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201.
In trihydrated lanthanum acid-diphosphates LnHP2O7·3H2O, prepared from acid LnCl3 and Na4P2O7 solutions (pH=1), two crystal forms were obtained. Layered structures of two representative members of this family have been determined by single-crystal X-ray diffraction (XRD) technique. In the case of orthorhombic LaHP2O7·3H2O (type I), lanthanum cations are ninefold coordinated and diphosphate groups adopt a staggered (alternated) configuration. In the case of triclinic ErHP2O7·3H2O (type II), erbium cations are eightfold coordinated and diphosphate groups adopt an eclipsed configuration. In agreement with Infrared (IR) spectroscopic data, a bended configuration for diphosphate groups has been deduced. In both structures, one-dimensional chains of edge-sharing rare-earth polyhedra are linked together by diphosphate groups to form the phosphate layers. In both diphosphates, PO4 and HPO4 environments have been identified by 31P MAS-NMR technique. In the two compounds, OH groups of HPO4 tetrahedra point out of diphosphate planes interacting with adjacent layers. In La-diphosphate, the interaction between HPO4 groups and water molecules of adjacent layers is favored; however, in Er-diphosphate, the interaction between phosphate acid groups of contiguous layers is produced. Based on structural information deduced, differences detected in IR and NMR spectra of two disphosphates are discussed. 相似文献
202.
The best alternative to fight against corrosion is the use of an inhibitor, the purpose of this work is the formulation of a new biomass-based molecule against corrosion of carbon steel. Lignin was extracted using the Kraft process and phenylhydrazine molecules have been scratched. The influence of the lignin-phenylhydrazone(LP) on the corrosion of carbon steel in salt and the acidic medium was studied by the polarization resistance, the potentiodynamic polarization, and the electrochemical impedance spectroscopy. The results of these tests reveal that the behavior of the inhi-bitor is a mixed type. The adsorption mechanism of the inhibitor follows the Langmuir isothermal model. Gibbs energy shows that the process of inhibition of carbon steel is spontaneous. The SEM confirms that the inhibitor reduces the corrosion of the steel and stops the corrosion pitting phenomenon. The modified lignin shown as a good corrosion inhibitor in acid medium is highly saline with an efficiency> 96%. 相似文献
203.
Synthesis and Spectroscopic Properties of PdII and PtII Complexes with Monosulfide and Monoselenide Bis(phosphanyl)amine Ligands
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Oxidation of N,N‐bis(diphenylphosphanyl)naphthalen‐1‐amine ( 1 ) with elemental sulfur or gray selenium (1:1 molar ratio) gave the corresponding monosulfide and monoselenide bis(phosphanyl)amine ligands C10H7‐1‐N(P(E)Ph2)(PPh2) [E = S ( 2 ), Se ( 3 )], respectively. Reactions of 2 and 3 with MCl2(cod) (M = Pd, Pt) afforded [MCl2{ 2 ‐κ2P,S}] [M = Pd( 4 ), Pt( 5 )] and [MCl2{ 3 ‐κ2P,Se}] [M = Pd( 6 ), Pt( 7 )], respectively. In contrast, reactions of the same ligands with NiCl2(PPh3)2 resulted in deselenization and desulfurization, producing complex 8 with the formula [NiCl2{1‐κ2P,P}]. Ligands 2 and 3 , as well as their complexes 4 – 7 and 8 were identified and characterized by multinuclear NMR (1H, 13C, 31P, and 77Se NMR) spectroscopy, elemental analysis, and IR spectroscopy. Additionally, the molecular structure of 8 was obtained. 相似文献
204.
Bioassay Guided Isolation and Identification of a Cytotoxic Compound from Azadirachta indica Leaves
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Jessinta Sandanasamy Azhari Hamid Nour Saiful Nizam Tajuddin Abdurahman Hamid Nour Hazrulrizawati Abd Hamid Ahmad Ziad Sulaiman 《中国化学会会志》2015,62(8):680-688
This study aimed to investigate the structural features of the isolated flavonol glycoside, which might behave as a cytotoxic compound. The hexane, chloroform, ethyl acetate, and aqueous fractions of an 80% methanol solution of Neem (Azadirachta indica) (Family: Meliaceae) leaves were subjected to a cytotoxicity bioassay against brine shrimp, Artemia salina. The ethyl acetate fraction exhibited the highest cytotoxic effect, supported by the lowest lethal concentration, a LC50 value of 1.35±0.40 ppm. A compound, Quercetin 3‐O‐β‐D‐glucopyranoside, was isolated from the most toxic fraction of the ethyl acetate via preparative liquid chromatography and then identified via ultraviolet‐visible (UV‐Vis), infrared (IR), mass spectrum (MS) and nuclear magnetic resonance (NMR) analyses. The compound was further confirmed by physical state, color, solubility, and melting point determination. The cytotoxic results suggest that the leaf ethyl acetate fraction consists of toxic compounds, which point towards the isolation of Quercetin 3‐O‐β‐D‐glucopyranoside. 相似文献
205.
Anne‐Françoise Mingotaud Christophe Mingotaud Wissam Moussa 《Journal of polymer science. Part A, Polymer chemistry》2008,46(8):2833-2844
Solubilization of the hydrophobic Hoveyda‐Grubbs' catalyst in micellar aqueous phase has been achieved using dodecyl and cetyl ammonium chloride as surfactants. The domain of solubilization has been estimated before carrying out ring‐opening metathesis polymerization in these micellar solutions with a hydrophilic monomer. Kinetics orders have been determined relative to monomer, initiator, and surfactant. A good control of the molecular weight has been obtained for ratios [micelles]/[initiator] over 1. The better control of the polymerization obtained in micellar solution has been explained by a difference of reactivity leading to a more efficient initiation step in the presence of the micelles. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2833–2844, 2008 相似文献
206.
The variational static approximation is applied to the elastic scattering of low-energy positrons by argon atoms. A trial function including up to 10 terms is taken to allow for correlation, depending on the positron-nucleus separation only. This method excludes singularities and succeeds in improving the calculated phase shifts. Three versions have been applied depending on the way of inclusion of polarization effects. Results of the phase shifts and cross sections agree with other theoretical calculations as well as experimental values. Our version (ii) yields the best agreement with experiment. 相似文献
207.
Shaltout AA Allam MA Moharram MA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,83(1):56-60
The inorganic constituents of 5 different plants (leaves and stalks) were investigated by using Fourier transformer infrared spectroscopy (FTIR), X-ray diffraction (XRD) and thermal analysis including thermal gravimetric analysis (TGA), derivative thermogravimetry (DTG) and differential scanning calorimetry (DSC). These plants are Catha edulis (Khat), basil, mint, green tea and trifolium. The absorption bands of carbonate ions CO(3)(2-) was exhibited at 1446 cm(-1), and the phosphate ions PO(4)(3-) was assigned at 1105 and 1035 cm(-1). At high temperatures (600, 700 and 600°C) further absorption bands of the phosphate ions PO(4)(3-) was assigned at the frequencies 572, 617, 962, 1043 and 1110 cm(-1) and the vibrational absorption band of the carbonate ions CO(3)(2-) was assigned at 871, 1416 and 1461 cm(-1). X-ray diffraction and thermal analysis confirm the obtained results of FITR. Results showed that the main inorganic constituents of C. edulis and basil leaves are hydroxyapatite whereas the hydroxyapatite content in the other plant samples is less than that in case of C. edulis and basil plant leaves. 相似文献
208.
IR, 1H NMR, mass, XRD and TGA/DTA investigations on the ciprofloxacin/iodine charge-transfer complex
Refat MS El-Hawary WF Moussa MA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(5):1356-1363
Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH)·2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H?O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases. 相似文献
209.
A systematic study on the corrosion and passivation behavior of AZ91D alloy in relation to the influence of concentration,
temperature, pH, and immersion time was made in aqueous sulfate solution using electrochemical techniques including open-circuit
potential, potentiodynamic polarization and impedance spectroscopy. It was found that the corrosion and pitting potentials
(E
corr and E
pit) of the alloy drift to more active values with increasing either concentration (0.01–1.0 M) or temperature (278–338 K) of
the test solution, suggesting that sulfate solution enhances the alloy dissolution, particularly at higher temperatures. On
the other hand, values of the total film resistance (R
T) indicate that neutral solution (pH 7.0) supports the formation of a better protective layer on AZ91D surface than alkaline
(pH 12.5) or acidic (pH 1.0) medium. The growth of a protective film on the alloy surface at short immersion times (up to
∼50 h) is evinced by a rapid positive evolution of E
corr and fast decrease in the corrosion rate (i
corr). However, for a long-term exposure (up to 500 h) E
corr drifts negatively and i
corr increases due to breakdown of the protective film, which causes a decrease in the alloy stability. Fitting the impedance
data to equivalent circuit models suitable to each behavior assisted to explore the mechanism for the attack of the sample
surface at various testing times. The results obtained from the three studied electrochemical techniques are in good agreement. 相似文献
210.
Elliott LC Barhoum M Harris JM Bohn PW 《Physical chemistry chemical physics : PCCP》2011,13(10):4326-4334
Four techniques for analyzing single molecule tracking data--confinement level analysis, time series analysis and statistical analysis of lateral diffusion, multistate kinetics, and a newly developed method, radius of gyration evolution analysis--are compared using a set of sample fluorophore trajectories obtained from the lipophilic carbocyanine dye 1,1'-dioctadecyl-3,3,3'3'-tetramethylindocarbocyanine, DiIC(18), partitioned into surface tethered poly(n-isopropylacrylamide). The purpose here is two-fold: first to test that these techniques can be applied to single molecules trajectories, which typically contain a smaller total number of frames than those obtained from other particles, e.g. quantum dots or gold nanoparticles; and second to critically compare the information obtained from each method against the others. A set of five SMT trajectories, ranging in length from 41 to 273 steps with a 30 ms frame transfer exposure, were all successfully analyzed by all four techniques, provided two important criteria were met: enough steps to define the motion were acquired in the trajectory, generally on the order of 50 steps, and the fast and slow diffusion coefficients differ by at least a factor of 5. Beyond that the four trajectory analysis methods studied provide partially confirmatory and partially complementary information. SMT data resulting from more complex physical behavior may well benefit from using these techniques in succession to identify and sort populations. 相似文献