交流和纳秒脉冲Ar/H2O介质阻挡放电聚丙烯材料表面亲水改性对比研究

为了提高等离子体对聚合物材料表面处理的应用效果,优化亲水处理的条件,研究了交流和纳秒脉冲氩气介质阻挡放电（DBD）中添加适量H₂O,对聚丙烯（PP）亲水改性的处理效果。利用电学和光学诊断方法,系统地对比了交流DBD和纳秒脉冲DBD的放电特性,结果表明,纳秒电源驱动DBD具有更高的放电瞬时功率,更好的放电均匀性和更高的能量效率。通过测量不同水蒸气含量下DBD的OH发射光谱强度,确定了PP材料亲水性处理中H₂O添加的最优含量。利用交流和纳秒脉冲电源驱动DBD分别对PP材料进行亲水改性的处理,测量了不同条件下改性处理后的表面水接触角,并利用原子力显微镜（AFM）和傅里叶红外光谱（FTIR）分别对处理前后PP材料的表面物理形貌和表面化学成分进行分析。结果发现,经DBD处理后PP材料的水接触角明显降低,表面粗糙度明显增大,表面的亲水性含氧基团,羟基（−OH）和羰基（C=O）的数量大幅增加。相比交流电源,纳秒脉冲DBD处理的改性效果更好,其处理后的材料表面水接触角,比交流DBD处理的低5°左右,表面粗糙度也有所提升。而水蒸气的加入可使PP材料的表面水接触角进一步减小4°左右,表面粗糙度明显提升。研究结果为优化DBD聚合物材料表面改性实验条件及处理的效果提供了重要的参考依据。     

Parameter and state estimation algorithm for single-input single-output linear systems using the canonical state space models

This paper presents a new parameter and state estimation algorithm for single-input single-output systems based on canonical state space models from the given input–output data. Difficulties of identification for state space models lie in that there exist unknown noise terms in the formation vector and unknown state variables. By means of the hierarchical identification principle, those noise terms in the information vector are replaced with the estimated residuals and a new least squares algorithm is proposed for parameter estimation and the system states are computed by using the estimated parameters. Finally, an example is provided.     

Effects of defects on the effective thermal conductivity of thermal barrier coatings

It is difficult to establish structure-property relationships in thermal barrier coatings (TBCs) because of their inhomogeneous-geometry microstructures caused by defects. In the current research, the effects of pores and cracks on the effective thermal conductivity of TBCs are studied. Based on the law of the conservation of energy, mathematical formulations are proposed to indicate the relationship between defects and the effective thermal conductivity. In this approach, detailed equations are illustrated to represent the shape and size of defects on the effective thermal conductivity of TBCs. Different from traditional empirical analyses, mixture law or statistical method, for the first time, our results with the aid of finite element method (FEM) and strict analytical calculation show the influence of pore radius and crack length on effective thermal conductivity can be quantified. As an example to a typical microstructure of plasma sprayed TBCs, the effects of defects on the effective thermal conductivity of TBCs are expressed by the influence parameter, which indicating that the longest transverse crack dominates the contribution of the effective thermal conductivity along the spray direction compared with any individual defect.     

Time-clustering behavior of sharp fluctuation sequences in Chinese stock markets

Sharp fluctuations (in particular, extreme fluctuations) of asset prices have a great impact on financial markets and risk management. Therefore, investigating the time dynamics of sharp fluctuation is a challenge in the financial fields. Using two different representations of the sharp fluctuations (inter-event times and series of counts), the time clustering behavior in the sharp fluctuation sequences of stock markets in China is studied with several statistical tools, including coefficient of variation, Allan Factor, Fano Factor as well as R/S (rescaled range) analysis. All of the empirical results indicate that the time dynamics of the sharp fluctuation sequences can be considered as a fractal process with a high degree of time-clusterization of the events. It can help us to get a better understanding of the nature and dynamics of sharp fluctuation of stock price in stock markets.     

Preparation, thermo-optic property and simulation of optical switch based on azo benzothiazole polymer

An azo chromophore molecule 4-[(benzothiazole-2-yl)diazenyl]phenyl-1,3-diamine (BTPD) was prepared with 2-amino benzothiazole and m-phenylenediamine by diazo-coupling reaction. Then, the chromophore molecule BTPD was polymerized with NJ-210 and isophorone diisocyanate (IPDI) to obtain novel azo benzothiazole polymer (BTPU). The structures of BTPD and BTPU were characterized using the Fourier transform infrared, UV–visible spectroscopy, DSC and TGA. The physical properties of the obtained BTPU were investigated. The refractive index (n) of BTPU was demonstrated at different temperature and wavelength (532, 650 and 850 nm) using attenuated total reflection technique. The transmission loss and dispersion characteristic of BTPU film were investigated using the CCD digital imaging devices and Sellmeyer equation. A Y-branch and 2 × 2 Mach–Zehnder interferometer (MZI) polymeric thermo-optic switches based on the thermo-optic effect of prepared BTPU were proposed and the performance of switches was simulated. The results indicated that the power consumption of the Y-branch thermo-optic switch could be only 0.6 mW. The Y-branch and MZI switching rising and falling times obtained were 8.0 and 1.8 ms.     

Non-Rayleigh photon statistics of superbunching pseudothermal light

Superbunching pseudothermal light has important applications in studying the second-and higher-order interference of light in quantum optics.Unlike the photon statistics of thermal or pseudothermal light is well understood,the photon statistics of superbunching pseudothermal light has not been studied yet.In this paper,we will employ single-photon detectors to measure the photon statistics of superbunching pseudothermal light and calculate the degree of second-order coherence.It is found that the larger the value of the degree of second-order coherence of superbunching pseudothermal light is,the more the measured photon distribution deviates from the one of thermal or pseudothermal light in the tail part.The results are helpful to understand the physics of two-photon superbunching with classical light.It is suggested that superbunching pseudothermal light can be employed to generate non-Rayleigh temporal speckles.     

二维正方各向异性碲圆柱光子晶体完全禁带中缺陷模的FDTD计算分析和设计

用FDTD方法计算了二维正方晶胞各向异性碲圆柱光子晶体的点缺陷模.为了得到TE,TM模式在完全禁带中具有相同共振频率的缺陷模,对中心点缺陷半径Rd以及中心附近对称位置的点缺陷半径Rn做了一系列微调.计算表明,TM模对于Rn的变化不敏感,而TE模随着Rn的改变出现了明显的规则的移动趋势.通过计算分析,发现对应于f=0.4的背景(R=0.3568a),当Rd=0.55a,Rn=0.26a时在完全禁带中TE和TM的缺陷模具有相同的共振频率ω0=0.2466ωe(其中ωe=2πca,a为晶格常数) 关键词： 时域有限差分法 光子晶体 缺陷模 各向异性     

多环涡旋光束的实验研究

涡旋光束的产生、传输与应用是当前光学领域热门的研究课题之一.本文提出的新型多环涡旋光束,包括双环涡旋及三环涡旋光束,它是由多束携带不同拓扑电荷数且束腰半径不同的拉盖尔-高斯涡旋光束共轴叠加而成,其光强分布为多环结构.从理论上研究了多环涡旋光束的形成与分布特征,基于共轭对称延拓Fourier计算全息方法生成了多环涡旋光束的计算全息图,并利用一个空间光调制器实验产生了与理论一致的高质量的多环涡旋光束.研究表明多环涡旋光束的各环携带不同的轨道角动量,空间分布保持相互独立.这种新型的多环涡旋光束相对于携带单一拓扑电荷数的涡旋光束,提供了更多的控制参数和更加多样化的结构分布,因此在光学镊子、光学捕获等微操控以及光通信领域具有潜在的应用潜力.     

大散射角散斑场中有关相位奇异新特性的研究

利用散斑场和参考光的干涉提取散斑场复振幅和相位, 研究了不同散射角下散斑场相位的分布规律以及相位奇异处光波复振幅实部零值线和虚部零值线夹角、光强等值线离心率的统计特性. 在大散射角散斑中发现了一种新的相位奇异现象, 即相位奇异线; 研究了相位在跨越奇异线时的突变规律及涡旋状相位的分布特征, 发现在相位奇异线处存在着呈双曲线或抛物线状的光强等值线.     

基于1/f噪声的NPN晶体管辐照感生电荷的定量分离

本文针对NPN双极性晶体管, 在研究辐照感生的氧化层电荷及界面态对晶体管基极电流和1/f噪声的影响的基础上, 建立辐照感生氧化层电荷及界面态与基极电流和1/f噪声的定量物理模型. 根据所建立的模型, 提出一种新的分离方法, 利用1/f噪声和表面电流求出氧化层电荷密度, 利用所求得氧化层电荷密度和表面电流求出界面态密度. 利用本方法初步实现了辐照感生氧化层电荷及界面态的定量计算.