改进的双曲等效法用于双站合成孔径雷达前视成像

双站合成孔径雷达(SAR)前视成像有着很多的潜在应用,比如在能见度很低的天气实现飞机的导航和盲降,提高飞机飞行的安全度等.然而实现双站SAR前视成像的难点在于其距离历程的双根式性,直接采用驻定相位原理对其分解将得到复杂的解析式,从而后续算法的推导变得困难.现有的双曲等效法可以将双根式距离历程等效为单根式,但由于该方法为距离历程的二阶近似,当用于双站SAR前视成像时,由于其较大的前视角,未完全等效的距离历程高次项造成的误差已经超出可以接受的范围.针对以上问题,本文首先提出了一种改进的双曲等效法,该方法通过引入新的补偿变量来提高距离历程的等效精度;然后在此基础上推导回波信号的二维频谱解析式,并给出了一种适用于双站SAR前视成像的距离多普勒算法;最后通过仿真实验,将原双曲等效法与改进方法的等效误差以及成像结果做对比,验证了本文算法的有效性和优越性.     

Anion recognition by alpha-arylazo-N-confused calix[4]pyrroles

The first example of substitution reaction in the free alpha-position of N-confused calix[4]pyrroles is reported: azo-coupling with various arenediazonium salts. The obtained azocompounds were used for studies of their anion-binding properties by UV-Vis spectroscopy.     

Dual-Atom Catalysts Derived from a Preorganized Covalent Organic Framework for Enhanced Electrochemical Oxygen Reduction

Dual-atom catalysts (DAC) are deemed as promising electrocatalysts due to the abundant active sites and adjustable electronic structure, but the fabrication of well-defined DAC is still full of challenges. Herein, bonded Fe dual-atom catalysts (Fe₂DAC) with Fe₂N₆C₈O₂ configuration were developed through one-step carbonization of a preorganized covalent organic framework with bimetallic Fe chelation sites (Fe₂COF). The transition from Fe₂COF to Fe₂DAC involved the dissociation of the nanoparticles and the capture of atoms by carbon defects. Benefitting from the optimized d-band center and enhanced adsorption of OOH* intermediates, Fe₂DAC exhibited outstanding oxygen reduction activity with a half-wave potential of 0.898 V vs. RHE. This work will guide more fabrication of dual-atom and even cluster catalysts from preorganized COF in the future.     

Solution-phase synthesis of spherical zinc sulfide nanostructures

A facile solution-phase method has been developed to synthesize specially hollow and solid ZnS nanospheres. High-resolution TEM images on the nanospheres suggest their formation via the oriented aggregation of the primary ZnS nanocrystals. The morphology and size of the ZnS nanospheres can also be tuned easily by controlling the experimental conditions. These special spherical structures are very easily encapsulated within a uniform silica layer without any surface modification, suggesting potential applications in biochemistry and biodiagnostics.     

Manipulating the Stacking of Triplet Chromophores in the Crystal Form for Ultralong Organic Phosphorescence

Provided here is evidence showing that the stacking between triplet chromophores plays a critical role in ultralong organic phosphorescence (UOP) generation within a crystal. By varying the structure of a functional unit, and different on‐off UOP behavior was observed for each structure. Remarkably, 24CPhCz, having the strongest intermolecular interaction between carbazole units exhibited the most impressive UOP with a long lifetime of 1.06 s and a phosphorescence quantum yield of 2.5 %. 34CPhCz showed dual‐emission UOP and thermally activated delayed fluorescence (TADF) with a moderately decreased phosphorescence lifetime of 770 ms, while 35CPhCz only displayed TADF owing to the absence of strong electronic coupling between triplet chromophores. This study provides an explanation for UOP generation in crystal and new guidelines for obtaining UOP materials.     

基于结构动力修改的桩基检测方法

采用结构动力修改技术研究桩身损伤检测，将其转化为在一定约束条件下拟合桩顶频响函数的优化问题。用遗传算法加以求解。文中给出的数值模拟试验和工程应用实例，显示该方法能在较大范围内可靠地反演出桩身横截面积、桩长、波速等参数，达到检测桩身缺陷的目的，实现测试和分析一体化，使桩基检测易于进行并且结果实用可靠。     

海底边坡稳定分析方法综述

本文指出海底边坡与陆上边坡的不同点,对一个完整的海底边坡稳定问题从几何形状和载荷情况两个方面进行了描述。由于波浪影响是海底边坡问题的最大特点,因此回顾了计算海底压力的各种方法以及在海底压力作用下海底土层产生的瞬态和残余孔隙压力。然后对极限平衡、静态变形分析和动力分析三大类边坡稳定分析方法进行了评述,并指出各自的适用范围。海底边坡破坏后的行为尤其复杂,指出用流变模型预测泥流性质的可能性。最后提出了海底边坡稳定性课题的当前致力方向。      

Generation of Ising interaction and cluster states in a one-dimensional coupled resonator waveguide

We propose a scheme for realizing the Ising spin-spin interaction and atomic cluster states utilizing the trapped two-level atoms inside a one-dimensional coupled resonator waveguide. In the strong driving and large detuning conditions, an effective Ising spin-spin interaction can be generated through suitably tuning the parameters. Then atomic cluster states are produced by using this Ising interaction. This scheme need not initially prepare the superposition states of atoms, and is insensitive to cavity decay.     

针孔辅助点投影诊断方法实验研究

针孔辅助点投影背光成像是近几年国外新兴的等离子体诊断技术,在惯性约束聚变相关物理实验诊断中具有重要的应用前景.为验证这一诊断方法的实用性,在神光Ⅱ第九路平台上开展了演示实验.利用激光驱动平面Ti靶获得约4.7 keV的Ti K壳层X射线,在十几微米的针孔约束下作为次级点源并对Au栅格样品投影成像,并用CCD记录.实验成功获得了清晰的样品二维空间分辨的时间积分图像,空间分辨力优于16.1 μm.实验结果表明针孔辅助点投影具有较高的空间分辨力、较大的视场、较高的图像对比度,将成为瑞利泰勒不稳定性研究、激光状态方程研究等物理实验的重要诊断方法之一.