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101.
It has been shown that the depotarisation end-point technique, based on the phenomenon of a sudden out-of-balance current, produced by the establishment of a new redox potential at the indicator electrode in a pre-balanced circuit, can also be applied to precipitation titrations. The use of a platinum indicator electrode instead of one made of silver, and determination in very dilute solution, yield better results than those obtained using the classical potentiometric method. 相似文献
102.
D. Minić Nada Štrbac I. Mihajlović Ž. Živković 《Journal of Thermal Analysis and Calorimetry》2005,82(2):383-388
In this paper, the results of copper-lead matte investigations are presented. Investigated copper-lead matte is intermediate
product of the lead production in TREPCA-Zvečan. In the first part of the paper characterization of starting material is presented,
consisting of: chemical composition analysis (XRQ), scanning electron microscopy (SEM) and diffractometry (XRD). Thermal properties
of investigated matte were determined using differential thermal analysis (DTA) at characteristic temperatures. Using results
of induced analysis, mechanism of matte oxidation process was determined. In the second part of the paper kinetic parameters
describing oxidative roasting of copper-lead matte are presented. For activation energy calculations, non-isothermal methods
defined by Kissinger and Ozawa were used [1, 2]. Kinetic equation describing oxidation process was determined using Sharps
method of reduced half time of reaction [3]. 相似文献
103.
Zorica?Crnjak Orel Egon?Matijevi? Dan?V.?GoiaEmail author 《Colloid and polymer science》2003,281(8):754-759
Uniform, spherical CuCl particles were obtained by mixing aqueous solutions of CuCl 2 and ascorbic acid in the presence of polyvinylpyrrolidone (PVP) as dispersing agent. The size and the uniformity of the resulting particles depended on the volume ratio of the reactant solutions, their concentrations, the distribution of the stabilizers, and the mixing method. The single jet precipitation yielded large spheres of broad size distributions, while the particles obtained by the double jet technique were rather uniform in size. The final colloidal CuCl particles were formed by the aggregation of nanocrystals, initially generated in the system. Depending on the pH of the reaction mixture, these particles slowly change to large CuCl crystals on aging in the mother liquor. 相似文献
104.
Milivoj Lovrić 《Journal of Electroanalytical Chemistry》1981,123(2):373-378
Recently proposed chemically prepared electrodes are coated with a thin, permeable, insulating, inert film which does not react with the depolarizer, does not allow depolarization on its surface and does not change the standard constant of the depolarization rate. It only changes the diffusion coefficient of a certain ion near the surface of the electrode. In this article, the theory of a reversible reduction of a simple ion at a film-coated stationary planar electrode is developed. If the film thickness is comparable with a diffusion layer thickness, considerable changes on the i-t curves can occur, but the position of the half-wave potential will remain constant. 相似文献
105.
106.
We calculate the density of states for the nondegenerate Anderson model for various values ofu=U/ andn
f
using the perturbation theory withu as the expansion parameter. Summing all the -independent self-energy diagrams, we use the Friedel sum rule and Ward identities to express the physical quantities in terms of the remaining -dependent part of the self-energy, which we evaluate to the 2nd order. The results for the spin and charge susceptibilities obtained in such a way compare rather well with the Bethe-ansatz results. The density of states exhibits different features in different parts of the parameter space. In Kondo region (u>1,n
f
1, i.e., –
f
~U/2), we obtain a many-body resonance (half-width T
K
) around the Fermi level and two broad peaks () at about
f
+n
f
U and
f
+U. In the VF region (u>1, and |
f
|) we obtain only two peaks (), one at about
f
and one between
f
+n
f
U and
f
+U. The consequences regarding the shape of the photoemission and inverse photoemission spectra of Ce intermetallics are discussed. 相似文献
107.
L. Janićijević 《Optical and Quantum Electronics》1985,17(2):125-138
Realized as an interferogram of a spherical and a cylindrical wave, the elliptical hologram is treated as a plane diffracting grating which produces Fresnel diffraction of a simple astigmatic gaussian incident wave. It is shown that if the principal axes of the incident beam coincide with the principal axes of the hologram, the diffracted wave field is composed of three different astigmatic gaussian waves, with their waists situated in parallel but distinct planes. The diffraction pattern, observed on a transverse screen, is the result of the interference of the three diffracted wave components. It consists of three systems of overlapped second-order curves, whose shape depends on the distance of the observation screen from the hologram, as well as on the parameters of the incident wave beam and the hologram. The results are specialized for gratings in the form of circular and linear holograms and for the case of a stigmatic gaussian incident wave, as well as for the normal plane-wave incidence on the three mentioned types of hologram. 相似文献
108.
Zusammenfassung Eine Reihe von Metallkomplexen des 2,5-Dibenzoyl-3,4-dihydroxy-selenophens wurden spektroskopisch untersucht. Das Verhalten des Wismutkomplexes und die Möglichkeiten einer spektrophotometrischen Wismutbestimmung auf diesem Wege wurden eingehend studiert.
Herrn Univ.-Prof. Dr.Hans Lieb zum 80. Geburtstag gewidmet. 相似文献
Summary A spectroscopic examination was made of a series of metal complexes of 2,5-dibenzoyl-3,4-dihydroxyselenophen. The behavior of the bismuth complex and the possibilities of a spectrophotometric method of determining bismuth in this manner were studied thoroughly.
Herrn Univ.-Prof. Dr.Hans Lieb zum 80. Geburtstag gewidmet. 相似文献
109.
V. Lazic F. Colao R. Fantoni V. Spizzichino S. Jovićević 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
Laser Induced Breakdown Spectroscopy (LIBS) was applied on sediments directly under water. The aim of the research was to develop a method for measuring the sediment elemental composition, including minor elements, which could be implemented in-situ. The plasma was generated by a double-pulse, Q-Switched Nd:YAG laser operated at 1064 nm. For signal detection, both ICCD and non-gated, compact detectors were used. The major difficulties in underwater sediment analyses are related to the natural and laser induced surface roughness, and to the sample softness. The latter is responsible for the formation of particle clouds above the surface, which scatter both the laser and plasma radiation, and often results in breakdown formation above the analyzed surface. In such cases, a broad sonoluminescence emission from water, formed during the gas bubble collapse was sometimes registered. Under optimized experimental conditions, even by using a non-gated detector and single shot acquisition, it was possible to detect several minor sediment constituents, such as titanium, barium, manganese and others. A crude estimation of the Limit of Detection (LODs) for these elements was performed by underwater measurements on certified soils/sediments. Due to strong shot-to-shot fluctuations in the plasma temperature, well correlated calibration curves, aimed for quantitative analyses, could only be obtained after applying an appropriate data processing procedure. The latter selects automatically only the spectra characterized by similar plasma parameters, which are related to their continuum spectral distribution. Application of such a procedure improves the measurement accuracy also in other surroundings and on samples different from the ones analyzed here. 相似文献
110.
The paper presents a survey of the contamination level of the Danube river sediments along its course, between 849 km and 1162 km, during the period 1985–1988. Sampling was performed on several locations in the seasons with extreme hydrological conditions (spring, autumn). 相似文献