塑性全量理论的变分不等式模式及其无迭代解

变分不等式是解决一类带单侧约束的定常力学问题的有效数学工具.本文就弹塑性全量理论构造了等价的变分不等式模式,解除了弹塑性问题本构约束的不等式关系,比一般能量形式的描述更为简洁.它便于计算,具有可靠的数学依据,可以用二次规划法求解.计算时无需分级加载迭代,一步即可得收敛解.     

激光拉曼光谱在玉石鉴定中的应用

本文提出玉石品种鉴定的新方法———激光拉曼光谱法。测试了一系列玉石的标准拉曼谱     

聚芳醚酮环状低聚物的基质辅助激光解吸电离质谱表征

采用基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)技术分别对2种合成的聚芳醚酮环状低聚物进行了分析研究 ,并讨论了低聚物中不同聚合度离子组分的分布规律。实验结果表明MALDI-TOF-MS是分析环状低聚物直观、准确、快速的分析工具。     

Free boundary problem of non-steady state seepage flow

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非线性薄膜波导TE模色散特性的多层分割法计算

对于芯区为非线性介质、衬底及包层为线性介质的平板波导、提出用多层分割法分析芯区的模场,采用递推公式（等效于推广的传递矩阵法）求解传播常数与光功率间的依赖关系,该法适用地克尔型或非克尔型介质及芯区折射率非均匀的一般情形,实例计算结果与已有的精确数值计算结果十分符合。     

光电离速率影响大气压空气正流注分支的机理研究

大气压空气中的流注放电有广泛的理论和应用研究价值,包括雷电机理、输变电系统空气绝缘理论以及材料表面改性等.流注是一个快速发展的强电离区域,在传播过程中存在着一种重要的特点—分支现象.光电离为正流注发展提供必要的自由电子,且实验结果表明分支特征与流注头部的光电离速率密切相关.本文基于新的流注分支判据,采用了粒子网格单元与蒙特卡罗碰撞相结合(PIC-MCC)的三维放电模型(Pamdi3D)进行数值仿真验证.为了研究光电离速率对正流注分支的影响,仿真了毫米尺度间隙针-板电极正流注发展,系统研究了不同光电离参数的影响.当减小氮气-氧气比例、光子吸收截面或光电离效率系数后,流注均更早地出现分支现象.这些计算结果表明大气压空气中流注头部光电离速率的降低将导致其发生分支的概率更高.     

FTIR investigation of the effects of ultra-strong static magnetic field on the secondary structures of protein in bacteria

Secondary structures of protein in Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) exposed to the ultra-strong static magnetic field (SMF) were investigated by Fourier transformation infrared spectroscopy (FTIR). Difference index D value of amide I (1600–1700 cm⁻¹) showed that the ultra-strong magnetic field had little impact on S. aureus, but had strong impact on E. coli. The results indicated that 3.46–9.92% of the disorder coils in the secondary structures of protein in E. coli were turned into α-helices under SMF while applying deconvolution and curve fitting to amide I. At the same time, intermolecular β-sheets transforming into intramolecular ones suggested that cohesion among protein molecules had been destroyed and intramolecular hydrogen bonds strengthened. All the differences among the compositions of protein’s secondary structures in E. coli were mostly due to the varying degrees of various proteins affected by the magnetic field. The results may provide new insights into the structural changes of proteins induced by the SMF.     

电光调制器的温度特性及其最优化设计

利用线性电光效应的波耦合理论对铌酸锂晶体电光调制器的温度特性进行研究,给出了不同光波波矢和晶体光轴夹角情况下电光效应的温度变化特性,发现可以利用角度调节来克服电光调制器的温度敏感性;在此基础上,进一步对电光调制器进行了最优化设计,得到一个半波电压小(几十伏)、零场泄漏几乎为零(零电压出射光强和入射光强比为0．0027)、消光比达到365．6、温度性能稳定而且不需要透明电极的一个设计。     

Electroanalysis and simultaneous determination of dopamine and epinephrine at poly(isonicotinic acid)-modified carbon paste electrode in the presence of ascorbic acid

A carbon paste electrode modified with electropolymerized fills of isonicotinic acid was developed.The modified electrode shows excellent electrocatalytic activity toward the oxidation of both dopamine(DA)and epinephrine(EP).Separation of the reduction peak potentials for dopamine and epinephrine was about 357 mV in pH 5.3 phosphate buffer solution(PBS)and the character was used for the detection DA and EP simultaneously.The peak currents increase linearly with DA and EP concentration over the range of 8.0×10-5 to 7.0×10-4 mol/L and 5.0×10-6 to 1.0×10-4 mol/L with detection limits of 2 × 10-5 and 1×10-6 mol/L,respectively.The interference studies showed that the modified electrode exhibits excellent selectivity in the presence of large excess of ascorbic acid(AA).     

Chemistry and cytotoxic activities of polyketides produced by the mangrove endophytic fungus <Emphasis Type="Italic">Phomopsis</Emphasis> SP. ZSU-H76

A new polyketide, 2-(7′-hydroxyoxooctyl)-3-hydroxy-5-methoxybenzeneacetic acid ethyl ester (1), together with three known compounds dothiorelone A (2), B (3), and C (4) were isolated from the mangrove endophytic fungus Phomopsis sp. ZSU-H76 obtained from the South China Sea. Their structures were elucidated by spectroscopic methods, mainly 1D and 2D NMR spectroscopic techniques. Primary bioassays showed that 1 exhibited cytotoxicity against HEp-2 and HepG2 cells with IC₅₀ values of 25 and 30 μg/mL, respectively.