Facile Yb(OTf)3 promoted one-pot synthesis of polyhydroquinoline derivatives through Hantzsch reaction

Yb(OTf)₃ catalyzed efficient Hantzsch reaction via four-component coupling reactions of aldehydes, dimedone, ethyl acetoacetate and ammonium acetate at ambient temperature was described as the preparation of polyhydroquinoline derivatives. The process presented here is operationally simple, environmentally benign and has excellent yield. Furthermore, the catalyst can be recovered conveniently and reused efficiently.     

The Standard Association Constant of Ion Pair [GaCl]~(2+)in the System of HCl+GaCl_3+H_2O

This paper reports the EMF(electromotive force) measurements of cell (A) without liquid junction at five temperatures from 278.15 to 318.15 K. Pt|H2(101.325kPa)|HCl(m1),GaCl3(m2),H2O|Ag|AgCl (A) The measurements on the system HCl+GaCl3+H2O was carried out in an appropriate concentration of hydrochloric acid when the concentration of hydrochloric acid is not lower than 0.13 mol/kg the hydrolysis of Ga3+ can be avoided or elimited1. The standard association constant, KAS ,…     

电流型大面积PIN探测器

研制了灵敏区面积为40,50和60mm,耗尽层厚度为200—300μm的电流型大面积薄型PIN半导体探测器,并对其物理性能进行了测量.测试和应用表明,这些探测器性能稳定,漏电流符合使用要求.与市场上的大面积PIN半导体探测器相比,这些探测器主要在几百伏偏压下工作在电流模式,但也可用于计数模式,而目前的商用产品仅适用于计数测量. 关键词： 半导体探测器 大面积 电流型     

Interior estimates for solutions of a fourth order nonlinear partial differential equation

Let be a locally strongly convex hypersurface, given by the graph of a convex function xn+1=f(x₁,…,xn) defined in a convex domain Ω⊂Rn. M is called a α-extremal hypersurface, if f is a solution of

     

Study on measurement of linear electro-optic coefficient of a minute irregular octahedron cBN wafer

The cubic boron nitride (cBN) is a kind of artificial electro-optic (EO) crystal, and we have not found any relative reports so far. Because the artificial synthetic cBN wafers are very small and hard, the wafers cannot be cut into rectangular slabs. The polarizer-sample-λ/4 retardation plate (compensator)-analyzer (PSCA) transverse EO modulator has to be adjusted to the minute irregular octahedron of cBN wafers. When the applied voltage is along [1 1 1] direction of the wafer, due to refraction, the angle between the incident beam direction and the (1 1 1) plane (top or bottom plane) of the wafer should be 25.4°, and the angle between the polarization direction of the polarizer and the plane of incidence should be 50.8° by calculation, respectively. The half-wave voltage of the cBN sample was obtained for the first time, by means of detection of the output optic signals from the modulator with and without an applied electric field on the sample, respectively. Furthermore, the linear EO coefficient was obtained, . The analysis of the experimental resulting error was carried out.     

An augmented Lagrangian method for optimization problems with structured geometric constraints

This paper is devoted to the theoretical and numerical investigation of an augmented Lagrangian method for the solution of optimization problems with geometric constraints. Specifically, we study situations where parts of the constraints are nonconvex and possibly complicated, but allow for a fast computation of projections onto this nonconvex set. Typical problem classes which satisfy this requirement are optimization problems with disjunctive constraints (like complementarity or cardinality constraints) as well as optimization problems over sets of matrices which have to satisfy additional rank constraints. The key idea behind our method is to keep these complicated constraints explicitly in the constraints and to penalize only the remaining constraints by an augmented Lagrangian function. The resulting subproblems are then solved with the aid of a problem-tailored nonmonotone projected gradient method. The corresponding convergence theory allows for an inexact solution of these subproblems. Nevertheless, the overall algorithm computes so-called Mordukhovich-stationary points of the original problem under a mild asymptotic regularity condition, which is generally weaker than most of the respective available problem-tailored constraint qualifications. Extensive numerical experiments addressing complementarity- and cardinality-constrained optimization problems as well as a semidefinite reformulation of MAXCUT problems visualize the power of our approach.

     

Cauchy problems for Hilfer fractional evolution equations on an infinite interval

It is well known that the classical Ascoli-Arzelà theorem is powerful technique to give a necessary and sufficient condition for investigating the relative compactness of a family of abstract continuous functions, while it is limited to finite compact interval. In this paper, we shall generalize the Ascoli-Arzelà theorem on an infinite interval. As its application, we investigate an initial value problem for fractional evolution equations on infinite interval in the sense of Hilfer type, which is a generalization of both Riemann-Liuoville and Caputo fractional derivatives. Our methods are based on the Hausdorff theorem, classical/generalized Ascoli-Arzelà theorem, Schauder fixed point theorem, Wright function, and Kuratowski measure of noncompactness. We obtain the existence of mild solutions on an infinite interval when the semigroup is compact as well as noncompact.     

A two-grid finite element method for the Allen-Cahn equation with the logarithmic potential

In this paper, we present a two-grid finite element method for the Allen-Cahn equation with the logarithmic potential. This method consists of two steps. In the first step, based on a fully implicit finite element method, the Allen-Cahn equation is solved on a coarse grid with mesh size H. In the second step, a linearized system whose nonlinear term is replaced by the value of the first step is solved on a fine grid with mesh size h. We give the energy stabilities of the traditional finite element method and the two-grid finite element method. The optimal convergence order of the two-grid finite element method in H¹ norm is achieved when the mesh sizes satisfy h = O(H²). Numerical examples are given to demonstrate the validity of the proposed scheme. The results show that the two-grid method can save the CPU time while keeping the same convergence rate.     

B型套筒角焊缝缺陷相控阵超声检测定量方法

B型套筒修复作为油气管道修复的主要方式之一,在其修复的焊接过程中,该结构的环形角焊缝内部常常出现以气孔、夹渣为代表的孔型缺陷。这类缺陷由于角焊缝特殊的结构,在利用相控阵超声无损检测技术对其检测时,难以对其进行定量分析。通过数值模拟和实验,发现通过相控阵超声扇扫得到缺陷回波信号峰值与孔型缺陷直径呈正相关,为孔型缺陷的定量分析提供了一种可靠的手段。     

Photonic graphene with reconfigurable geometric structures in coherent atomic ensembles

Photonic graphene, possesses a honeycomb-like geometric structure, provides a superior platform for simulating photonic bandgap, Dirac physics, and topological photonics. Here, the photonic graphene with reconfigurable geometric structures is demonstrated in a 5S_1/2 − 5P_3/2 − 5D_5/2 cascade-type ⁸⁵Rb atomic ensembles. A strong hexagonal-coupling field, formed by the interference of three identical coupling beams, is responsible for optically inducing photonic graphene in atomic vapor. The incident weak probe beam experiences discrete diffraction, and the observed pattern at the output plane of vapor cell exhibits a clear hexagonal intensity distribution. The complete photonic graphene geometries from transversely stretched to longitudinally stretched are conveniently constructed by varying the spatial arrangement of three coupling beams, and the corresponding diffraction patterns are implemented theoretically and experimentally to map these distorted geometric structures. Moreover, the distribution of lattice sites intensity in photonic graphene is further dynamically adjusted by two-photon detuning and the coupling beams power. This work paves the way for further investigation of light transport and graphene dynamics.