全文获取类型
收费全文 | 10785篇 |
免费 | 1983篇 |
国内免费 | 1295篇 |
专业分类
化学 | 7853篇 |
晶体学 | 65篇 |
力学 | 668篇 |
综合类 | 82篇 |
数学 | 1090篇 |
物理学 | 4305篇 |
出版年
2024年 | 43篇 |
2023年 | 284篇 |
2022年 | 390篇 |
2021年 | 436篇 |
2020年 | 492篇 |
2019年 | 431篇 |
2018年 | 363篇 |
2017年 | 302篇 |
2016年 | 537篇 |
2015年 | 470篇 |
2014年 | 573篇 |
2013年 | 812篇 |
2012年 | 999篇 |
2011年 | 978篇 |
2010年 | 649篇 |
2009年 | 642篇 |
2008年 | 715篇 |
2007年 | 624篇 |
2006年 | 548篇 |
2005年 | 483篇 |
2004年 | 372篇 |
2003年 | 331篇 |
2002年 | 285篇 |
2001年 | 215篇 |
2000年 | 216篇 |
1999年 | 258篇 |
1998年 | 215篇 |
1997年 | 196篇 |
1996年 | 208篇 |
1995年 | 180篇 |
1994年 | 143篇 |
1993年 | 126篇 |
1992年 | 103篇 |
1991年 | 74篇 |
1990年 | 87篇 |
1989年 | 59篇 |
1988年 | 52篇 |
1987年 | 51篇 |
1986年 | 34篇 |
1985年 | 30篇 |
1984年 | 18篇 |
1983年 | 9篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1957年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Chongyu Mei Junqiao Ding Bing Yao Yanxiang Cheng Zhiyuan Xie Yanhou Geng Lixiang Wang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1746-1757
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007 相似文献
32.
Generalized KKM Type Theorems in FC-Spaces with Applications (I) 总被引:1,自引:0,他引:1
Xie Ping Ding 《Journal of Global Optimization》2006,36(4):581-596
The class KKM(X,Y) (resp., s-KKM(X,Y,Z)) of set-valued mappings with KKM (resp., s-KKM) property is introduced in FC-spaces without any convexity structure. Some generalized KKM (resp., s-KKM) type theorems are proved in FC-spaces under much weak assumptions. As applications, some new section theorems and coincidence theorems are established in FC-spaces. These theorems generalize many known results in literature. The further applications of these results will be given in a follow-up paper. 相似文献
33.
34.
1IntroductionThispaperisconcernedwithpositivesolutionOfthesemilinearheatequationswithlocalizedreactionssubjecttoeitherinitialconditions(Cauchyproblem)ortheinitialandboundary-value(DirichletorNeumanntype)conditionswherenisaboundeddomaininRe,icEO.Equations(1.1)canbethoughtofasamodeltodescribesomephysicalphenomena(heatpropagation,chemicalreaction)inwhichthenonlinearreactionsinadynndcalsystemtakesplaceonlyatasinglesite.InthesequelforconvenienceweshallsamplycalltheCauchy,initial-Direchlet,orini… 相似文献
35.
We give some sufficient conditions for proper lower semicontinuous functions on metric spaces to have error bounds (with exponents).
For a proper convex function f on a normed space X the existence of a local error bound implies that of a global error bound. If in addition X is a Banach space, then error bounds can be characterized by the subdifferential of f. In a reflexive Banach space X, we further obtain several sufficient and necessary conditions for the existence of error bounds in terms of the lower Dini
derivative of f.
Received: April 27, 2001 / Accepted: November 6, 2001?Published online April 12, 2002 相似文献
36.
凸集的广义Reuleaux三角形 总被引:1,自引:1,他引:0
常宽凸集的面积最小者为Reulaux三角形,而非常宽凸集的面积最小者为何呢?它就是本文将给出的广义Reuleaux三角形△R。 相似文献
37.
In this paper, we study the existence, uniqueness, and the global exponential stability of the periodic solution and equilibrium of hybrid bidirectional associative memory neural networks with discrete delays. By ingeniously importing real parameters di > 0 (i = 1,2, …, n) which can be adjusted, making use of the Lyapunov functional method and some analysis techniques, some new sufficient conditions are established. Our results generalize and improve the related results in [9]. These conditions can be used both to design globally exponentially stable and periodical oscillatory hybrid bidirectional associative neural networks with discrete delays, and to enlarge the area of designing neural networks. Our work has important significance in related theory and its application. 相似文献
38.
In this paper, according to the molecular fragment principle, a series of eight ternary luminescent lanthanide complex systems were assembled, and whose compositions were determined with elemental analysis and infrared spectrum: Ln(MA)3(L)·H2O, where Ln = Sm, Eu, Tb, Dy; HMA = α‐methylacrylic acid; L = 1,10‐phenanthroline (phen), 2,2′‐bipyridine (bipy). The photophysical properties of these functional molecular systems were studied with ultraviolet‐visible absorption spectrum, and fluorescence excitation and emission spectrum. It was found that the heterocylic compounds (phen and bipy) act as the main energy donor and luminescence sensitizer for their suitable energy match and effective energy transfer to the emission energy level of Ln3+ ions. MMA ligand was only used as the terminal structural ligand to influence the luminescence. Especially terbium complex systems show the strongest luminescence for the optimum energy match and transfer between phen (bipy) and Tb3+ ion. 相似文献
39.
40.
The clusters of Eu3+ ion in Eu(DBM)3Phen-doped polymethyl methacrylate (PMMA) have been studied by three means. The relative fluorescence intensity ratio of the 5D0 → 7F2 to 5D0 → 7F1 transitions with different concentrations of Eu3+ in Eu(DBM)3Phen-doped PMMA and metastable-state (5D0) lifetime dependence on Eu3+ concentration are analyzed. The analysis indicates that there are no clustering effects in Eu3+ ions of Eu(DBM)3Phen-doped PMMA when the Eu3+ doping concentration is up to 1.0 wt.-%. At the same time, the clustering effect has not been observed by the scanning near-field optical microscopy (SNOM) in Eu(DBM)3Phen-doped PMMA with 1.0 wt.-% of Eu3+ ions. The analysis reveals that a high concentration of Eu3+ can be incorporated into polymer optical fiber (POF) without clustering effect.OCIS codes: 180.5810, 300.6280, 250.5460, 160.5690. 相似文献