采用热处理方法提高MEH-PPV单层聚合物有机发光二极管发光性能的研究

对以MEH－PPV为发光层的单层聚合物有机发光二极管（OLED）器件在最佳条件下进行真空热处理，并用金相显微镜观察施加电压后器件的阴极表面形貌。发现处理后的器件阴极表面的气泡及黑斑明显减少。器件的发光性能显著提高。与未经处理的器件相比，最大相对发光强度提高了一个数量级、启亮电压降低了2．0V，半寿命提高了12．7倍。初步分析表明热处理方法提高器件发光性能的主要原因在于有效地减少了器件在工作过程中由于焦耳热产生的某些气体，从而减少阴极表面气泡及黑斑的出现，另一方面，热处理方法也增强了有机发光层与阴极接触界面的结合力，提高电子注入水平。     

分形维数与城市规模分布评析

本在分形概念的基础上，指出城市规模分布是基于统计意义上的一种分形分布，并计算了安徽省1978～1998年城市规模分布的分维值，评析了安徽省城市规模分布变化的特征。     

A NUMERICAL EMBEDDING METHOD FOR SOLVING THE NONLINEAR COMPLEMENTARITY PROBLEM(Ⅱ)-ALGORITHM AND ITS CONVERGENCE

In this paper,based on the results presented in part Ⅰ of this paper[18],we present a numerical embedding algorithm for solving the nonlinear complementarityproblem, and prove its convergence carefully. Numerical experiments show that thealgorithm is successful.     

PERSISTENCE AND GLOBAL STABILITY FOR TWO-SPECIES NONAUTONOMOUS PREDATOR-PREY SYSTEM WITH DIFFUSION AND TIME DELAY

In this paper, a non-autonomous predator-prey model with diffusion andcontinuous time delay is studied, where the prey can diffuse between two pat-ches of a heterogeneous environment with barriers between patches, but for thepredator, the diffusion does not involve a barrier between patches, further itis assumed that all the parameters are time-dependent. It is shown that thesystem can be made persistent under some appropriate conditions. Moreover,sufficient conditions that guarantee the existence of a unique periodic solutionwhich is globally asymptotic stable are derived.     

从数学解题看数学美

本论述了“教学好玩”(陈省身语)的五个方面；教学语言精确；教学发现(类比发现；归纳发现和直党发现)；教学解题思路；教学思想方法和数学应用都体现了教学关。     

NONLOCAL INITIAL PROBLEM FOR NONLINEAR NONAUTONOMOUS DIFFERENTIAL EQUATIONS IN A BANACH SPACE

The nonlocal initial problem for nonlinear nonautonomous evolution equati-ons in a Banach space is considered. It is assumed that the nonlinearities havethe local Lipschitz properties. The existence and uniqueness of mild solutionsare proved. Applications to integro-differential equations are discussed.The main tool in the paper is the normalizing mapping (the generalizednorm).     

Winograd矩阵乘法算法用于任意阶矩阵时的一种新处理方法

摘要t矩阵乘法StraSsen算法及其变形winograd算法用分而治之的方法把矩阵乘法时间复杂性由传统的D(n。)改进到0(佗kg。n.但是对于奇数阶矩阵,在划分子矩阵时,要作特殊处理才能继续使用此算法.本文提出了一种非等阶“十”字架划分方法,可以最少化填零,最大化性能,使得奇数阶矩阵乘法的时间复杂性更加接近偶数阶矩阵乘法的效果.计算实例显示该方法是有效的.     

利用电泳技术在不锈钢和铁基底上制备MgB2带材

本文首次报道了利用电泳技术在铁和不锈钢基底上制备MgB2超导带材.电阻测量表明,沉积在铁和不锈钢基底上MgB2带材的超导零电阻转变温度分别为37.5K和31K,超导转变宽度分别为0.3K和1K.磁测量表明,(5K,OT)时不锈钢基底上带材的临界电流密度为6×105(A/cm2).X射线衍射谱和扫描电子显微镜图象表明样品结晶良好,晶粒生长致密.本工艺制备MgB2带材时不受系统真空度的限制,生长迅速,成本低廉,并且可以根据不同的需要任意选择基底的形状和大小.     

Click chemistry in materials synthesis. III. Metal‐adhesive polymers from Cu(I)‐catalyzed azide–alkyne cycloaddition

1,2,3‐Triazole‐based polymers generated from the Cu(I)‐catalyzed cycloaddition between multivalent azides and acetylenes are effective adhesive materials for metal surfaces. The adhesive capacities of candidate mixtures of azide and alkyne components were measured by a modified peel test, using a customized adhesive tester. A particularly effective tetravalent alkyne and trivalent azide combination was identified, giving exceptional strength that matches or exceeds the best commercial formulations. The addition of Cu catalyst was found to be important for the synthesis of stronger adhesive polymers when cured at room temperature. Heating also accelerated curing rates, but the maximum adhesive strengths achieved at both room temperature and high temperature were the same, suggesting that crosslinking reaches the same advanced point in all cases. Polytriazoles also form adhesives to aluminum, but copper is bound more effectively, presumably because active Cu(I) ions may be leached from the surface to promote crosslinking and adhesion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5182–5189, 2007     

Photocatalytic Synthesis of Oxygenates from Gaseous CO2 and CH4 over Semiconductor

Photoinduced synthesis of CO2 and CH4 was investigated using a batch reaction system on several photoactive materials supported on silicon dioxide. Single semiconductor showed higher selectivity to C1 compounds. The production of C2-C3 oxygenates took place preferentially on composite semiconductor photocatalysts. In particular, it was found that acetone was the primary product over Cu/CdS-TiO2/SiO2.