氟化镁锶中铕和铽的电荷迁移及其平衡解析

在氩气氛中，合成子ＳｒＭｇＦ４：ｘＥｕ，ｙＴｂ复合氟化物磷光体，该体系中Ｅｕ＾３＋和Ｅｕ＾２＋共存，随共掺入Ｔｂ浓度的增加，Ｅｕ＾３＋的荧光发射强度降低，Ｅｕ＾３＋的发光增强，并且Ｅｕ＾２＋的ＥＳＲ信号增强，认为Ｅｕ＾３＋和Ｔｂ３＋之间存在的电荷迁移，即Ｅｕ＾３＋Ｔｂ＾３＋→Ｅｕ＾２＋＋Ｔｂ＾４＋，通过半量手段研究了这一电荷迁移反应的平衡常数。     

[Cu(H2O)(phen)2](CIO4)2的晶体结构

标题化合物晶体属三斜晶系;空间群为P₁;晶胞参数:a=8.182(2)Å,b=10.389(2)Å,c=16.261(5)Å,α=99.38(2)°,β=89.97(2)°,γ=113.18(2)°;Z=2,两个phen上的四个N原子和一个配位水中的O原子围绕中心体Cu原子形成一个畸变的三角双锥构型,配位水与阴离子ClO₄^-中的O原子形成氢键。     

Chemical constituents of Taraxacum formosanum

Three new compounds, taraxacine-A (1), taraxacine-B (2) and taraxafolin (3) together with twenty-five known compounds, which include two beta-carboline alkaloids, two indole alkaloids, two chlorophylls, two flavonoids, one coumarin, two triterpenoids, one monoterpenoid, one ionone, four steroids and eight benzenoids, were isolated and characterized from the fresh aerial parts of Taraxacum formosanum. Structures of new compounds were determined by spectral analysis.     

三异丙氧钐催化下醇的选择性乙酰化反应

本文报道了三异丙氧钐(5%)催化下，以乙酸乙酯为乙酰化试剂醇的选择性乙酰化反应。此法操作简便，产率良好。     

VO(PMBP)2·nL型加合物的合成和性质研究

本文合成了四个VO(PMBP)₂·nL型加合物,元素分析确定其组成为VO(PMBP)₂·2H₂O、VO(PMBP)₂·py、VO(PMBP)₂·β-MP·H₂O、VO(PMBP)₂·γ-MP,其中PMBP、py、β-MP、γ-MP分别为1-苯基-3-甲基-4-苯甲酰吡唑酮-5,吡啶,3-甲基吡啶、4-甲基吡啶.通过摩尔电导、差热热重分析、红外光谱、电子光谱、顺磁共振波谱等方法研究了加合物的性质.     

共价氢化物与汞离子反应的研究 Ⅰ 痕量锑高灵敏度的分析新方法

本文提出了一个氢化物发生一冷原子荧光法间接测定痕量锑的新方法。考察了各种实验条件,并将此法用于水及沉积物标样分析,结果令人满意,对水中锑检出限为0.1μg/L,回收率96％～102％。     

Gold nanoshells on polystyrene cores for control of surface plasmon resonance

A method is presented for synthesizing core-shell structures consisting of monodisperse polystyrene latex nanospheres as cores and gold nanoparticles as shells. Use of polystyrene spheres as the core in these structures is advantageous because they are readily available commercially in a wide range of sizes, and with dyes or other molecules doped into them. Gold nanoparticles, ranging in size from 1 to 20 nm, are prepared by reduction of a gold precursor with sodium citrate or tetrakis(hydroxymethyl)phosphonium chloride (THPC). Carboxylate-terminated polystyrene spheres are functionalized with 2-aminoethanethiol hydrochloride (AET), which forms a peptide bond with carboxylic acid groups on their surface, resulting in a thiol-terminated surface. Gold nanoparticles then bind to the thiol groups to provide up to about 50% coverage of the surface. These nanoparticles serve as seeds for growth of a continuous gold shell by reduction of additional gold precursor. The shell thickness and roughness can be controlled by the size of the nanoparticle seeds as well as by the process of their growth into a continuous shell. By variation of the relative sizes of the latex core and the thickness of the gold overlayer, the plasmon resonance of the nanoshell can be tuned to specific wavelengths across the visible and infrared range of the electromagnetic spectrum, for applications ranging from the construction of photonic crystals to biophotonics. The position and width of the plasmon resonance extinction peak are well-predicted by extended Mie scattering theory.     

壳聚糖／聚丙烯酸聚电解质复合物膜对水／有机液体系的渗透汽化性能

以壳聚糖和聚丙烯酸为原料制备了聚电解质复合物膜，并对其分离水／乙醇体系的渗透汽化特性和浓度，温度，化学组成等因素的影响进行了研究，发现后处理方法对复合物膜的分离性能影响很大。同时对其它水／有机液体系，该膜也具备优异的分离性能。     

The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative

O-Phosphoryl serine derivative can perform serf-catalytic esterification reaction in the mixture of CH3OH and CHCl3 at the room temperature. The phosphoryl group participation was the key step of the esterification. This type of reactions were proposed through an intermediate of mixed phosphoric-carboxylic anhydride that might provide a clue to the function of the phosphoryl group in the phosphorylated enzymes and in the prebiotic synthesis of protein.     

显微共焦拉曼光谱研究电化学合成聚苯胺膜

显微共焦拉曼技术被用来研究电化学合成的聚苯胺（PANI）膜. 研究结果表明：在不同的激发光聚焦深度，聚苯胺膜的拉曼光谱有明显变化.从而反映出聚苯胺膜的掺杂程度在膜生长过程中随膜厚度的增长而增加. 并由X射线电子能谱（XPS）和紫外吸收光谱（UV）分析证实.