低热固相反应合成Mo(W)-Cu(Ag)-S簇合物

本文对现有中,高温固相化学反应方法合成含硫原子簇化合物作了探讨,介绍了我们实验室用低热温度固相反应合成原子簇化合物的新方法,总结了几年来我们用此法合成的S-Mo(W)-Cu(Ag)原了簇化合物,并测定结构二十余个,其中包括了含有二十个金属原子的大核原子簇化合物[(n-Bu)_4N]_4[Mo_8Cu_(12)S_(32)]。     

Syntheses,Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

Two coordination polymers {[Co₃L₃(Me₂NH)₂]·(Me₂NH)}_n(1) and [CuL(bpy)]_n(2)(L=2,2'-biphenyl dicarboxylate ion, bpy=4,4'-bipyridine) were obtained and characterized. Compound 1 was synthesised via solvothermal method, with the L ligands adopting syn-syn-μ₂-η¹:η¹- and μ₂-η²-coordination modes and Co(II) centers being linked to form a 1D coordination chain with trinuclear Co₃ cluster as sub-units. Compound 2 was synthesized at room temperature, with the L ligand chelating the Cu(II) centers to form a 1D chain, which was further linked by the auxiliary 4,4'-bpy ligand to form a 3D coordination network. The results of variable temperature susceptibility studies reveal that there were ferromagnetic and antiferromagnetic interactions between the paramagnetic metal centers in compounds 1 and 2, respectively.     

Synthesis, crystal structure and forming mechanism of two novel copper (II) α-methacrylate complexes with benzimidazole

Two copper (II) α-Methacrylate complexes with benzimidazole, Cu[CH₂ = C(CH₃)-COO]₂ (C₃H₆N₂)₂(1) and Cu₂[CH₂ = C(CH₁)-COO]₂(C₃H₆N₂)₂(2), have been prepared and characterized by elemental analyses, IR and electronic reflectance spectroscopies. ’The single crystal X-ray diffraction study of the two complexes shows that complex 1 has a square planar configuration, while complex 2 has a binuclear cage structure. The crystal structural analyses show that both complexes 1 and 2 are monoclinic. with space group p2₁/c,a = 0.924 16(8) nm,b = 1.233 02(13) nm,c = 0.989 1(3) nm,β = 91.912 (13),D _c = 1.386 g/cm³,Z=2,R = 0.033 9 for the former; anda = 0.905 7(2) nm,b = 2.252 1(5) nm,c = 1.623 5(4) nm,β = 90.11 (2),D _c = 1.411 g/cm³,Z = 4,R = 0.056 8, Cu-Cu = 0.266 21 nm for tin latter. Different structural types of complexes 1 and 2 were produced simultaneously in the reaction of copper (II) α-methacrylate with benzimidazole in methanol solution. ’The forming mechanism of the complexes has been summanzed. Project supported by the national natural Science Foundation of China (Grant No. 29831010) and the Foundation of the State Key Laboratory of Coordination Chemistry of Nanjing university.     

Air-stable catalysts for highly efficient and enantioselective hydrogenation of aromatic ketones

A series of chiral trans-[RuCl(2)(dipyridylphosphine)(1,2-diamine)] complexes have been synthesized and characterized by NMR and single-crystal X-ray diffraction studies. These Ru complexes combined with (CH(3))(3)COK in 2-propanol formed a very effective catalyst system for the hydrogenation of a diverse range of simple aromatic ketones with high activity (substrate-to-catalyst ratio up to 100 000) and excellent enantioselectivity (up to >99.9%). The catalyst system was also found to be stable in solution even under a normal atmosphere.     

沉管隧道横向动力响应分析的多体动力学方法

沉管隧道横向地震响应分析是沉管隧道结构抗震设计的重点.根据沉管隧道的结构特点和接头剪力键的节点构造,建立了沉管隧道的多刚体-剪切铰-黏性阻尼铰多体动力学模型,并应用多体动力学中的离散时间传递矩阵法(multibody system discrete time transfer matrix method,MS-DT-TMM)建立了数学模型及表达式,同时编写Matlab程序进行求解实现.设定算例分别采用MS-DT-TMM和传统有限元法(finite element method,FEM)对沉管隧道横向地震响应进行对比分析,两者吻合较好,表明MS-DT-TMM应用于沉管隧道横向动力响应分析的可行性和有效性.     

汽车转弯不容忽视的力学问题

旨在对驾驶员进行安全行车教育,避免汽车转弯时出现爆胎、翻车、漂移、“推头”、甩尾等事故苗头. 通过在研究过程中,利用实车在转弯、坡道、冰雪等复杂路面上反复演练,发现：弯中强力制动会导致爆胎、翻车、漂移;弯中猛踩油门会导致“推头”、甩尾. 并提出预防措施.     

基于传递函数法的大展弦比机翼阵风响应分析1)

将传递函数法应用于大展弦比机翼的阵风响应分析。首先,基于二元机翼的运动方程和准定常片条理论建立机翼的阵风响应微分方程,对其进行Laplace变换,并转换为状态空间方程形式。然后,运用传递函数方法,获得机翼响应在频域的解析解,通过Laplace数值逆变换求得机翼在时域内的响应。通过与已有文献结果对比,验证了本文方法的正确性。最后,采用该方法求解了“1-cos”型阵风和连续大气湍流作用下的机翼响应,并对结果进行了分析讨论。     

Single-peak solutions for a subcritical Schrödinger equation with non-power nonlinearity

This paper deals with the following slightly subcritical Schrödinger equation: $$-\mathrm{\Delta }u+V(x)u=f_{\epsilon }(u),u>0\text{in}{\mathbb{R}}^N,$$ where $V(x)$ is a nonnegative smooth function, $f_{\epsilon }(u)=\frac{u^p}{{[\ln (e+u)]}^{\epsilon }}$, $p=\frac{N+2}{N-2}$, $\epsilon >0$, $N\ge 7$. Most of the previous works for the Schrödinger equations were mainly investigated for power-type nonlinearity. In this paper, we will study the case when the nonlinearity $f_{\epsilon }(u)$ is a non-power nonlinearity. We show that, for ε small enough, there exists a family of single-peak solutions concentrating at the positive stable critical point of the potential $V(x)$.