, 并将剩余的秘密信息应用奇偶校验矩阵纠正其中存在的比特翻转错误, 所有接收节点获得纠正后的秘密信息. 对协议安全、吞吐效率、通信效率等进行了分析和讨论. 相似文献
942.
针对传统非相干宽带腔增强吸收光谱浓度反演方法的定量结果易受镜片反射率标定误差的影响问题, 提出了一种基于测量大气O2-O2吸收的浓度反演方法. 该方法是将非相干宽带腔增强吸收光谱技术的光学增强腔等效成吸收光程不随波长变化的多次反射池, 首先根据测得的宽带腔增强大气吸收谱和参考谱计算出光学厚度, 并应用差分光学吸收光谱算法拟合修正后的气体吸收截面到光学厚度, 反演得到大气中O2-O2以及被测气体的柱浓度, 然后根据O2-O2在大气中的含量已知且相对稳定这一特性, 确定出等效多次反射池的吸收光程, 最后从被测气体的柱浓度中扣除吸收光程信息得到被测气体的浓度值. 以监测大气中NO2实验为例, 应用该方法在454-487 nm波段反演得到了大气NO2的浓度(1-30 ppbv范围内), 并将反演结果与传统浓度反演方法的结果进行了对比, 发现两者的不一致性在7%以内. 实验结果表明, 非相干宽带腔增强吸收光谱技术可以利用大气O2-O2的吸收来定量其他被测气体的浓度, 而且定量结果对镜片反射率的标定误差不敏感. 相似文献
943.
Yan‐Hong Li Juan He Yan Li Xing‐De Wu Li‐Yan Peng Ru‐Nan Du Xiao Cheng Qin‐Shi Zhao Rong‐Tao Li 《Helvetica chimica acta》2014,97(11):1481-1486
A phytochemical study of the CHCl3 extract of the dried unripe fruits of Evodia rutaecarpa (Juss. ) Benth. (Rutaceae) resulted in the isolation of three new alkaloids, evollionines A–C ( 1 – 3 , resp.), together with two known compounds, evodianinine and wuzhuyumide I. The structures of the new compounds were elucidated on the basis of detailed spectroscopic evidence and confirmed in the case of compound 1 by single‐crystal X‐ray analysis. 相似文献
944.
Hongfen Zhang Shaomin Shuang Linlin Sun Anjia Chen Yong Qin Chuan Dong 《Mikrochimica acta》2014,181(1-2):189-196
We report on an electrochemical aptasensor for the ultrasensitive determination of thrombin. A glassy carbon electrode modified with a graphene-porphyrin nanocomposite exhibits excellent electrochemical activity and can be used as a redox probe in differential pulse voltammetry of the porphyrin on its surface. The thrombin aptamer is then immobilized via p-stacking interactions between aptamer and graphene and π-π stacking with porphyrin simultaneously. The resulting electrochemical aptasensor displays a linear response to thrombin in the 5–1,500 nM concentration range and with a limit of detection of 0.2 nM (at an S/N of 3). The sensor benefits from the synergetic effects of graphene (with its high conductivity and high surface area), of the porphyrin (possessing excellent electrochemical activity), and of the aptamer (with its high affinity and specificity). This kind of aptasensor conceivably represents a promising tool for bioanalytical applications. Figure
The representation of the sensing procedure for analysis of thrombin based on the TA/GN-Por/GCE by an electrochemical strategy 相似文献
945.
Bin Dong Di Qin Hong L. Shi Yui R. Fang Wen Z. Wang Yang Y. He Bao S. Cao Yan X. Liu Yong Ding 《Mikrochimica acta》2014,181(7-8):791-795
We report on the synthesis and optical spectra of silver nanorice particles. Two strong absorption bands are resolved in the near UV and near-IR region, and the dark field scattering spectra are consistent with the absorption spectra. Finite-difference time-domain simulations reveal that the peak in the IR region can be attributed to the E field that is parallel to the long axis, while the peak in the UV can be attributed to the E field perpendicular to the short axis of the silver nanorice particles. Figure
This paper reports on the synthesis of Ag nanorices, and their characterization by optical absorption, TEM, dark field scattering microscopy of single Ag nanorice and theoretical simulations using time domain finite-difference time-domain method. Electric field distribution of Ag nanorice dimer excited by polarization along long axis. 相似文献
946.
A sequential one-pot two-step tandem reaction for selective and efficient synthesis of pyrrolo[2,1-a]isoquinoline and its dihydro- and tetrahydro-derivatives has been developed. The tandem reactions of isoquinoline, α-halogenated methylene compounds, aromatic aldehydes, and cyanoacetamide firstly give tetrahydropyrrolo[2,1-a]isoquinolines as main products. The corresponding pyrrolo[2,1-a]isoquinolines and dihydropyrrolo[2,1-a]isoquinolines can be obtained directly by controlling oxidation with DDQ. The mechanism of this tandem reaction involved the 1,3-dipolar cycloaddition of isoquinolinium ylide as the key step. A unique elimination of the amido group preferring to the cyano group has been observed. 相似文献
947.
Yanyan Kong Xingqin Zhou Guoxian Cao Xijie Xu Meifen Zou Xiaofeng Qin Rongjun Zhang 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(1):93-101
Pyrroloquinoline quinone (PQQ), an essential nutrient, antioxidant, redox modulator and nerve growth factor found in a class
of enzymes called quinoproteins, was labeled with 99mTc by using stannous fluoride (SnF2) method. Radiolabeling qualification, quality control and characterization of 99mTc-PQQ and its biodistribution studies in mice were performed and discussed. Effects of pH values, temperature, time and reducing
agents concentration on the radiolabeling yield were investigated. The quality control procedure of 99mTc-PQQ was determined by thin layer chromatography (TLC), radio high-performance liquid chromatography (RHPLC) and paper electrophoresis
methods. The average radiolabeling yield was 94 ± 1% under optimum conditions of 0.99 mg of PQQ, 30 μg of SnF2, 0.5 mg of ethylenediaminetetraacetic acid disodium salt (EDTA-2Na) and 18.5 MBq of Na99mTcO4 at pH 6 and 25 °C with a response volume of 1 ± 0.1 mL. 99mTc-PQQ was stable and anionic. Lipid–water partition coefficient of 99mTc-PQQ was −1.49 ± 0.16. The pharmacokinetics parameters of 99mTc-PQQ were t
1/2α = 18.16 min, t
1/2β = 100.45 min, K
12 = 0.013 min−1, K
21 = 0.017 min−1, K
e = 0.016 min−1, AUC (area under the curve) = 1040.78 ID% g−1 min and CL (plasma clearance) = 0.096 mL min−1. The dual-exponential equation was Y = 10.88e−0.038t
+ 5.21e−0.0069t
. The biodistribution of 99mTc-PQQ was studied in ICR (Institute for Cancer Research 7701 Burhelme Are., Fox Chase, Philadelphia, PA 1911 USA) mice. In
vitro autoradiographic studies clearly showed that the 99mTc-PQQ radioactivity accumulated predominantly in the hippocampus and cortex, which had a high density of N-methyl-d-aspartate Receptor (NMDAR). The enrichment can be blocked by NMDAR redox modulatory site antagonists-ebselen (EB) and 99mTc-PQQ is therefore a promising candidate for the molecular imaging of NMDAR. To date, however, there have been no studies
characterizing 99mTc-PQQ. 相似文献
948.
949.
950.
Xihan Ma Qin Wei Shanshan ZhangLin Shi Zhong Zhao 《Journal of Analytical and Applied Pyrolysis》2011,91(2):338-343
Based on differences in acidity, organic acids and phenols were enriched by pH gradient extraction method from walnut shell pyroligneous acid. Contents of organic acids and phenols were measured by acid-base titration method and Folin colorimetric assay, respectively to assess the effectiveness of the extraction. In addition, the antimicrobial activity of the organic acids and antioxidant activity of phenols extracted were investigated. Chemical components of the extracts that were from the optimal concentrations of NaHCO3 and NaOH were measured by GC-MS. The results showed that 5% NaHCO3 could enrich the highest amount of organic acids, whereas 4% NaOH could enrich the highest amount of phenols. The enriched organic acids exhibited high antimicrobial activity, and the enriched phenols exhibited antioxidant activity under low concentrations, and demonstrated dosage dependency. 相似文献