Up-conversion luminescence analysis in ytterbium-sensitized erbium-doped oxide-halide tellurite and germanate-niobic-lead glasses

Ytterbium-sensitized erbium-doped oxide-halide tellurite and germanate-niobic-lead glasses have been synthesized by conventional melting method. Intense green and red emissions centered at 525, 546 and 657 nm, corresponding to the transitions 2H11/2-->4I15/2, 4S3/2-->4I15/2 and 4F9/2-->4I15/2, respectively, were simultaneously observed at room temperature in these glasses. The quadratic dependence of the 525, 546 and 657 nm emissions on excitation power indicates that a two-photon absorption process occurs. Tellurite glass showed a weaker up-conversion emission than germanate-niobic-lead glass, which is inconsistent with the prediction from the difference of maximum phonon energy between tellurite and germanate-niobic-lead glasses. In this paper, Raman spectroscopy was employed to investigate the origin of the difference in up-conversion luminescence in the two glasses. Compared with phonon side-band spectroscopy, Raman spectroscopy extracts more information including both phonon energy and phonon density. Our results reveal that the phonon density and the maximum phonon energy of host glasses are both important factors in determining the up-conversion efficiency.     

Constrained instanton and black hole creation

It is generally accepted that the Einstein theory of general relativity governs the evolution of the universe. However, the singularity theorem of Hawking and Penrose[1] shows that under the most reasonable physical conditions, a spacetime singularity, where physics laws and even causality are broken down, is unavoidable. One has to impose the boundary or initial conditions at the edge of spacetime for the evolution of the universe. This is the so-called first cause problem. The no-boundary …     

瞬态声振耦合问题的边界元分析及实验研究

本文探求任意外形结构在外力作用下的瞬态声场特性,研究声辐射机理,用时域边界元技术讨论外力、结构振动响应和声辐射三者之间的关系,并用实验结果加以验证,为瞬态声振耦合研究提供一种新的数值分析方法。     

流场有限元分析的并行计算

在流场有限元分离式求解法的基础上 ,导出了并行计算的算法流程 ,可利用并行计算机同时求解的相互耦合的流场描述非线性方程组 ,并在曙光 2 0 0 0并行计算机系统上成功实施 ,比之串行计算 ,较大幅度地提高了计算效率     

HL—1M装置的密度极限研究

描述了ＨＬ－１Ｍ 装置欧姆加热状态下的密度极限,该密度极限是放电破裂前的最高密度值。通过比较氘、氢放电,硅化前后的放电,超声分子束注入、冰弹丸注入和脉冲送气放电,发现ＨＬ－１Ｍ装置的壁条件、加料方式以及氢同位素对ＨＬ－１Ｍ 装置的密度极限影响很大。产生密度极限破裂的原因主要是等离子体约束变差,总体辐射损失与欧姆加热功率平衡被破坏     

Asymptotic Behavior of Solutions to Second-Order Nonlinear Differential Equations

In this paper the authors study the oscillation and the asymptotic behavior of solutiosn to the second-order nonlinear differential equations $[\ddot x]\pmX(t,x,[\dot x])=0$(X_{\pm}) and give necessary and sufficient conditions for Equation (X_+) to have a bounded nonoscillatory solution or to be oscillatory. There are four classes of solutions to Equation (X_) with different asymptotic behavior. For each class of solution, the necessary or sufficient condition of the existence is obtained.     

Limit Boundary Value Problems of a class of Nonlinear Differential Equations of the Second order

In this paper, the existence and uniqueness of solution of the limit boundary value problem $\[\ddot x = f(t,x)g(\dot x)\]$(F) $\[a\dot x(0) + bx(0) = c\]$(A) $\[x( + \infty ) = 0\]$(B) is considered, where $\[f(t,x),g(\dot x)\]$ are continuous functions on $\[\{ t \ge 0, - \infty < x,\dot x < + \infty \} \]$ such that the uniqueness of solution together with thier continuous dependence on initial value are ensured, and assume: 1)$\[f(t,0) \equiv 0,f(t,x)/x > 0(x \ne 0);\]$; 2) f(t,x)/x is nondecreasing in x>0 for fixed t and non-increasing in x<0 for fixed t, 3)$\[g(\dot x) > 0\]$, In theorem 1, farther assume: 4) $\[\int\limits_0^{ \pm \infty } {dy/g(y) = \pm \infty } \]$ Condition (A) may be discussed in the following three cases $x(0)=p(p \neq 0)$(A_1) $\[x(0) = q(q \ne 0)\]$(A_2) $\[x(0) = kx(0) + r{\rm{ }}(k > 0,r \ne 0)\]$(A_3) The notation $\[f(t,x) \in {I_\infty }\]$ will refer to the function f(t,x) satisfying $\[\int_0^{ + \infty } {\alpha tf(t,\alpha )dt = + \infty } \]$ for each $\alpha \neq 0$, Theorem. 1. For each $p \neq 0$, the boundary value problem (F), (A_1), (B) has a solution if and only if $f(t,x) \in I_{\infty}$ Theorem 2. For each$q \neq 0$, the boundary value problem (F), (A_2), (B) has a solution if and only if $f(t, x) \in I_{\infty}$. Theorem 3. For each k>0 and $r \neq 0$, the boundary value problem (F), (A_3), (B) has a solution if and only if f(t, x) \in I_{\infty}, Theorem 4. The boundary value problem (F), (A_j), (B) has at most one solution for j=l, 2, 3. .     

Dual Intramolecular Electron Transfer for In Situ Coreactant‐Embedded Electrochemiluminescence Microimaging of Membrane Protein

The demand for transporting coreactant to emitter and short lifetime of the radicals in electrochemiluminescence (ECL) emission inhibit greatly its application in cytosensing and microscopic imaging. Herein we designed a dual intramolecular electron transfer strategy and tertiary amine conjugated polymer dots (TEA‐Pdots) to develop a coreactant‐embedded ECL mechanism and microimaging system. The TEA‐Pdots could produce ECL emission at +1.2 V without need of coreactant in test solution. The superstructure and intramolecular electron transfer led to unprecedented ECL strength, which was 132 and 45 times stronger than those from the mixture of Pdots with TEA at equivalent and 62.5 times higher amounts, respectively. The ECL efficiency was even higher than that of typical [Ru(bpy)₃]²⁺ system. Therefore, this strategy and coreactant‐embedded ECL system could be used for in situ ECL microimaging of membrane protein on single living cells without additional permeable treatment for transporting coreactant. The feasibility and validity were demonstrated by evaluating the specific protein expression on cell surface. This work opens new avenues for ECL applications in single cell analysis and dynamic study of biological events.     

Supercontinuum generation in short tellurite microstructured fibers pumped by a quasi-cw laser

We investigate supercontinuum (SC) generation in highly nonlinear tellurite microstructured fibers pumped by a continuous wave (cw)/quasi-cw laser. We investigate two types of tellurite fibers. One type has the constant core diameter, and the other type has a longitudinally varying core diameter. For the fibers with a constant core diameter, when pumped in the anomalous dispersion region, the SC is symmetric in a fiber that has a zero dispersion wavelength close to the pump wavelength. For the fibers with a longitudinally varying diameter, the calculated phase-matching conditions show that they have a broad wavelength range of dispersive waves, and therefore the measured SC spectrum can be broader than one octave. In this work, the fiber lengths are as short as several tens of centimeters, and the pump power is in the watt level.     

基于电驱动纳米光栅的结构设计及仿真分析

针对传统机械光栅周期不可调、检测精度低、无法实现光谱的连续扫描等问题,提出了一种基于石墨烯(GNP)和聚二甲基硅氧烷(PDMS)构成的复合材料的低压直流电驱动可调谐纳米光栅,并对光栅整体结构进行了设计.利用COMSOL Multiphysics软件研究了光栅结构尺寸和驱动电压对光栅周期和膜层温度的影响规律.分析结果表明,在低电压驱动下膜层最大温度变化约为160℃,光栅周期在5s内的最大调谐量为160 nm.此外,在不同的驱动电压下,光栅周期和膜层温度的变化规律是相似的,这满足了工业气体的不同检测需求.