Thermal expansion of a rig

Summary We have estimated and measured the daily thermal expansion of an oceanographic platform. This has been found negligible as far as the calibration of a satellite altimeter is concerned.     

Acyl derivatives of N,N′-diaminodibenzo-18-crown-6 ether,their complexing and catalytic properties

Conclusions Complex compounds of bisacyl derivatives of diaminodibenzo-18-crown-6 ether are active catalysts of the two stages of the synthesis of poly(ethylene terephthalate).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2544–2547, November. 1987.     

Grafting onto poly(ethylene terephthalate) driven by 172 nm UV light

The reactivity of the surface of poly(ethylene terephthalate) (PET) film under 172 nm UV irradiation (xenon excimer lamp) towards nitrogen-borne 1-octene, n-nonane and heptafluorodecene vapor was investigated. Materials receiving from 0 to 24 J/cm² of UV were examined by X-ray photoelectron spectroscopy (XPS), time of flight secondary ion mass spectroscopy (ToF/SIMS), water and mineral oil contact angle measurement and atomic force microscopy (AFM). A uniform nanoscale layer developed on PET surface attributed to the grafting reaction between photolytically-produced polymer radicals and vapor phase molecules.     

An algebra of meromorphic corner symbols

Operators on manifolds with corners that have base configurations with geometric singularities can be analysed in the frame of a conormal symbolic structure which is in spirit similar to the one for conical singularities of Kondrat'ev's work. Solvability of elliptic equations and asymptotics of solutions are determined by meromorphic conormal symbols. We study the case when the base has edge singularities which is a natural assumption in a number of applications. There are new phenomena, caused by a specific kind of higher degeneracy of the underlying symbols. We introduce an algebra of meromorphic edge operators that depend on complex parameters and investigate meromorphic inverses in the parameter-dependent elliptic case. Among the examples are resolvents of elliptic differential operators on manifolds with edges.     

Asymptotics of collision integral matrix elements in the isotropic case

The method of nonlinear moments, when used to solve the Boltzmann equation, necessitates the calculation of collision integral matrix elements. The matrix elements are hard to calculate numerically, especially at large indices. The asymptotics of the matrix elements are constructed. In terms of the model of pseudopower particle interaction, a formula free of summation is derived. This makes it possible to find the asymptotic behavior of linear and nonlinear elements when two indices are large. For an arbitrary interaction cross section, asymptotic expansions of linear and nonlinear matrix elements in one index are obtained. For Maxwellian molecules, asymptotic formulas are derived for three large indices.     

Semiempirical calculation of the fine structure of the indium ion

The fine-structure parameters of a series of configurations of the first ion of indium and the gyromagnetic ratios in intermediate coupling are calculated by a semiempirical method in the single-configuration approximation.     

Dicyclopentadienyl complexes of titanium,niobium, and tungsten in the controlled synthesis of poly(methyl methacrylate)

Organometallic compounds Cp₂TiCl₂, (EtC₅H₄)₂NbCl₂, and (PrⁱC₅H₄)₂WCl₂ were assessed as additives that control polymer chain growth in the polymerization of methyl methacrylate. In the presence of compounds mentioned in amounts comparable with that of the initiator, a uniform process with no gel-effect occured and respective linear increase in the molecular weight of the polymer up to high degrees of the monomer conversion was observed.