Simulation of Decoherence by Averaged Semiquantum Method for Spin-Boson Model

We investigate the dynamics of a system coupled to an environment byaveraged semiquantum method. The theory origins from the time-dependentvariational principle (TDVP) formulation and contains nondiagonal matrixelements. So it can be applied to study dissipation, measurement, anddecoherence problems in the model (H = h_S + h_E + h_I). In the calculation, the influence of the environment govern by differential dynamical equation is incorporated through a mean field. We have performed averaged semiquantum method for a spin-boson model, which reproduce theresults from stochastic Schrodinger equation method and Hierarchicalapproach quite accurately. The problems, dynamics in nonequilibriumenvironments, have also been studied by our method.     

Synthesis and Characterization of Novel Aliphatic Poly(carbonate‐ester)s with Functional Pendent Groups

Summary: A novel cyclic carbonate monomer 5‐methyl‐5‐(succinimide‐N‐oxycarbonyl)‐1,3‐dioxan‐2‐one (MSTC) was prepared. The copolymers of MSTC with caprolactone (CL) were further synthesized by ring‐opening copolymerization. The copolymers with amido‐amine pendent groups were obtained by aminolysis of poly(MSTC‐co‐CL) with ethylenediamine. These copolymers were characterized by IR, ¹H NMR, ¹³C NMR spectroscopies and GPC. The hydrophilicity and degradability of the copolymers with amido‐amine pendent groups were greatly improved in comparison with the PCL homopolymer.

Hydrophilicity of PCL (1), poly(MATC‐co‐CL) (16.5:83.5) (2), and poly(MATC‐co‐CL) (29.5:70.5) (3).     

锆螯合物交联丙烯酸酯共聚物无皂水溶胶的研究Ⅰ丙烯酸酯三元共聚物合成条件对无皂水溶胶性能的影响

三乙醇胺螯合锆烷氧化物;交联反应;锆螯合物交联丙烯酸酯共聚物无皂水溶胶的研究 Ⅱ锆螯合物与丙烯酸酯三元共聚物无皂水溶胶的交联反应     

Obtaining the band structure of a complicated photonic crystal by linear operations

Absolute band gaps can be created by lifting the degeneracy in the bands of a photonic crystal.To calculate the band structure of a complicated photoinc crystal generated by e.g.symmetry breaking ,general forms of all possible linear operations are presented in terms of matrices and procedure to combine these operations in given.Other forms of linear operations (Such as the addition,subtraction,and translation transforms)are also presented to obtain an explicit expression for the Fourier coefficient of the dielectric function in the plane-wave expansion method.With the present method,band structures for various complicated photoinc crystals(related through these linear operations)can be obtained easily and quickly.As a numerical example,a large absolute and gap for a complicated photonic crystal structure of GaAs is found in the high reglon of normalized frequency.     

Identification of Collective Bands in Neutron-Rich 113Ru Nucleus

Through measuring high-fold prompt γ- ray coincidence events following the spontaneous fission of 252 Cf with the Gammasphere detector array, new level scheme in the very neutron-rich odd-A 113Ru nucleus has been established. An intruder collective band based on 11/2^－ level has been identified with spin up to 31/2 k and excitation energy 3.6 MeV. This band most probably originates from vh_11/2. intruder orbital. Another collective band probably built on 9/2^－ level is also observed. Some important characteristics of the collective bands have been systematically discussed.     

成核剂对PHBV等温结晶行为的影响

用DSC方法测定了氮化硼及滑石粉成核剂对(β-羟基丁酸酯-与-β-羟基戊酸酯) 共聚物(简称PHBV)等温结晶行为的影响. 结果表明,Avrami方程指数n、成核机理、晶体生长方式基本上不受成核剂的影响.少量的成核剂可使结晶成核自由能降低,结晶速率加大,其中氮化硼的效果最为显著.     

HIPS-g-GMA相容剂对PC/HIPS共混物相容性的影响*

将两种或两种以上聚合物进行共混是获得性能优异合金材料的简单而有效的途径[1,2 ] .但是大多数聚合物共混时 ,由于混合焓ΔＨ >0且混合熵ΔＳ非常小 ,导致混合自由能大于零 ,故大多数共混体系是不相容的 .而对于不相容的共混 ,由于两相间的界面张力大 ,两相间形成锐形界面 ,两相之间的界面粘结力低 ,导致材料性能很差 .为了改善两相间的相容性 ,需要加入相容剂[3 ,4 ] .绝大多数增容剂是嵌段或接枝共聚物 .这类增容剂分子量较大 ,在加工条件下 ,由于其粘度较大往往难于迁移到两相的界面处 ,起不到应有的增容作用 .聚合物反应加工技术是近 2…     

HF,Ne等电子体系对内对间电子相关能的比较研究

采用MELD程序ROHF－OPT1方法在MP2/6-311++G(d)水平上,计算了HF分子基态1^∑和Ne原子基态1^S的对内对间电子相关能,并对两等电子体系的对相关能进行了分析和比较,深入研究两等电子体系对内对间相关能所具有的共同规律和存在的差异性,通过比较说明分子内的化学键是影响电子相关能的重要因素之一。HF分子和Ne原子两体系三重激发和四重激发对体系电子相关能的贡献的计算结果表明高激发项对电子相关能的贡献在精确量子化学计算中是不可以忽略的。     

永磁同步电动机中的混沌现象

讨论永磁同步电动机（PMSM）的动态特性,给出常输入电压、常外部扭转条件下的系统稳态特性表达式,基于Hopf分支条件提出一种调节系统参数的方法,以使其呈现极限环或混沌行为。计算机仿真结果表明在永磁同步电动机中存在混沌现象。     

Two New Glucosides from Radix Polygoni multiflori Preparata

The root tuber of Polygonum multiflorum Thunb. ( Polygonaceae ) (PM ) is a famous Chinese traditional medicine, which has been used to remedy for treatment many diseases such as cardiovascular and aging diseases for long times. When it is used as a tonic drug, PM must be prepared in order to eliminate its side effects, and the preparation is known as Radix Polygoni multiflori Preparata ( PMP )1. Here we report the isolation of 2,3,5,4'-tetrahydroxystilbene-2-O-(2'-O-feruloyl)-(-D-gluco …