Helical polyurethane@attapulgite nanocomposite: Preparation, characterization and study of optical activity

Helical polyurethane@attapulgite (BM-ATT) based on R-1,1′-binaphthyl-2′,2-diol (R-BINOL) composite was prepared after the surface modification of attapulgite (ATT). BM-ATT was characterized by Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HTEM) and vibrational circular dichroism (VCD) spectroscopy. FT-IR and XRD analyses indicate that the helical polyurethane has been successfully grafted onto the surfaces of the modified ATT without destroying the original crystalline structure of ATT. BM-ATT exhibits the rod-like structure by SEM, TEM, and HTEM photographs. BM-ATT displays obvious Cotton effect for some absorbance in VCD spectrum, and its optical activity results from the singlehanded conformation of helical polyurethane.     

吉林速滑馆悬索钢结构屋盖稳定及抗震性能分析

针对国内第一个90米跨度大型索拱这一新型结构(吉林速滑馆悬索钢结构)进行稳定及抗震性能分析,分析结果表明:特征值屈曲分析结果不能作为评价本结构承载能力的依据;材料非线性对结构的承载能力影响很大,初始几何缺陷的影响不大,大变形对结构动力性能的影响不能忽略;反应谱法计算本结构地震作用会有较大的偏差,应采用时程分析法来分析地震作用;行波效应对本工程的影响不大.     

St/BA/KH-570三元共聚物的合成及其在云母增强聚丙烯中的应用

通过原子转移自由基聚合反应，合成了苯乙烯，丙烯酸丁酯和3－甲基丙烯酰氧基丙基三甲氧基硅烷的三元共聚物，发现该共聚合体系是一“活性”／受控聚合体系，三元共聚物的结构通过红外光变和核磁共振得以确认。研究了该三元共聚物作为大分子偶联剂对云母增强聚丙烯力学性能的影响。发现三元共聚物的组成和分子量对云母增强聚丙烯的力学性能有较大影响。     

Hydrogen bond effect of azido polyurethane elastomer by dynamic mechanical analysis

Hydrogen bond effects in azido polyurethane elastomers (APUE) have been studied by dynamic mechanical analysis (DMA) and the results show that the hydrogen bond effect has stronger temperature dependence. The activation energy of hydrogen bond dissociation (E_a) and the hydrogen bond density (vs/V) have been evaluated from the elastic modulus–temperature relationship. The calculated E_a in this work is much higher than the reported values of normal polyurethane elastomer (PUE). The values of E_a are 81.3, 68.1, 53.3, and 42.3 kJ/mol at 150, 110, 50, and 20 Hz, respectively, for PUE‐1 (CPPB/HDI trimer elastomer); 94.6, 75.8, 48.4, and 36.9 kJ/mol at 150, 110, 50, and 20 Hz, respectively, for PUE‐2 (APPB/HDI trimer elastomer); 82.1, 74.4, 59.8, and 46.5 kJ/mol at 150, 110, 50, and 20 Hz, respectively, for PUE‐3 (APPB/HDI trimer/EG elastomer); 145, 124, 88.0, and 75.5 kJ/mol at 150, 110, 50, and 20 Hz, respectively, for PUE‐4 (APPB/HDI trimer/BD elastomer); and 72.2, 64.3, 49.8, and 39.9 KJ/mol at 150, 110, 50, and 20 Hz, respectively, for PUE‐5 (APPB/HDI trimer/HD elastomer). The DMA estimations are semiquantitative for it ignores other physical crosslinking effects and the results give relative order of vs/V and E_a. The values of vs/V of crosslinked APUE (PUE‐3, PUE‐4, and PUE‐5) are much higher than PUE‐2. The test frequency could affect the values of vs/V and higher frequency would minify the difference of the values of vs/V for two given temperatures. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2841–2851, 2006     

Hydrodynamic Effect on Secondary Phase Separation in an Epoxy Resin Modified with Polyethersulfone

Summary: The evolution of the morphologies in blends of epoxy/4,4′‐methylenebis(2,6‐dimethylaniline)/polyethersulfone was followed by time‐resolved light scattering, optical microscopy and scanning electron microscopy. The results suggest that, once the diffusion of epoxy molecules cannot follow the geometrical growth, a secondary phase separation occurs, even in the droplet morphology, in which the size of the epoxy‐rich domain grows as usual. The viscoelastic effect of polyethersulfone is also discussed.

Development of morphologies followed by OM: bicontinuous phase separation in the PES‐15.9 blend cured at 140 °C after 80 s.     

Synthesis and Characterization of a Novel Class of PPV Derivatives Covalently Linked to C60

Poly(phenylenevinylene) (PPV) derivatives covalently linked to fullerene C₆₀ (PPV‐1‐C₆₀ and PPV‐2‐C₆₀) were synthesized by cycloaddition reaction between C₆₀ and azide group‐containing PPV derivatives. By tuning the initial feed ratio of the azido monomer, the content of C₆₀ in the copolymers was controlled. The copolymers were partially soluble in common organic solvents and were characterized by means of ¹H NMR, FT‐IR, UV‐Vis and fluorescence spectroscopy, as well as by GPC, TGA and cyclic voltammetry techniques.     

超声波辅助-活性炭富集-火焰原子吸收光谱法测定岩石矿物中的金

在战略性性矿产资源中,金一直都是极其紧缺且重要的元素。目前岩石矿物测定金使用较广泛的方法主要为火试金重量法、活性炭富集-原子吸收光谱法。然而这两种方法分析步骤都比较繁琐,受环境条件影响大,测样周期长,不适合大批量分析测试任务。本文通过超声波辅助,基于超声空化效应,活性炭在超声空化所产生的局部高温、高压、冲击波、微射流等加强传质作用下,能快速高效地对样品中的金离子进行富集的原理,建立一种独特的活性炭富集方法,改进过滤方式,运用火焰原子吸收光谱仪测定金的新方法。通过对9个金矿石成分标准物质GBW(E)070012a、GBW07807a、GBW07808b、GBW07300a、GBW07809b、GBW07297a、GBW07298a、GBW07299a、GBW07810进行实验对比分析,优化方法中活性炭用量,超声波频次与功率、时间、溶液温度等实验条件。研究确定活性炭用量为0.5g后金的回收率趋于稳定;超声波频次和时间设定为100kHZ,20min不仅测定数据准确且能较大幅度缩短工作时间;溶液温度控制在20℃为宜。在优化条件下,方法验证测定得出金的质量浓度在0~20mg/L范围内校准曲线方程为Abs=0.01958K+0.000642,相关系数（R2）为1.0000,以金矿石标准物质GBW(E)070012a平行测定12次计算得出方法检出限（MDL）为0.02248ug/g;以GBW07807a等8个金矿石标准物质进行精密度和正确度方法实验,相对误差（RE）为0.23%~1.50%,相对标准偏差（RSD）为0.43%~3.65%。与国家标准方法进行比对实验,实验证明新方法满足岩石矿物中金的分析要求。