拉曼喷泉原子钟

利用托曼光场代替喷泉原子钟的微波腔实现拉曼喷泉原子钟.将分离托曼光场技术与冷原子喷泉技术相结合.避免了存真空腔内放置微波腔,简化了真空系统.同时还保持了很高的准确度.采用半经典理论研究了冷原子喷泉与托曼光场的相互作用过程.得到了冉赛(Ramsey)条纹.比较了托曼喷泉原子钟与热铯束拉曼原子钟,前者有更小的体积和功耗,其精度可能达到或超过商用小铯钟.还比较了拉曼喷泉原子钟与微波喷泉原子钟的差别,分析了光子反冲的影响,提出利用同向传播和相向传播的两台拉曼原子钟测最精细结构常数.     

Design,Synthesis, and In Vitro and In Vivo Antifungal Activity of Novel Triazoles Containing Phenylethynyl Pyrazole Side Chains

A series of triazole derivatives containing phenylethynyl pyrazole moiety as side chain were designed, synthesized, and most of them exhibited good in vitro antifungal activities. Especially, compounds 5k and 6c showed excellent in vitro activities against C. albicans (MIC = 0.125, 0.0625 μg/mL), C. neoformans (MIC = 0.125, 0.0625 μg/mL), and A. fumigatus (MIC = 8.0, 4.0 μg/mL). Compound 6c also exerted superior activity to compound 5k and fluconazole in inhibiting hyphae growth of C. albicans and inhibiting drug-resistant strains of C. albicans, and it could reduce fungal burdens in mice kidney at a dosage of 1.0 mg/kg. An in vivo efficacy evaluation indicated that 6c could effectively protect mice models from C. albicans infection at doses of 0.5, 1.0, and 2.0 mg/kg. These results suggested that compound 6c deserves further investigation.     

Porous Carbon Nitride Frameworks Derived from Covalent Triazine Framework Anchored Ag Nanoparticles for Catalytic CO2 Conversion

Porous carbon nitride frameworks (PCNFs) with uniform and rich nitrogen dopants and abundant porosity were successfully fabricated through the direct carbonization of the covalent triazine frameworks (CTFs) at different pyrolysis temperatures and used as supports to anchor and stabilize Ag nanoparticles (NPs) for catalytic CO₂ conversion. Importantly, the pyrolysis temperature plays a crucial role in the properties of porous carbon nitride frameworks. The material carbonized at 700 °C showed the highest surface area and micro- and mesoporous structure with a certain interlayer distance. Taking advantage of their unique surface characteristics, PCNF-supported Ag NP catalysts (Ag/PCNF-T, T=pyrolysis temperature) were prepared by a simple chemical method. A series of characterizations revealed that Ag NPs are embedded in the porous carbon nitride frameworks and confined to a relatively small size with high dispersion owing to the assistance of the abundant surface groups and porous structures. The as-obtained Ag/PCNF-T catalysts, especially Ag/PCNF-700, showed excellent catalytic activity, selectivity, and stability for the carboxylation of CO₂ with terminal alkynes under mild conditions. This can be due to the existence of abundant nitrogen atoms and diverse porosity, which resulted in highly efficient catalytic activity and stability.     

双色光光伏空间孤子的形成条件及其应用

以折射率改变为正的光伏晶体为例，讨论在其中形成双色光光伏空间孤子的条件-一般而言，在满足上述条件的情况下，双色光可以形成双色光亮孤子、双色光暗孤子、一亮一暗孤子-对于一个波长的光（ray2）单独不能形成亮孤子（它的Glass系数与背景光的Glass系数之比R2小于１）的情况，如果再加上一束另一个波长的光（ray1），且其Glass系数与背景光的Glass系数之比R1大于１，则在一定条件下，这个双色光中两个颜色的光可以都形成亮孤子-还讨论了ray1的光强对孤子宽度的影响- 关键词： 双色光 光伏 空间孤子 全光开关     

扩散效应对光伏孤子相互作用的影响

用数值方法研究扩散效应对两个平行传播相干光伏孤子光束相互作用的影响. 结果表明，在扩散效应的影响下，两相干孤子光束同相相互作用不是使它们相互融合, 而是使它们趋向相互分离，且光束之间存在能量耦合；异相孤子相互作用不再是简单地互相排斥，在一定的条件下，两光束既互相排斥，又同时向同侧偏转. 关键词： 光伏空间孤子 相干相互作用 扩散效应     

亮-暗复色光伏孤子

提出一种实现亮-暗复色光伏孤子的方法.不共轴的两束同频率相干但反相的亮光束共同形成一中空光束，在此暗区引入另一束不同频率的亮光束.这三束光在一定条件下可以通过非线性相互作用而形成亮-暗复色孤子.通过数值分析的方法对这种亮-暗复色光伏孤子的空间动力过程进行了研究.研究表明，这种亮-暗结构具有光控光特性. 关键词： 亮-暗复色光伏空间孤子 光控光     

High-spectral-resolution rayleigh-mie lidar measurement of vertical aerosol and atmospheric profiles

A new two-channel ground-based high-spectral-resolution Rayleigh-Mie lidar and its operation is described. Upon the inversion of data collected during the night of August 14–15, 1990, with this unique lidar system (553.7 nm), vertical profiles of atmospheric parameters including temperature, potential temperature, pressure and density, as well as aerosol parameters including backscatter-ratio, extinction coefficient and backscatter phase function are determined.     

An incoherent Doppler lidar for ground-based atmospheric wind profiling

Received: 17 April 1996/Revised version: 7 October 1996