全文获取类型
收费全文 | 8862篇 |
免费 | 1783篇 |
国内免费 | 1204篇 |
专业分类
化学 | 6668篇 |
晶体学 | 203篇 |
力学 | 564篇 |
综合类 | 129篇 |
数学 | 785篇 |
物理学 | 3500篇 |
出版年
2024年 | 28篇 |
2023年 | 200篇 |
2022年 | 321篇 |
2021年 | 383篇 |
2020年 | 510篇 |
2019年 | 458篇 |
2018年 | 363篇 |
2017年 | 363篇 |
2016年 | 548篇 |
2015年 | 576篇 |
2014年 | 661篇 |
2013年 | 793篇 |
2012年 | 892篇 |
2011年 | 894篇 |
2010年 | 630篇 |
2009年 | 563篇 |
2008年 | 562篇 |
2007年 | 475篇 |
2006年 | 399篇 |
2005年 | 370篇 |
2004年 | 281篇 |
2003年 | 237篇 |
2002年 | 246篇 |
2001年 | 180篇 |
2000年 | 109篇 |
1999年 | 114篇 |
1998年 | 90篇 |
1997年 | 64篇 |
1996年 | 60篇 |
1995年 | 36篇 |
1994年 | 43篇 |
1993年 | 37篇 |
1992年 | 36篇 |
1991年 | 24篇 |
1990年 | 40篇 |
1989年 | 29篇 |
1988年 | 23篇 |
1987年 | 15篇 |
1986年 | 19篇 |
1985年 | 18篇 |
1984年 | 18篇 |
1983年 | 19篇 |
1982年 | 14篇 |
1981年 | 18篇 |
1980年 | 14篇 |
1979年 | 15篇 |
1978年 | 10篇 |
1977年 | 8篇 |
1974年 | 9篇 |
1973年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
111.
112.
meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉诱导的单抗 (MAb)导致meso -四 (α,α ,α ,α - 0 -苯乙酰苯 )卟啉Soret带来巨大红移 ,并且在meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉上产生巨大的诱导Cotton效应 (ICD) .借用ICD定量分析meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉同抗体的结合 ,表明在抗体超过meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉的情况下 ,既有 1∶1结合 ,又有 2∶1结合〔结合位点 :meso -四 (α ,α ,α ,α - 0 -苯乙酰苯 )卟啉〕 相似文献
113.
二维卷积在动力学分析中的应用 总被引:2,自引:0,他引:2
本文用计算机模拟和二维卷积研究了稀土与间乙酰基偶氮氯膦的显色反应,选择不同的模型参数可描述这类反应的细节,二维卷积则增强对叠合二维谱的分辨。 相似文献
114.
Yiyi Weng Xingxing Ding Joo C. A. Oliveira Xiaobin Xu Nikolaos Kaplaneris Meijie Zhu Hantao Chen Zhuo Chen Lutz Ackermann 《Chemical science》2020,11(34):9290
There is a strong demand for novel native peptide motifs for post-synthetic modifications of peptides without pre-installation and subsequent removal of directing groups. Herein, we report an efficient method for peptide late-stage C(sp3)–H arylations assisted by the unmodified side chain of asparagine (Asn) without any exogenous directing group. Thereby, site-selective arylations of C(sp3)–H bonds at the N-terminus of di-, tri-, and tetrapeptides have been achieved. Likewise, we have constructed a key building block for accessing agouti-related protein (AGRP) active loop analogues in a concise manner.An efficient method for peptide late-stage C(sp3)-H arylations assisted by unmodified side chain of asparagine (Asn) without any exogenous directing group has been reported. 相似文献
115.
Constituting the artificial carbon cycle,for example,through recycling CO2 and converting CH4 to value-added fuels and chemicals with solar energy,offers a sustainable future for humankind to tackle the global environmental issues and energy crisis.However,significant bottlenecks remain in such photocatalytic conversion,mainly related to the reaction activity and product selectivity.Herein,we share our efforts and systematic research progress on addressing the double bottlenecks for achieving solar-driven artificial carbon cycle,with specifically focusing on the photocatalytic CO2 and CH4 conversion.We further elucidate the common fundamentals behind various designed photocatalytic materials systems.Toward future development,we highlight the opportunities and challenges in the research field. 相似文献
116.
Fashui?HongEmail author Xuefeng?Wang Chao?Liu Guoxing?Su Weiping?Song Kang?Wu Ye?Tao Guiwen?Zhao 《中国科学B辑(英文版)》2003,46(1):42-50
It was studied by spectroscopy that PSII reaction center complex consisting of three polypeptides, D1, D2 and Cytb559, were purified from PSII particle of CeCl3 treated spinach. The results of the experiment show that Ce3+ could improve the growth of spinach, and accelerate electron transport of PSII particles. Of chl-a of UV-Vis spectrum of
D1/D2/Cytb559 complex, Soret band was blue-shifted by 3 nm and Q band by 2 nm, respectively, and the fluorescence emission
peak was blue-shifted by 5 nm in CeCl3-treated spinach compared with the one in control. By the extended X-ray absorption fine structure (EXAFS) spectroscopy methods,
it has been found that Ce3+ is coordinated with 8 nitrogen atoms in the first coordination shell with Ce-N bond length of 0.253 nm, and Ce3+ with 6 oxygen atoms in the second coordination shell with Ce-O bond length of 0.32 nm. However, the secondary structure of
D1/D2/Cytb559 complex by circular dichroism (CD) spectroscopy has no significant change after CeCl3 treated. It might be that Ce3+ binds to porphyrin rings of chlorophyll and oxygen of amino acid residue of polypeptide in D1/D2/Cytb559 complex, and then
accelerates the primary reaction of PSII, intensifies function of P680+ primary electron donor of D1/D2/Cytb559, but there is little change in conformation of PSII reaction center complex. 相似文献
117.
Fission fluctuation-dissipation dynamics of heavy nuclei has been studied using Langevin Monte Carlo simulations. The covariant form of the fission transport equation and the coefficients related to it are investigated. To learn about the influence of the dynamics from the ground state to the saddle point on the kinetic energy distributions we have studied various systems and compared the calculations both starting from the ground state and from the saddle point. Both the mean total kinetic energy of the fission fragments and its variances can fit with the experimental values in terms of a finite neck radius as scission condition.This work was supported by the National Natural Science Foundation of China. 相似文献
118.
119.
Mao Guangjun Li Zhuxia Zhuo Yizhong Han Yinlu Yu Ziqiang M. Sano 《Zeitschrift für Physik A Hadrons and Nuclei》1994,347(3):173-179
The collision term has been deduced based on the effective Lagrangian in addition to the mean-field. We propose the momentum- and density-dependent coupling strengths for scalar and vector fields. The saturation properties of nuclear matter, the experimental data of the energy-dependent optical potential and the mean free path in the nuclei can be reproduced simultaneously. The in-mediumn–n cross section has also been calculated for different densities and energies, our results are consistent with Dirac-Brueckner-Hartree-Fock calculations.Supported by National Natural Science Foundation of China 相似文献
120.