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961.
962.
A simple procedure for the systematical synthesis of eight distamycin analogues containing N‐methylpyrrole (Py) and N‐methylimidazole (Im) has been developed by a chloroform reaction and DCC coupling reaction without amino protection and deprotection, and the interaction of the analogues with Herring Sperm DNA was investigated by fluorescence spectroscopy. 相似文献
963.
Y Q Tang S H Tian J C Hua S X Wu G Zou K Tsou G F Wu E M Zhao 《Science in China. Series B, Chemistry, life sciences & earth sciences》1990,33(7):828-834
A new neurotensin (NT)-related peptide, margaratensin, was obtained by Sep-Pak C18 and RP-HPLC from methanol extracts of the skin of Chinese frog Rana margaratae. The structure of the peptide has been determined to be Asp-Lys-Arg-Pro-Tyr-Ile-Leu-His-Glu, which is found to be homologous to the COOH-terminal sequence of NT, but has an extra His-Glu at the COOH-terminus. The synthetic preparation was shown to be indistinguishable from the native peptide during HPLC, amino acid analysis and bioassay. Margaratensin exhibited a hypotensive effect in the rat but the response was weaker than NT. The peptide could induce a potent and reproducible contractile activity on GPI which was different from xenopsin, another NT-related peptide from amphibian skin. 相似文献
964.
Based on composite materials, the equivalent elastic-plastic constitutive equations of multiphase solid are researched. According to the suggested definition of constitutive equivalence it is demonstrated that the multiphase solid, composed of several kinds of homogeneous elastic-plastic media that conform to the generalized normality rule, has the same type of constitutive equations as its constituents have that also conform to the generalized normality rule. 相似文献
965.
966.
A theoretical approach to polycondensation reaction of Aa-Bb type Involving intramolecular cycllzatlon has been proposed by Tang Au-chin et al.. In this paper, the theoretical sol-gel distribution is tested by polycondensation of adipic acid with trimethylol propane in a sto-ichiometric ratio of 0. 8, and the effect of intramolecular cyclization is discussed in detail. 相似文献
967.
In a real production and distribution business environment with one supplier and multiple heterogeneous buyers, the differences
in buyers’ ordering cycles have influence on production arrangements. Consequently, the average inventory level (AIL) at the
supplier’s end is affected by both the production policy and the ordering policy, typically by the scheduling of deliveries.
Consequently, the average inventory holding cost is most deeply affected. In this paper, it is proposed that the scheduling
of deliveries be formulated as a decision problem to determine the time point at which deliveries are made to buyers in order
to minimize the supplier’s average inventory. A formulation of the average inventory level (AIL) in a production cycle at
the supplier’s end using a lot-for-lot policy is developed. Under the lot-for-lot policy, the scheduling of deliveries (SP) is formulated as a nonlinear programming model used to determine the first delivery point for each buyer with an objective
to minimize the sum of the product of the individual demand quantity and the first delivery time for each buyer. Thus, the
SP model determines not only the sequence of the first deliveries to individual buyers, but also the time when the deliveries
are made. An iterative heuristic procedure (IHP) is developed to solve the SP model assuming a given sequence of buyers. Six sequence rules are considered and evaluated via simulation. 相似文献
968.
Enhanced targeted energy transfer for adaptive vibration suppression of pipes conveying fluid 总被引:1,自引:0,他引:1
Nonlinear Dynamics - In this paper, a nonlinear energy sink and a negative stiffness element are integrated for achieving enhanced, passive, and adaptive vibration suppression for a pipe conveying... 相似文献
969.
Xiang Ru Xianghua Zeng Zhimei Li David J. Evans Caixia Zhan Ying Tang Lianjie Wang Xiaoming Liu 《Journal of polymer science. Part A, Polymer chemistry》2010,48(11):2410-2417
A complex pendant with two ethynyl groups, [Fe2(μ‐SCH2CCH)2(CO)6] ( 2 ), as a model of the diiron subunit of [FeFe]‐hydrogenase was polymerized and the {Fe2(CO)6} core was successfully incorporated into the polymer matrix. The polymer was characterized by a variety of spectroscopic techniques, TGA, FTIR, SEM, TEM, and NMR. The resultant polymer was immobilized via “click” chemistry using its terminal C?CH bond onto the surface of a gold electrode, which was premodified with azidothiol by self‐assembled monolayer (SAM). The assembled electrode showed electrochemical responses. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2410–2417, 2010 相似文献
970.
Bin Zhang Yu Chen Xiaodong Zhuang Gang Liu Bo Yu En‐Tang Kang Jinhui Zhu Yongxi Li 《Journal of polymer science. Part A, Polymer chemistry》2010,48(12):2642-2649
A new soluble donor‐acceptor type poly(N‐vinylcarbazole)‐covalently functionalized graphene oxide (GO‐PVK) has been synthesized by reaction of DDAT (S‐1‐dodecyl‐S′‐(α,α′‐dimethyl‐α″‐aceticacid)trithiocarbonate)‐PVK with GO‐toluene‐2,4‐diisocynate. The incorporation of sufficient amount of PVK chains makes the modified GO nanosheets readily dispersible in organic solvents. The resulting material exhibits an enhanced solubility of 10 mg/mL in organic solvents. Covalent grafting of PVK onto the edge and surface of GO nanosheets did not change the carbazole absorption in the ultraviolet region, but substantially reduced the absorption intensity of GO in the visible region. The intensity of the emission band of GO‐PVK at 437 nm was a little bit quenched when compared with that of DDAT‐PVK, suggesting intramolecular quenching from PVK to GO. Such intramolecular quenching process may involve energy or electron transfer between the excited singlet states of the PVK moiety and the GO moiety. The HOMO/LUMO values and the energy bandgap of GO‐PVK experimentally estimated by the onset of the redox potentials are ?5.60, ?3.58, and 2.02 eV, respectively. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2642–2649, 2010 相似文献