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101.
Yao Xiao Yan‐Fang Zhu Wei Xiang Zhen‐Guo Wu Yong‐Chun Li Jing Lai Shi Li Enhui Wang Zu‐Guang Yang Chun‐Liu Xu Ben‐He Zhong Xiao‐Dong Guo 《Angewandte Chemie (International ed. in English)》2020,59(4):1491-1495
Demands for large‐scale energy storage systems have driven the development of layered transition‐metal oxide cathodes for room‐temperature rechargeable sodium ion batteries (SIBs). Now, an abnormal layered‐tunnel heterostructure Na0.44Co0.1Mn0.9O2 cathode material induced by chemical element substitution is reported. By virtue of beneficial synergistic effects, this layered‐tunnel electrode shows outstanding electrochemical performance in sodium half‐cell system and excellent compatibility with hard carbon anode in sodium full‐cell system. The underlying formation process, charge compensation mechanism, phase transition, and sodium‐ion storage electrochemistry are clearly articulated and confirmed through combined analyses of in situ high‐energy X‐ray diffraction and ex situ X‐ray absorption spectroscopy as well as operando X‐ray diffraction. This crystal structure engineering regulation strategy offers a future outlook into advanced cathode materials for SIBs. 相似文献
102.
103.
Zu‐Shun Xu Zi‐Wei Deng Xiao‐Xi Hu Lei Li Chang‐Feng Yi 《Journal of polymer science. Part A, Polymer chemistry》2005,43(11):2368-2376
Monodisperse polystyrene microspheres with diameters of 200–500 nm were prepared by dispersion polymerization with microwave irradiation with poly(N‐vinylpyrrolidone) as a steric stabilizer and 2,2′‐azobisisobutyronitrile as a radical initiator in an ethanol/water medium. The morphology, size, and size distribution of the polystyrene microspheres were characterized with transmission electron microscopy and photon correlation spectroscopy, and the formed films of the polystyrene dispersions were characterized with atomic force microscopy. The effects of the monomer concentration, stabilizer concentration, and initiator concentration on the size and size distribution of the polystyrene microspheres were investigated. The polystyrene microspheres prepared by dispersion polymerization with microwave irradiation were smaller, more uniform, and steadier than those obtained with conventional heating. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2368‐2376, 2005 相似文献
104.
VALUE-AT-RISK的核估计理论 总被引:5,自引:0,他引:5
如何根据历史数据估计Value-at-Risk(VaR);是风险分析与管理中一个重要的基本问题.木文基于非参数核估计方法,通过拟合实际数据过程的分布,构造了VaR的估计.在合适的相依数据条件下,证明了该估计量的渐近正态性,并给出了渐近方差的估计.由此表明:本文所构造的估计量不仅比参数模型具有更广泛的适应性,而且如同参数模型具有n~(-1/2)的收敛速度.本文假设的数据过程避免使用混合性,可很好地适用于金融管理中广泛应用的ARMA与GARCH模型族及非线性模型. 相似文献
105.
IrnmobilisedaIninoacylaseisanotablecatalystforthekineticresolutionofN-acetyl-D,L-aIninoacidsandquitealotofresearchworkhasbeeninvolvedonaminoacylase~bilisationswithitscarriers.lTheauthorshaverePortedthattheaIninosilicagelspreparedbyanlinProvedmethodwereeffechveforchymotryPsininunobilisahon,'l'butitwasnotproperforaIninoacylasetriobilisahon.InordertodevelopasahsfactorysurfacesmictUreofsilicagelsforaIninoacylasetriobilisation,tWokindsofreactivegrouPs,theN,N-diethylaIninogrouPandthehydroxygr… 相似文献
106.
DelphiniumsoulieiFranch,distributedintheSouthwestofGansuProvince,WestofSichuanProvince,andtheQinghaiProvinceofChina,isreportedtopossessantipyretic,antitoxic,antidysenteric,andantidiarrhealactivities.linthisstUdy,twonewditerpenoidalkaloidswereisolatedfromthewholeplantsofD.soulidi.TheirstructUreswereestablishedassoulineA(l)andsoulineB(2)onthebasisofspectraldata.SoulineA(l)wasisolatedascolorlesscrystals.Themolecularionpeakatm/z477.2678initsHREIMSrevealedthemolecularformulaC26H39NO7(cafe… 相似文献
107.
108.
PreviousinvestigationsrevealedthatsomeVitisspeciesarerichinoligostilbenes'-'.InthecontinuinginvestigationforoligostilbenesfromVitisspp-,wehaveisolatedanoveltetrastilbene,davidolA1,alongwithresveratrol',( )-E-viniferin',ampelopsinC',ampelopsinE',vitisinAl'3andhopeaphenol7-9fromthestemsofVitisdavidiiFoex9.ThedriedpowderedstemsofVdavidiiFoex.wasextractedwithacetone.TheacetoneextractwasthenconcentratedunderreducedpressureandfractionatedbyaseriesofsolventpartitionintoanEtOAc-solublephenolicfr… 相似文献
109.
A discussion is given of the relation between the maximum functionaltheorem and Schwinger's variational principle, and it is shownthat the bound given by Schwinger's principle is better thanor the same as that given by the maximum functional theorem. 相似文献
110.