氢化物发生—原子荧光法测定不同产地绞股蓝及其根际土壤中As,Hg,Se

通过优化了的氢化物发生—原子荧光法测定了7个省产绞股蓝及其根际土壤中As,Hg,Se三种元素的含量,研究结果表明:7个省产绞股蓝中As,Hg,Se的含量存在较大差异,但As和Hg两种重金属元素含量均低于《药用植物及制剂进出口绿色行业标准》中As和Hg的限量标准。Se元素含量同根际土壤中Se元素含量显示极显著相关性,故湖北恩施富硒区产绞股蓝中Se含量明显高于其他6省产绞股蓝。研究结果可以初步判定,绞股蓝中Se元素主要来源于土壤,而As和Hg元素的积累则不同于Se元素,还可能受到大气气溶胶的干、湿沉降等因素的影响。     

SiH3+O(3P)反应机理的理论研究

利用abinitio方法对SiH3+O(3P)反应进行了理论研究,在MP2/6-311+G(d,p)水平上优化得到了反应途径上的反应物、中间体、过渡态和产物的几何构型,并在QCISD(T)/6-311+G(d,p)水平上进行单点能计算.计算结果表明,SiH3+O(3P)→IM1→TS3→IM2→TS8→HOSi+H2为主反应通道,其他可能存在的次要产物有HSiOH+H、H2SiO+H和HSiO+H2.HOSi、HSiO和HSiOH(cis)还可能进一步解离生成SiO.另外,计算结果对SiH4+O(3P)反应机理中存在的争议给出了可能的解释,认为Withnall等人在实验中观察到的产物HSiOH、H2SiO和SiO并不是SiH4+O(3P)反应的直接产物,而是来自副反应SiH3+O(3P).     

Generation of minimally persistent circle formation for a multi-agent system

In this paper, two methods of generating minimally persistent circle formation are presented. The proposed methods adopt a leader-follower strategy and all followers are firstly motivated to move into the leader＇s interaction range. Based on the information about relative angle and relative distance, two numbering schemes are proposed to generate minimally persistent circle formation. Distributed control laws are also designed to maintain the desired relative distance between agents. The distinctive features of the proposed methods are as follows. First, only 2n - 3 unilateral communication links for n agents are needed during the circle formation process and thus the communication complexity can be reduced. In addition, the formation topology is kept fixed for the whole motion and achieves a self-stability property. Finally, each follower keeps a regualr interval with its neighbors and the formation converges to a uniform circle formation. Simulation results are also provided to demonstrate the effectiveness of the proposed methods.     

抽运光与信号光的光强重叠因子和掺铒玻璃波导放大器的增益特性

在掺铒玻璃波导放大器（EDWA）的三能级速率-传输方程中,考虑两次离子交换工艺中波导掩模窗口宽度w不同所导致的抽运光、信号光模场与光强分布的不同,讨论不同w对EDWA增益特性的影响,得到光强分布的数值解.引入描述波导中抽运光和信号光的归一化光强重叠因子,对EDWA的传统近似解提出修正,得到了修正解,使其更加接近光强分布的数值解.模拟结果表明,在条波导长度为4 cm、抽运光波长为980 nm、功率为80 mW、信号光波长为1534 nm、功率为-10 dBm条件下,不同w所导致EDWA的增益差别可达297 dB.修正解的结果比传统近似解更加接近光强分布的数值解.修正解对于EDWA的理论研究、器件设计具有指导作用. 关键词： 集成光学 掺铒玻璃波导放大器 重叠积分因子 增益     

Sequential over-barrier ionization of multi-electron atoms in the tens-to-hundreds keV/u energy range

Our previous work on the classical over-barrier ionization model for helium double ionization is extended to the complex multi-electron system of Ne.The total and q-fold ionization cross sections are calculated at energies ranging from a few tens to several hundred keV/u.The calculation results are in good agreement with the experimental data,and the energy dependence of the cross sections suggests that the multi-ionization of a strong perturbated complex atom is probably the sequential over-barrier ionization process.     

Filter-free ultra-wideband doublet pulses generation based on wavelength conversion and fiber dispersion effect

Filter-free ultra-wideband (UWB) doublet pulse generation is experimentally demonstrated in the optical domain based on cross-gain modulation (XGM) in semiconductor optical amplifier (SOA) and UWB-over-fiber technology is implemented by exploiting dispersion-induced pulse broadening effect in single-mode fiber (SMF). In our proposed system, the SOA generates a polarity-inversed Gaussian pulse train with respect to the injected one through the XGM. After a piece of SMF, the bandwidth of polarity-reversed Gaussian pulse broadens due to the induced dispersion. After the combination of the two light waves with a suitable time delay between them, UWB pulse is obtained. The key parameters for UWB pulse, including central frequency, 10 dB bandwidth, as well as fractional bandwidth are experimentally obtained with 8 GHz, 9.9 GHz and 123% respectively. The generated UWB doublet pulse conforms with the UWB definition of Federal Communications Commission (FCC).     

A density-functional theory investigation on desorption of O2 on Sn（111） and its comparison with initial oxidation on the X（111） （X=Si,Ge, Sn,Pb） surfaces

<正>The first-principles calculations are performed to investigate the adsorption of O₂ molecules on an Sn（111） 2×2 surface.The chemisorbed adsorption precursor states for O₂ are identified to be along the parallel and vertical channels, and the surface reconstructions of Sn（lll） induced by oxygen adsorption are studied.Based on this,the adsorption behaviours of O₂ on X（111）（X=Si,Ge,Sn,Pb） surfaces are analysed,and the most stable adsorption channels of O₂ on X（111）（X=Si,Ge,Sn,Pb） are identified.The surface reconstructions and electron distributions along the most stable adsorption channels are discussed and compared.The results show that the O₂ adsorption ability declines gradually and the amount of charge transferred decreases with the enhancement of metallicity.     

A method for extracting human gait series from accelerometer signals based on the ensemble empirical mode decomposition

In this paper,the ensemble empirical mode decomposition(EEMD) is applied to analyse accelerometer signals collected during normal human walking.First,the self-adaptive feature of EEMD is utilised to decompose the accelerometer signals,thus sifting out several intrinsic mode functions(IMFs) at disparate scales.Then,gait series can be extracted through peak detection from the eigen IMF that best represents gait rhythmicity.Compared with the method based on the empirical mode decomposition(EMD),the EEMD-based method has the following advantages:it remarkably improves the detection rate of peak values hidden in the original accelerometer signal,even when the signal is severely contaminated by the intermittent noises;this method effectively prevents the phenomenon of mode mixing found in the process of EMD.And a reasonable selection of parameters for the stop-filtering criteria can improve the calculation speed of the EEMD-based method.Meanwhile,the endpoint effect can be suppressed by using the auto regressive and moving average model to extend a short-time series in dual directions.The results suggest that EEMD is a powerful tool for extraction of gait rhythmicity and it also provides valuable clues for extracting eigen rhythm of other physiological signals.     

Diffusion Monte Carlo analysis of the crossover from three to two dimensions for trapped Bose gases

We investigate the crossover from three to two dimensions for harmonically trapped hard-sphere Bose gases by varying the aspect ratio of the trapping potential. The diffusion Monte Carlo method is used to calculate both the ground-state energy and structural properties. The effect of trap anisotropy, interparticle interaction, and number of particles on the ground-state properties is discussed. Our results show that the minimum value of the aspect ratio at which the system reaches an asymptotic equilibrium distribution in the weakly confined direction decreases with increasing scattering length, while the minimum value of the aspect ratio at which the system enters the quasi-two-dimensional (2D) regime increases as both the scattering length and the number of particles increase. Additionally, the role played by particle correlations is proved to be more pronounced in the quasi-2D system than in the three-dimensional (3D) system by directly comparing the ground-state properties for the two cases.     

Heteronuclear Multiple-Quantum Coherence NMR Spectroscopy of Im-cyt C

Some ¹³C chemical shifts of the CH_n groups in the aliphatic side chains of Im-cyt c have been determined for the first time based on the H chemical shifts of their attached protons with the aid of heteronuclear multiple-quantum coherence (HMQC) spectroscopy. Comparison of chemical shifts of these specifically assigned ¹³C and H resonances from Im-cyt c with those from cyt c indicates that ¹³C-NMR spectra may provide an opportunity to probe the electronic structure and conformational changes induced by axial ligand substitution.