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991.
Wenbin Zhang Siru Guo Prof. Shujuan Han Prof. Zhihua Yang Prof. Shilie Pan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(47):12047-12051
The first mixed calcium zinc borate with a new fundamental building block (FBB) [B8O17], Ca1.13Zn0.87B8O14 has been successfully synthesized. It exhibits two independent interpenetrating three-dimensional B−O anion networks constructed by [B8O17] groups, enriching the structural diversity of B−O configurations. In particular, the UV-Vis-NIR diffuse-reflectance spectrum shows that it has a short UV cutoff edge (<195 nm). 相似文献
992.
Nb2O5/C nanosheets are successfully prepared through a mixing process and followed by heating treatment.Such Nb2O5/C based electrode exhibits high rate performance and remarkable cycling ability, showing a high and stable specific capacity of ~380 mAh g-1 at the current density of 50 mA g-1(much higher than the theoretical capacity of Nb2O5).Further more,at a current density of 500 mA g-1,the nanocomposites electrode still exhibits a specific capacity of above 150 mAh g-1 after 100 cycles.These results suggest the Nb2O5/C nanocomposite is a high performance anode material for lithium-ion batteries. 相似文献
993.
可变体飞行器若要实现机翼后掠角、面积和前后缘弯度等参数的大幅度变化,机翼蒙皮需要具有光滑的气动外形、大变形、高承载以及驱动力小的特点。针对柔性蒙皮的需求,本文利用拓扑优化方法设计了一种新型零泊松比蜂窝结构,通过有限元仿真与U形蜂窝结构和余弦形蜂窝结构进行对比,验证其变形和承载等性能。以最大应变2%为基准,比较了三种蜂窝结构的变形能力。结果表明,新型蜂窝结构的拉伸变形量高达75%,分别是U形蜂窝结构和余弦形蜂窝结构的1.7倍和2.1倍。在最大位移量相同时,所需驱动力分别是U形蜂窝结构和余弦形蜂窝结构的0.51倍和0.28倍,表明新型蜂窝结构具有很大的易变形能力。当蜂窝结构的橡胶蒙皮受到相同压强载荷且处于初始未拉伸状态/拉伸状态时,新型蜂窝结构橡胶蒙皮的最大法向位移量分别是U形蜂窝橡胶蒙皮和余弦形蜂窝橡胶蒙皮的0.4倍/0.56倍和0.29倍/0.42倍,表明新型蜂窝结构具有良好的面外承载能力。另外,通过适当增加壁厚,可以提高新型蜂窝结构本身的抗弯曲能力。分析结果表明,本文设计的新型蜂窝结构具备大变形、高承载以及驱动力小的优点。 相似文献
994.
Liu H Zhang X Gao H Wang N Jin S Cai B Yao X Cai G 《Chemical & pharmaceutical bulletin》2005,53(10):1310-1313
Phytochemical study of the ethanol extract of the seeds of Aesculus assamica led to the isolation of two new triterpenoid saponins. The structure of the new compounds were elucidated on the basis of spectral data to be 28-O-acetyl-21-O-(4-O-angeloyl)-6-deoxy-beta-glucopyranosyl-3-O-[beta-glucopyranosyl(1-2)-O-[beta-glucopyranosyl(1-4)]-beta-glucuronopyranosyl]protoaescigenin (1), and 21-O-(4-O-angeloyl)-6-deoxy-beta-glucopyranosyl-3-O-[beta-glucopyranosyl(1-2)-O-[beta-glucopyranosyl(1-4)]-beta-glucuronopyranosyl]protoaescigenin (2). Their in vitro bioactivity against plant pathogenic fungus Pyricularia oryzae and cytotoxicity against K562 and HCT-15 cell lines were evaluated. 相似文献
995.
Synthesis,Characterization, and Energetic Properties of 6‐Amino‐tetrazolo[1,5‐b]‐1,2,4,5‐tetrazine‐7‐N‐oxide: A Nitrogen‐Rich Material with High Density 下载免费PDF全文
The synthesis and energetic properties of a novel N‐oxide high‐nitrogen compound, 6‐amino‐tetrazolo[1,5‐b]‐1,2,4,5‐tetrazine‐7‐N‐oxide, are described. Resulting from the N‐oxide and fused rings system, this molecule exhibits high density, excellent detonation properties, and acceptable impact and friction sensitivities, which suggests potential applications as an energetic material. Compared to known high‐nitrogen compounds, such as 3,6‐diazido‐1,2,4,5‐tetrazine (DiAT), 2,4,6‐tri(azido)‐1,3,5‐triazine (TAT), and 4,4′,6,6′‐tetra(azido)azo‐1,3,5‐triazine (TAAT), a marked performance and stability increase is seen. This supports the superior qualities of this new compound and the advantage of design strategy. 相似文献
996.
997.
Jiajia Ru Ting He Binjie Chen Yutong Feng Lianhai Zu Zhijun Wang Qiaobao Zhang Tianzi Hao Ruijin Meng Renchao Che Chi Zhang Jinhu Yang 《Angewandte Chemie (International ed. in English)》2020,59(34):14621-14627
Weak van der Waals interactions between interlayers of two‐dimensional layered materials result in disabled across‐interlayer electron transfer and poor layered structural stability, seriously deteriorating their performance in energy applications. Herein, we propose a novel covalent assembly strategy for MoS2 nanosheets to realize unique MoS2/SnS hollow superassemblies (HSs) by using SnS nanodots as covalent linkages. The covalent assembly based on all‐inorganic and carbon‐free concept enables effective across‐interlayer electron transfer, facilitated ion diffusion kinetics, and outstanding mechanical stability, which are evidenced by experimental characterization, DFT calculations, and mechanical simulations. Consequently, the MoS2/SnS HSs exhibit superb rate performance and long cycling stability in lithium‐ion batteries, representing the best comprehensive performance in carbon‐free MoS2‐based anodes to date. Moreover, the MoS2/SnS HSs also show excellent sodium storage performance in sodium‐ion batteries. 相似文献
998.
999.
Effective extraction and simultaneous determination of Sudan dyes from tomato sauce and chili‐containing foods using magnetite/reduced graphene oxide nanoparticles coupled with high‐performance liquid chromatography 下载免费PDF全文
Ming‐Yue Zhang Man‐Man Wang Yu‐Lan Hao Xin‐Ran Shi Xue‐Sheng Wang 《Journal of separation science》2016,39(9):1749-1756
A simple, effective, and robust magnetic solid‐phase extraction method was developed using magnetite/reduced graphene oxide nanoparticles as the adsorbent for the simultaneous determination of Sudan dyes (I, II, III, and IV) in foodstuffs. The magnetite/reduced graphene oxide nanoparticles were characterized by X‐ray diffraction, scanning electron microscopy, and vibrating sample magnetometry. The extraction parameters including extraction time, elution solution, and elution time and volume were investigated in detail. Such magnetite/reduced graphene oxide nanoparticles based magnetic solid‐phase extraction in combination with high‐performance liquid chromatography and variable wavelength detection gave the detection limits of 3–6 μg/kg for Sudan I–IV in chili sauce, tomato sauce, chili powder, and chili flake samples. The recoveries were 79.6–108% at three spiked levels with the intra‐ and inter‐day relative standard deviations of 1.2–8.6 and 4.5–9.6%, respectively. The feasibility was further performed by a comparison with commercial alumina‐N. This method is suitable for the routine analysis of Sudan dyes due to its sensitivity, simplicity, and low cost. 相似文献
1000.
基于压电陶瓷精密微位移系统的扫描探测技术是目前精密测量仪器进行微纳区域/结构性能测试的核心系统,但压电陶瓷材料存在迟滞、非线性问题,限制了对微位移分辨能力的提升.本文以金刚石氮空位色心为敏感单元,利用电子自旋效应对磁场强度的高分辨敏感机理,结合永磁体周围不同位置对应的磁场强度变化关系,提出了一种基于金刚石氮空位色心电子自旋敏感机理的微位移检测方法.通过建立电子自旋效应与微位移的关联模型,搭建了相应的微位移测量系统.经实验验证,该系统对微位移测试的灵敏度为16.67 V/mm,检测分辨率达到60 nm,实现了对微位移的高分辨率测量.并通过理论分析,该系统的微位移测量分辨率可进一步提升至亚纳米级水平,为新型微位移测量技术提供了发展方向和研究思路. 相似文献