全文获取类型
收费全文 | 8505篇 |
免费 | 1288篇 |
国内免费 | 1265篇 |
专业分类
化学 | 6209篇 |
晶体学 | 99篇 |
力学 | 673篇 |
综合类 | 94篇 |
数学 | 1118篇 |
物理学 | 2865篇 |
出版年
2024年 | 25篇 |
2023年 | 167篇 |
2022年 | 210篇 |
2021年 | 285篇 |
2020年 | 320篇 |
2019年 | 306篇 |
2018年 | 229篇 |
2017年 | 251篇 |
2016年 | 424篇 |
2015年 | 352篇 |
2014年 | 436篇 |
2013年 | 592篇 |
2012年 | 725篇 |
2011年 | 681篇 |
2010年 | 560篇 |
2009年 | 474篇 |
2008年 | 528篇 |
2007年 | 447篇 |
2006年 | 436篇 |
2005年 | 421篇 |
2004年 | 360篇 |
2003年 | 334篇 |
2002年 | 387篇 |
2001年 | 351篇 |
2000年 | 243篇 |
1999年 | 249篇 |
1998年 | 187篇 |
1997年 | 171篇 |
1996年 | 182篇 |
1995年 | 139篇 |
1994年 | 129篇 |
1993年 | 95篇 |
1992年 | 70篇 |
1991年 | 70篇 |
1990年 | 43篇 |
1989年 | 26篇 |
1988年 | 35篇 |
1987年 | 18篇 |
1986年 | 28篇 |
1985年 | 20篇 |
1984年 | 9篇 |
1983年 | 14篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1974年 | 1篇 |
1957年 | 3篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
Jin Yan Dong Ye Gao Chen Hong Chuan Song Yan Ping He Lei Li Yong Ping Zhong Yan Hui Zhu Jie Cao Luo Wang Ke Qin Zhang Laboratory for Conservation Utilization of Bioresources Yunnan University Kunming China Department of Chemistry Yunnan Normal University Kunming China Provincial Key Lab of Rural Energy Engineering Yunnan Normal University Kunming China 《中国化学快报》2007,18(2):165-167
Microbial transformation of nigranoic acid by Caryospora carllicarpa YMF1.01026 afforded the new derivative 6β-hydro-xynigranoic acid. Its structure was elucidated by spectroscopic methods. 相似文献
52.
Wei ZHANG Ni SONG Zhong Zhen LI Ying Xia LI 《中国化学快报》2006,17(3):285-288
Obyanamide 1 is a cyclic depsipeptide that was recently isolated from the marine cyanobacterium Lyngbya confervoides by Moore and co-workers1. This compound displayed a potent inhibitory effect on both KB and LoVo cells in vitro. Several structural analog… 相似文献
53.
Da Xu Zhong Lan Gao Na Li Ke An Li Key Laboratory of Bioorganic Chemistry Molecular Engineering of Ministry of Education College of Chemistry Molecular Engineering Peking University Beijing China 《中国化学快报》2007,18(5):561-564
Ru(bpy)_(3~(2 )) electrochemiluminescence (ECL) was applied to determination of rutin. ECL intensity of Ru(bpy)_(3~(2 ))could be enhanced in the presence of rutin in basic solution on platinum electrode. At pH 9.9, light emission intensity was found to be linear with rutin in the range of 1-50 mmol/L. 相似文献
54.
55.
56.
从我国西沙群岛采集的软珊瑚Nephthea albida和南沙群岛采集的N.tixiexae uer seueldt的乙醇,抽提物中,通过硅胶层析分离出一种罕见的含19-羟基的多羟基甾醇——Nephalsterol-A(1),该物质为无色针状结晶,m.p.242~243℃,[a]_D~(20)=O(C 0.053,CH_3OH),为一新化合物。 (1)的ELMS显示分子离子峰m/z 448,结合~(13) NMR DEPT谱确定(1)的分子式为C_(28)H_(48) 相似文献
57.
基团的电子效应与单取代苯对位1H、13C的化学位移*韩长日冯娇杨钟照平(海南师范学院化学系海口571158)关键词1H的化学位移13C的化学位移基团电负性共轭效应引言在1H、13C核磁共振谱中,化学位移值的大小主要取决于屏蔽作用的大小,而屏蔽作用的大... 相似文献
58.
The gas-phase photocatalytic oxidation of aniline on a new kind of porous nano-TiO2 composite films is investigated. The composite film was prepared on glass fiber with the water glass as binders and dilute
H2SO4 solution as solidifying reagent. The surface characters were observed by scanning electron microscope. The photocatalytic
degradation of aniline on the composite films was carried out in a TiO2/UV system. Some important factors affecting the photodegradation, such as the concentration of TiO2, the initial concentration of aniline, and the existing water vapor, are also studied. The product of photocatalytic oxidation
was detected by Fourier transform-Infrared. The partial intermediate products were absorbed on TiO2 surface, which resulted in catalyst deactivation. But when it was irradiated under UV illumination or solar irradiation for
some time, the catalyst could be reused without loss of catalytic activity.
Translated from the Journal of Wuhan University (Natural Science Edition), 2005, 51(2) (in Chinese) 相似文献
59.
Dong-Dong Zhou Jun Wang Pin Chen Yangyong He Jun-Xi Wu Sen Gao Zhihao Zhong Yunfei Du Dingyong Zhong Jie-Peng Zhang 《Chemical science》2021,12(4):1272
Rational manipulation of supramolecular structures on surfaces is of great importance and challenging. We show that imidazole-based hydrogen-bonded networks on a metal surface can transform into an isostructural coordination network for facile tuning of the pore size and guest recognition behaviours. Deposition of triangular-shaped benzotrisimidazole (H3btim) molecules on Au(111)/Ag(111) surfaces gives honeycomb networks linked by double N–H⋯N hydrogen bonds. While the H3btim hydrogen-bonded networks on Au(111) evaporate above 453 K, those on Ag(111) transform into isostructural [Ag3(btim)] coordination networks based on double N–Ag–N bonds at 423 K, by virtue of the unconventional metal–acid replacement reaction (Ag reduces H+). The transformation expands the pore diameter of the honeycomb networks from 3.8 Å to 6.9 Å, giving remarkably different host–guest recognition behaviours for fullerene and ferrocene molecules based on the size compatibility mechanism.A hydrogen-bonded network on a Ag(111) surface can transform into an isostructural Ag(i) coordination network, giving drastically different host–guest recognition behaviours. 相似文献
60.